知搜-全球专利检索

  1. Login
  2. Sign Up

Search Results

115 records (took 0.015 seconds)

    Liquid-crystal mixture with a pleochroic anthraquinone dye, and method for producing such a dye
    2.
    发明授权
    Liquid-crystal mixture with a pleochroic anthraquinone dye, and method for producing such a dye 失效
    具有多色性蒽醌染料的液晶混合物，以及这种染料的制造方法

    公开(公告)号：US4491532A

    公开(公告)日：1985-01-01

    申请号：US301046

    申请日：1981-09-10

    Applicant: Gunther Scherowsky ,  Alexander Moller ,  Gerd Heppke ,  Burkhard Knippenberg

    Inventor： Gunther Scherowsky ,  Alexander Moller ,  Gerd Heppke ,  Burkhard Knippenberg

    IPC: C09B1/00 ,  C09B1/02 ,  C09B1/14 ,  C09B1/22 ,  C09B1/28 ,  C09B1/50 ,  C09B1/503 ,  C09B1/515 ,  C09B1/54 ,  C09B55/00 ,  C09K19/60 ,  G02F1/137 ,  C09K3/34 ,  C09B1/16

    CPC classification number: C09B1/50 ,  C09B1/22 ,  C09B55/007 ,  C09K19/603

    Abstract: Liquid-crystal mixture with a pleochroic anthraquinone dye of the general formula ##STR1## with R.sup.1, R.sup.3, R.sup.4, R.sup.6 =H, OH, OCH.sub.3, NH.sub.2, NHCH.sub.3, NO.sub.2, characterized by the feature that ##STR2## (R.sup.7 =H, alkyl, cycloalkyl, alkoxy, alkylmercapto, amino, alkylamino, dialkylamino, nitro, cyano, halogen), ##STR3## COOR.sup.9, CH.sub.2 --OR.sup.9 (R.sup.8 =H, alkyl, cycloalkyl, alkoxy, alkylmercapto, amino, alkylamino, dialkylamino, nitro, cyano, halogen); R.sup.9 =H, alkyl and either R.sup.1, R.sup.4 =H, OH, NH.sub.2, NHCH.sub.3, NO.sub.2, NHCH.sub.3, NO.sub.2, OCH.sub.3, where at least one of the two radical is an NH.sub.2 or an NHCH.sub.3, R.sup.3 =R.sup.6 =H, or R.sup.3, R.sup.6 =H, OH, NH.sub.2, NHCH.sub.3, NO.sub.2, OCH.sub.3, where at least one of the two radicals is an NH.sub.2 or an NHCH.sub.3, R.sup.1 =R.sup.4 =H.

    Abstract translation: 具有通式“IMAGE”的具有R1，R3，R4，R6 = H，OH，OCH3，NH2，NHCH3，NO2的双色性蒽醌染料的液晶混合物，其特征在于， 烷基，烷基，烷基氨基，烷基氨基，硝基，烷基氨基，烷基氨基，烷基氨基，烷基氨基， 氰基，卤素）; R 9 = H，烷基和R 1，R 4 = H，OH，NH 2，NHCH 3，NO 2，NHCH 3，NO 2，OCH 3，其中两个基团中的至少一个是NH 2或NHCH 3，R 3 = R 6 = H或R 3 ，R6 = H，OH，NH2，NHCH3，NO2，OCH3，其中两个基团中的至少一个是NH 2或NHCH 3，R 1 = R 4 = H。

    Process for the manufacture of N-alkylamino- and N,N-dialkylaminoanthraquinones
    6.
    发明授权
    Process for the manufacture of N-alkylamino- and N,N-dialkylaminoanthraquinones 失效
    制备N-烷基氨基和N，N-二烷基氨基蒽醌的方法

    公开(公告)号：US4044030A

    公开(公告)日：1977-08-23

    申请号：US688517

    申请日：1976-05-20

    Applicant: Zdenek Seha

    Inventor： Zdenek Seha

    IPC: C09B1/28 ,  C09B1/30 ,  C09B1/515 ,  C09B1/16 ,  C09B1/20

    CPC classification number: C09B1/28 ,  C09B1/30 ,  C09B1/515

    Abstract: A process for the manufacture of N-alkylamino- and N,N-dialkylaminoanthraquinone from the corresponding nitroanthraquinones, which comprises reacting substituted or unsubstituted nitroanthraquinones or dinitroanthraquinones with at least twice the molar amount, referred to the nitro groups to be reacted, of an alkyl acid amide, at temperatures between 100.degree. C and the boiling point of the alkyl acid amide.The present invention provides a process for the manufacture of N-alkylamino- and N,N-dialkylaminoanthraquinones from the corresponding nitroanthraquinones, which process comprises reacting substituted or unsubstitued nitroanthraquinones or dinitroanthraquinones with at least twice the molar amount, referred to the nitro groups to be reacted, of an alkyl acid amide which is simultaneously reactant and reaction medium, at temperatures between 100.degree. C and the boiling point of the alkyl acid amide.The reaction takes place according to the general reaction equation ##STR1## wherein R and R', which are the same or different, represent alkyl, aralkyl, cycloalkyl or hydroxyalkyl radicals of 1 to 8 carbon atoms,n is 0 or 1,X represents a functional substituent, for example the carboxyl, sulpho, hydroxy, amino or halogen group, which can be attached direct or through a bridge member to the anthraquinone nucleus.The reaction can be carried out with mononitroanthraquinones and/or dinitroanthraquinones.The aminoanthraquinones obtained by the process of this invention are known and are useful dyes or dyestuff intermediates.The aminolysis of nitroanthraquinones is described in German Pat. Nos. 136.777, 136.778 and 144.634. However, polar solvents, such as water, alcohols or pyridine, are used as reaction media therein.The use of polar solvents as reaction media results in only very poor yields and lengthy reaction times are required. For example, the reaction of 1-nitroanthraquinone with a 300% excess of isopropylamine at 75.degree. C after 100 hours gives a yield of only 70% of 1-isopropylaminoanthraquinone.Swiss Pat. application No. 12793/74 describes the aminolysis by reacting nitroanthraquinones with organic amines using dipolar aprotic solvents which contain --SO.sub.2 or --SO groups as reaction media. This process is satisfactory up to the recovery of the solvents used as reaction medium, which may have to be separated by distillation from the amines used as reactants.By comparison, N-alkylamino- and N,N-dialkylamino-anthraquinones are obtained surprisingly in very high and often even quantitative yields by the process of this invention. The products are obtained in a high degree of purity, so that mostly they do not need to be purified any more. The reaction conditions are simple and the reaction course is easily kept under control. No problems regarding corrosion or of a technical nature arise in respect of the apparatus used and the recovery of the excess acid amide used as reaction medium presents no difficulties. The reaction course is uniform and virtually no residues occur, so that the process of this invention also marks a considerable advance especially from the ecological standpoint.The excess acid amide can be almost completely recovered after the reaction by simple distillation or by filtering it off from the product, and reused for a fresh batch.Examples of aminoanthraquinones which can be obtained by the process of this invention are:1-isopropylaminoanthraquinone, 1-isobutylamino-2-methylanthraquinone, 1-methylaminoanthraquinone, 1-diethylaminoanthraquinone, 1-cyclohexylaminoanthraquinone, the sodium salt of 1-isopropylaminoanthraquinone-6/7-sulphonic acid, 1-isobutylaminoanthraquinone, 1-diisopropyl-, 1-diisobutyl- and 1-dicyclohexylaminoanthraquinone, 1-isopropylamino-2-methylanthraquinone 1-cyclohexylamino-2-methylanthraquinone, 1,5-bis-methylaminoanthraquinone and 1-dimethylaminoanthraquinone.The aminolysis is carried out in conventional reaction vessels or autoclaves. A suitable apparatus is the rotary evaporator or, for batches produced on an industrial scale, the paddle drier (Venulett). The reaction temperature will be at least 100.degree. C. The preferred reaction temperature is between 160.degree. and 200.degree. C. The aminolysis can be carried out both under pressure and without pressure. It is preferred to operate without pressure. The reaction time is from 0.5 to 15 hours, preferably 1 to 5 hours.The weight ratio of the acid amide as reactant and reaction medium to the nitroanthraquinone is advantageously between 4:1 to 10:1.Suitable acid amides are those of the formulae HCONHR, RCONHR, HCONRR', RCONNRR' or those of the formulae PO(--NRR').sub.3, SO.sub.2 (--NRR').sub.2 or SO(--NRR').sub.2, wherein R and R', which are the same or different, represent alkyl, aralkyl, cycloalkyl or hydroxyalkyl radicals of 1 to 8 carbon atoms.An alkyl group represented by each of R and R' can be the same or different, straight-chain or branched, and is in particular a low molecular alkyl group of 1 to 4 carbon atoms, such as methyl, ethyl, propyl, isopropyl, tert.butyl, or a long-chain alkyl group, such as hexyl or octyl. A cycloalkyl group represented by each of R and R' is in particular the cyclohexyl group and an aralkyl group represented by R and R' is above all the benzyl or phenethyl group. Preferably each of R and R' represents a lower alkyl group.Examples of acid amides which can be used according to the invention are:N-methyl formamide, N-methyl acetamide, N,N-dimethyl formamide, N-ethyl formamide and hexamethylphosphoric triamide or tetramethyl thionyl diamide.The reaction is carried out, for example, in such a way that the reactants, nitroanthraquinone and acid amide, are charged into a reaction vessel and stirred for several hours at temperatures between 100.degree. and 200.degree. C. When the reaction is complete, the excess acid amide is distilled off and can be reused. In many cases the product crystallises out after the reaction mixture has cooled, so that it is separated by filtration, and the mother liquor (i.e., excess acid amide with a small amount of dissolved product) can be reused for further reactions. It will be readily understood that the products can also be isolated by diluting the reaction mixture with water or alcohols and subsequent filtration.The following Examples illustrate the process of the present invention without implying any restriction to what is described therein. The parts are by weight.

    Abstract translation: 一种从相应的硝基蒽醌制备N-烷基氨基 - 和N，N-二烷基氨基蒽醌的方法，其包括使取代或未取代的硝基蒽醌或二硝基蒽醌与至少两倍摩尔量的硝基蒽醌或二硝基蒽醌反应， 酸酰胺，在100℃和烷基酰胺的沸点之间。

    Transfer dyes
    8.
    发明授权
    Transfer dyes 失效
    转移染料

    公开(公告)号：US4029468A

    公开(公告)日：1977-06-14

    申请号：US582727

    申请日：1975-06-02

    Applicant: Karl Maier ,  Fritz Graser ,  Guenter Meyer

    Inventor： Karl Maier ,  Fritz Graser ,  Guenter Meyer

    IPC: B41M5/382 ,  C09B1/02 ,  C09B1/28 ,  C09B1/515 ,  D06P5/00 ,  D06P5/28 ,  B41C1/06 ,  D06P1/22

    CPC classification number: D06P5/006 ,  C09B1/02 ,  C09B1/28 ,  C09B1/515

    Abstract: Dye formulations for transfer printing which in addition to conventional ingredients contain dyes of the formula ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 are hydrogen, hydroxy, chloro, bromo or alkylamino substituents, one of R.sup.1 to R.sup.3 being different from hydrogen. The dyes are distinguished by a comparatively very low transfer temperature.

    Abstract translation: 用于转印的染料配方，其中除了常规成分之外，还含有式“IMAGE”的染料，其中R 1，R 2和R 3为氢，羟基，氯，溴或烷基氨基取代基，R 1至R 3不同于氢。 通过相对非常低的转印温度区分染料。

    Turquoise biscationic anthraquinone dyes
    9.
    发明授权
    Turquoise biscationic anthraquinone dyes 失效
    TURQUOISE BISCATIONIC ANTHRAQUINONE DYES

    公开(公告)号：US3646072A

    公开(公告)日：1972-02-29

    申请号：US3646072D

    申请日：1970-07-27

    Applicant: DU PONT

    Inventor： JAMES DANIEL SHAW

    IPC: C09B1/50 ,  C09B1/515

    CPC classification number: C09B1/501 ,  C09B1/515

    Abstract: ACID MODIFIED BULK CONTINUOUS FILAMENT NYLON FIBERS CAN BE DYED IN TURQUOISE SHADES WITH BISCATIONIC ANTHRAQUINONE DYES PREPARED BY QUARTERNIZING THE BISCONDENSATION PRODUCT OF AN N,N-DISUBSTITUTED C2-4 ALKYLENEDIAMINE AND 1,4,5,8-TETRAHYDROXYANTHRAQUINONE. THE BISCATIONIC DYES HAVE EXCELLENT RESERVE ON UNMODIFIED NYLON FIBERS AND FIBERS SO DYED HAVE SUFFICIENT LIGHT FASTNESS FOR USE IN NYLON STYLING CARPETING.

Patent Agency Ranking