公开(公告)号：US11739050B2

公开(公告)日：2023-08-29

申请号：US17467974

申请日：2021-09-07

申请人： SCI PHARMTECH INC.

发明人： Chen-Yi Kao ,  Feng-Hsu Li

IPC分类号： C07C213/10 ,  C07C213/02 ,  C07D301/03

CPC分类号： C07C213/10 ,  C07C213/02 ,  C07D301/03 ,  C07C2601/14

摘要： Provided is a method of purifying a terpenoid amino alcohol derivative, including providing a crude terpenoid amino alcohol derivative; performing an acid/base crystallization process of the crude terpenoid amino alcohol derivative to obtain an organic salt; and reacting the organic salt with NaOH and toluene to obtain a purified terpenoid amino alcohol derivative. Also provided is a method of preparing p-mentha-2,8-diene-1-ol from the purified terpenoid amino alcohol derivative.

公开(公告)号：US20210292920A1

公开(公告)日：2021-09-23

申请号：US17197614

申请日：2021-03-10

申请人： CALERA CORPORATION

发明人： Michael Joseph Weiss ,  Kyle Self ,  Thomas A. Albrecht ,  Ryan J. Gilliam

IPC分类号： C25B3/27 ,  C25B1/26 ,  C25B1/02 ,  C25B1/20 ,  C25B3/23 ,  C25B9/17 ,  C25B9/19 ,  C25B11/095 ,  C25B1/00 ,  C07D301/03 ,  C25B1/18 ,  B01J27/122 ,  B01J27/132 ,  C07C17/02 ,  C25B1/46 ,  C25B1/16

摘要： There are provided methods and systems for an electrochemical cell including an anode and a cathode where the anode is contacted with a metal ion that converts the metal ion from a lower oxidation state to a higher oxidation state. The metal ion in the higher oxidation state is reacted with hydrogen gas, an unsaturated hydrocarbon, and/or a saturated hydrocarbon to form products.

公开(公告)号：US10604496B2

公开(公告)日：2020-03-31

申请号：US15554922

申请日：2016-03-02

申请人： SABIC Global Technologies B.V.

发明人： Talal Al-Shammari ,  Khalid Karim ,  Zeeshan Nawaz ,  Ali Al-Hammad ,  Shehzada Khurram ,  Mubarik Ali Bashir ,  Labeeb Chaudhary Ahmed ,  Abdullah Turki Al-Jaloud ,  Saud Al-Khudeer ,  Thabet Al-Qahtani

IPC分类号： C07D301/03 ,  C07D301/32 ,  C07C213/04 ,  C07C29/10 ,  C07C1/04 ,  C07C5/32 ,  C07C9/06 ,  C07C11/04 ,  C07C31/20 ,  C07C215/08 ,  C10G2/00

摘要： Disclosed herein is a method comprising the steps of: a) producing a hydrocarbon stream from syngas via a Fischer-Tropsch reaction, wherein the hydrocarbon stream comprises a first C2 hydrocarbon stream comprising ethane and a first ethylene product; b) separating at least a portion of the first C2 hydrocarbon stream from the hydrocarbon stream; c) separating at least a portion of the first ethylene product from the first C2 hydrocarbon stream, thereby producing a second C2 hydrocarbon stream; d) converting at least a portion of the ethane in the second C2 hydrocarbon stream to a second ethylene product; and e) producing ethylene oxide from at least a portion of the second ethylene product.

公开(公告)号：US20190184387A1

公开(公告)日：2019-06-20

申请号：US16328033

申请日：2017-08-30

申请人： Dow Technology Investments LLC

发明人： Mohmed A. Syed ,  Apoorva Kulkarni ,  Vera P. Santos Castro ,  Victor J. Sussman ,  John C. McKeen ,  Cathy L. Tway ,  Clifford S. Todd

IPC分类号： B01J37/02 ,  B01J23/50 ,  B01J37/00 ,  B01J21/04 ,  B01J37/08 ,  B01J35/10 ,  C07D301/03 ,  C07C68/00 ,  C07C213/00 ,  C07C41/02 ,  C07C29/00

摘要： A process for preparing a silver-containing catalyst for the selective oxidation of ethylene to ethylene oxide including the steps of: (a) providing a multimodal support, (b) preparing an impregnation solution comprising a silver component, (c) impregnating, at least once, the multimodal support of step (a) with the silver-containing impregnation solution of step (b) to form an impregnated support; (d) subjecting the impregnated multimodal support from step (c) to a removal means, such as a centrifuge, at least once, for a time sufficient to remove impregnated silver impregnation solution from the multimodal support and to control the amount of silver in the pores of the multimodal support by selectively removing impregnated silver impregnation solution from a set of larger pores in the multimodal support; (e) roasting, at least once, the multimodal support after the step (d); (f) optionally, repeating the impregnation step (c), (g) optionally, repeating the centrifugation step (d), and (h) optionally, repeating the calcination step (e).

公开(公告)号：US20180148426A1

公开(公告)日：2018-05-31

申请号：US15876974

申请日：2018-01-22

申请人： Novozymes A/S

发明人： Henrik Lund ,  Lisbeth Kalum ,  Martin Hofrichter ,  Sebastian Peter

IPC分类号： C07D301/03 ,  C12N9/08 ,  C12P17/02

CPC分类号： C07D301/03 ,  C07D301/12 ,  C12N9/0065 ,  C12P7/00 ,  C12P17/02 ,  C12Y111/02001 ,  Y02P20/52

摘要： The invention relates to enzymatic methods for epoxidation of a non-cyclic aliphatic alkene, or a terpene.

公开(公告)号：US09908948B2

公开(公告)日：2018-03-06

申请号：US15507029

申请日：2015-08-28

申请人： GALDERMA S.A.

发明人： Jean-Guy Boiteau ,  Lars Nord ,  Thibaut Gerfaud

IPC分类号： A61K31/728 ,  C08B37/08 ,  C07D303/27 ,  C07D303/24 ,  C07D301/03 ,  C07C29/10

CPC分类号： C08B37/0072 ,  A61K31/728 ,  C07C29/10 ,  C07D301/03 ,  C07D303/24 ,  C07D303/27

摘要： Enantiomers of butanediol diglycidyl ether (BDDE) are present in an enantiomerically enriched enantioenriched mixture of BDDE stereisomers or in an enantiomerically pure BDDE. Enantiomerically enriched or pure BDDE is useful as a cross-linking agent, such as in the preparation of a cross-linked hyaluronic acid product.

公开(公告)号：US09783548B2

公开(公告)日：2017-10-10

申请号：US15038107

申请日：2014-11-17

申请人： JX NIPPON OIL & ENERGY CORPORATION ,  OSAKA UNIVERSITY

发明人： Junko Ichihara ,  Shunro Yamaguchi ,  Atsushi Kameyama ,  Takashi Suzuki ,  Takashi Morikita

IPC分类号： C07D301/12 ,  C07D301/03 ,  C07D493/04 ,  B01J23/30

CPC分类号： C07D493/04 ,  B01J23/30 ,  C07D301/12

摘要： A method for producing an epoxy compound by reacting a compound having a carbon-carbon double bond with hydrogen peroxide in the coexistence of the compound having a carbon-carbon double bond, aqueous hydrogen peroxide, a powder of a solid catalyst support and a powder of a solid catalyst, wherein the solid catalyst comprises an isopolyacid, and the isopolyacid is produced from a catalyst raw material comprising (a) tungstic acid or a salt thereof and (b) at least one selected from the group consisting of a salt of an alkaline earth metal and a cationic polymer.

公开(公告)号：US09719037B2

公开(公告)日：2017-08-01

申请号：US15197838

申请日：2016-06-30

申请人： NOVOMER, INC.

发明人： Sadesh H. Sookraj

IPC分类号： C07C51/14 ,  C10J3/72 ,  C07D301/03 ,  C07D307/60 ,  C07D493/18 ,  C07D307/89 ,  C07C1/24 ,  C07C51/41

CPC分类号： C10J3/72 ,  C07C1/24 ,  C07C51/416 ,  C07D301/03 ,  C07D307/60 ,  C07D307/89 ,  C07D493/18 ,  C10J2300/0916 ,  Y02P20/52 ,  C07C63/26 ,  C07C11/04

摘要： The present invention provides methods for the production of terephthalic acid and derivatives thereof using ethylene oxide, carbon monoxide and furan as feedstocks. The process is characterized by high yields and high carbon efficiency. The process can utilize 100% biobased feedstocks (EO via ethanol, CO via biomass gasification, and furan via known processes from cellulosic feedstocks).

公开(公告)号：US09433925B2

公开(公告)日：2016-09-06

申请号：US14602410

申请日：2015-01-22

申请人： Lyondell Chemical Technology, L.P.

发明人： Roger Grey ,  Debra Jackson ,  Daniel F. White ,  Sandor Nagy

IPC分类号： C07D301/03 ,  B01J21/08 ,  B01J37/08 ,  B01J21/06 ,  B01J35/10 ,  B01J37/02 ,  B01J37/06 ,  B01J29/03 ,  B01J29/89 ,  C07D301/12 ,  C07D301/19

CPC分类号： B01J21/08 ,  B01J21/06 ,  B01J29/0308 ,  B01J29/89 ,  B01J35/10 ,  B01J35/1042 ,  B01J37/02 ,  B01J37/0203 ,  B01J37/0209 ,  B01J37/06 ,  B01J37/08 ,  B01J2229/186 ,  B01J2229/32 ,  C07D301/12 ,  C07D301/19

摘要： A method of preparing epoxidation catalysts is disclosed. The method comprises: (a) adding an inorganic siliceous solid to a column to produce a solid-filled column; (b) adding to the solid-filled column a solution comprising titanium tetrachloride and a hydrocarbon solvent to produce a titanium tetrachloride-impregnated solid; and (c) calcining the titanium tetrachloride-impregnated solid at a temperature from 500° C. to 1000° C. to produce the catalyst. The inorganic siliceous solid has a pore volume of at least 0.8 cm3/g.

摘要翻译： 公开了制备环氧化催化剂的方法。 该方法包括：（a）将无机硅质固体加入柱中以制备固体填充柱; （b）向固体填充柱中加入包含四氯化钛和烃溶剂的溶液以产生四氯化钛浸渍的固体; 和（c）在500℃至1000℃的温度下煅烧四氯化钛浸渍的固体以制备催化剂。 无机硅质固体具有至少0.8cm 3 / g的孔体积。

公开(公告)号：US09346774B2

公开(公告)日：2016-05-24

申请号：US12437172

申请日：2009-05-07

申请人： Marek Matusz ,  Paul Michael McAllister

发明人： Marek Matusz ,  Paul Michael McAllister

IPC分类号： C07D301/03 ,  C07D301/10

CPC分类号： C07D301/10 ,  Y02P20/142 ,  Y02P20/52

摘要： A process is provided for the start-up of an ethylene epoxidation process comprising: (a) contacting a catalyst bed comprising a high selectivity epoxidation catalyst with a feed comprising ethylene, oxygen and an organic chloride for a period of time until an increase of at least 1×10−5 mole-% of vinyl chloride (calculated as the moles of vinyl chloride relative to the total gas mixture), preferably 2×10−5 mole-% of vinyl chloride is detected in a reactor outlet gas or a recycle gas loop; and (b) subsequently adjusting the quantity of organic chloride in the feed to a value sufficient to produce ethylene oxide at a substantially optimum selectivity.

摘要翻译： 提供了一种启动乙烯环氧化方法的方法，包括：（a）将包含高选择性环氧化催化剂的催化剂床与包含乙烯，氧气和有机氯化物的进料接触一段时间，直到增加 在反应器出口气体或回收物中检测到最少1×10-5摩尔％的氯乙烯（以氯乙烯相对于总气体混合物的摩尔计算），优选2×10-5摩尔％的氯乙烯 气回路 和（b）随后将进料中的有机氯化物的量调节至足以以基本上最佳选择性产生环氧乙烷的值。