摘要:
An embodiment of the present application aims at providing a material which repeatedly undergoes a conversion reaction and an alloying reaction to have an improved columbic efficiency in a first cycle of the repeating, and thereby allowing the material to serve as a high-electrical capacity negative electrode of a lithium secondary battery. In order to attain the object, a negative-electrode material is made by mixed dispersion of (i) nanoparticles of an electrical conducting material having electronic conduction and (ii) nanoparticles of an electrode active material which is reducible to a simple substance which undergoes an alloying reaction with lithium. The electrical conducting material is a sulfide having electronic conduction, and the electrode active material is a sulfide of an element which undergoes the alloying reaction with lithium. Further, the element which undergoes the alloying reaction with lithium is silicon.
摘要:
An embodiment of the present application aims at providing a material which repeatedly undergoes a conversion reaction and an alloying reaction to have an improved coulombic efficiency in a first cycle of the repeating, and thereby allowing the material to serve as a high-electrical capacity negative electrode of a lithium secondary battery. In order to attain the object, a negative-electrode material is made by mixed dispersion of (i) nanoparticles of an electrical conducting material having electronic conduction and (ii) nanoparticles of an electrode active material which is reducible to a simple substance which undergoes an alloying reaction with lithium. The electrical conducting material is a sulfide having electronic conduction, and the electrode active material is a sulfide of an element which undergoes the alloying reaction with lithium. Further, the element which undergoes the alloying reaction with lithium is silicon.
摘要:
An Object of the invention is to obtain an all solid lithium battery having an excellent output performance. To achieve the object, a sulfide based solid electrolyte is used as an electrolyte; an oxide containing lithium, a metal element that acts as a redox couple, and a metal element that forms an electron-insulating oxide is used as a cathode active material; and the concentration of the metal element that forms the electron-insulating oxide on the surface of the cathode active material (oxide) that is in contact with the sulfide solid electrolyte is made high.
摘要:
An Object of the invention is to obtain an all solid lithium battery having an excellent output performance. To achieve the object, a sulfide based solid electrolyte is used as an electrolyte; an oxide containing lithium, a metal element that acts as a redox couple, and a metal element that forms an electron-insulating oxide is used as a cathode active material; and the concentration of the metal element that forms the electron-insulating oxide on the surface of the cathode active material (oxide) that is in contact with the sulfide solid electrolyte is made high.
摘要:
Therefore, the problem to be solved by the present invention is to provide highly general purpose ultra high strength fiber-reinforced mortar or concrete that shows a higher fluidity (workability) at the fresh state, a higher bending strength with a less content of metal fiber by enhancing both the absolute value of the compressive strength of mortar -matrix excluding metal fiber and the ratio of the bending strength relative to the compressive strength simultaneously at the hardened state, and acceptability of fine aggregate being used in ordinary ready-mixed concrete. An ultra high strength fiber-reinforced cement composition is characterized in that it contains cement, silica fume, coal gasification fly ash, gypsum and metal fiber and that the mass ratio of silica fume : coal gasification fly ash is 95 through 50 portions: 5 through 50 portions. Ultra high strength fiber-reinforced mortar or concrete contains such a cement composition and fine aggregate. An ultra high strength cement additives is characterized in that it contains silica fume, coal gasification fly ash and gypsum as principal ingredients and the mass ratio of silica fume: coal gasification fly ash is 95 through 50 portions: 5 through 50 portions.
摘要:
A solid-state secondary lithium battery with excellent charge and discharge cycle characteristics, using a negative electrode active material which shows discontinuous change of potential caused by the lithium ion insertion and extraction reactions, wherein the amount of the lithium ion inserted, until discontinuous change of potential of the negative electrode takes place, is equal to or smaller than the maximum amount of extraction of lithium ions within the range where lithium ions are inserted and extracted into or from the lithium transition metal oxide reversibly, and a battery assembly using these batteries.
摘要:
Electrochemical devices comprise at least a pair of electrodes and a lithium ion conductive electrolyte provided between the pair of electrodes. At least one of the electrodes comprises a lithium nitride-metal compound having a one-dimensional chain structure. By this, the number of end groups which greatly take part in characteristic degradation of the device can be reduced significantly, ensuring good characteristic properties. The devices include lithium secondary cells, electric double-layer capacitors, and electrochemical display devices.
摘要:
An electrode element contains a positive electrode active material and a second solid electrolyte. The positive electrode active material has an active material and a first solid electrolyte. Seventy percent or more of a surface of the active material is coated with the first solid electrolyte.
摘要:
A totally-solid lithium secondary battery can be improved in charge and discharge characteristics by adding to the negative electrode a first transition metal chalcogenide or lithium•transition metal chalcogenide which acts as the active material for negative electrode and a second transition metal chalcogenide or lithium•transition metal chalcogenide which inhibits precipitation of metallic lithium.
摘要:
A lithium iron oxide which can be used as an electrode active material for a lithium battery is disclosed. A lithium iron oxide represented by Li.sub.x FeO.sub.2, where 0