Organopolysiloxanes having quaternary ammonium groups and processes for the preparation thereof
    1.
    发明授权
    Organopolysiloxanes having quaternary ammonium groups and processes for the preparation thereof 失效
    具有季铵基团的有机聚硅氧烷及其制备方法

    公开(公告)号:US06730766B2

    公开(公告)日:2004-05-04

    申请号:US10202822

    申请日:2002-07-25

    IPC分类号: C08G7726

    摘要: Organopolysiloxanes bearing quaternary ammonium groups and containing units of the general formula —[R2—(SiR2—O)b—SiR2—R2—N+R12]n—·nX−  (I′) where R are identical or different monovalent, SiC-bonded, optionally substituted C1-12 hydrocarbon radicals, R1 are identical or different monovalent, optionally substituted C1-12 hydrocarbon radicals or are a bridging alkylene radical, X is an organic or inorganic anion, R2 is a divalent hydrocarbon radical having at least 4 carbon atoms which contains at least one hydroxyl group and is optionally interrupted by one or more oxygens, b is an integer from 1 to 200 and n is an integer from 1 to 50. and processes for the preparation thereof.

    摘要翻译: 带有季铵基团并且含有通式化合物R的单元的有机聚硅氧烷是相同或不同的一价,SiC键合的任选取代的C 1-12烃基,R 1是相同或不同的单价,任选取代的C 1-12烃基或是 桥连亚烷基,X是有机或无机阴离子,R 2是具有至少4个碳原子的二价烃基,其含有至少一个羟基并且任选被一个或多个氧中断,b是1的整数 至200,n为1〜50的整数,其制备方法。

    Polyurethane prepolymers with reduced functionality having terminal alkoxysilane and OH groups, a method of preparing them and their use
    6.
    发明授权
    Polyurethane prepolymers with reduced functionality having terminal alkoxysilane and OH groups, a method of preparing them and their use 失效
    具有缩合官能度的聚氨酯预聚物具有末端烷氧基硅烷和OH基团,其制备方法及其应用

    公开(公告)号:US06762270B2

    公开(公告)日:2004-07-13

    申请号:US10357002

    申请日:2003-02-03

    IPC分类号: C08G7726

    摘要: The present invention relates to polyurethane prepolymer having terminal alkoxysilane and OH groups which is the reaction product of A) a polyurethane prepolymer prepared by incomplete reaction of i) an aromatic, aliphatic or cycloaliphatic diisocyanate component having an NCO content of 20 to 60% by weight with ii) a polyol component comprising a polyoxyalkylene diol having a number average molecular weight of 3000 to 20,000, wherein the reaction is stopped after 50 to 90% of the OH groups of component ii) are reacted and 10 to 50% are unreacted, with B) a compound having alkoxysilane and amino groups, preferably a compound containing alkoxysilane and aspartate groups. The present invention also relates to a process for preparing these polyurethane prepolymers containing terminal alkoxysilane and OH groups and to isocyanate-free, sealants, adhesives, primers and coatings containing these polyurethane prepolymers containing terminal alkoxysilane and OH groups as binders.

    摘要翻译: 本发明涉及具有末端烷氧基硅烷和OH基团的聚氨酯预聚物,其是A)由NCO含量为20〜60重量%的芳香族,脂肪族或脂环族二异氰酸酯成分的不完全反应制备的聚氨酯预聚物,ii) 包含数均分子量为3000〜20,000的聚氧化亚烷基二醇的多元醇成分,其中在组分ⅱ)的50〜90%的OH基反应10〜50%后,反应停止,B)化合物 具有烷氧基硅烷和氨基,优选含有烷氧基硅烷和天冬氨酸基团的化合物。本发明还涉及一种制备这些含有末端烷氧基硅烷和OH基团的聚氨酯预聚物和不含异氰酸酯的密封剂,粘合剂,底漆和含有这些聚氨酯的涂料的方法 含有末端烷氧基硅烷和OH基作为粘合剂的预聚物。

    Solventless polyimide silicone resin compositions
    7.
    发明授权
    Solventless polyimide silicone resin compositions 有权
    无溶剂聚酰亚胺硅树脂组合物

    公开(公告)号:US06706841B2

    公开(公告)日:2004-03-16

    申请号:US10140251

    申请日:2002-05-08

    IPC分类号: C08G7726

    摘要: A polyimide silicone resin composition comprising a polyimide silicone resin having recurring units of formula (1), a (meth)acrylic compound, and a polymerization initiator has fluidity at 25° C. despite the substantially absence of a solvent. In formula (1), X is a tetravalent organic group, Y is a divalent organic group, Z is a divalent organic group having an organosiloxane structure, p and q are positive numbers. The composition using the reactive (meth)acrylic compound as a diluent for the polyimide silicone resin is substantially free of a solvent and thus eliminates the step of solvent removal while it is highly adherent to various shapes of substrates

    摘要翻译: 包含具有式(1)的重复单元的聚酰亚胺硅树脂,(甲基)丙烯酸化合物和聚合引发剂的聚酰亚胺硅树脂组合物尽管基本上不存在溶剂,但在25℃下具有流动性。 在式(1)中,X是四价有机基团,Y是二价有机基团,Z是具有有机硅氧烷结构的二价有机基团,p和q是正数。 使用反应性(甲基)丙烯酸类化合物作为聚酰亚胺硅酮树脂的稀释剂的组合物基本上不含溶剂,因此消除了溶剂去除的步骤,同时它与各种形状的基材高度贴合

    Room temperature curable organopolysiloxane composition
    8.
    发明授权
    Room temperature curable organopolysiloxane composition 失效
    室温可固化的有机聚硅氧烷组合物

    公开(公告)号:US06670439B2

    公开(公告)日:2003-12-30

    申请号:US10268897

    申请日:2002-10-11

    IPC分类号: C08G7726

    摘要: A room temperature curable organopolysiloxane composition of the ketone removal type comprising a diorganopolysiloxane having a minimized content of low-molecular-weight organopolysiloxanes as a base polymer, and an alkenoxysilane as a crosslinking agent does emit essentially no low-molecular-weight siloxanes and organic matter with the passage of time after curing and is suitable for use as a sealant in a clean room and as a sealant or adhesive on electrical and electronic parts.

    摘要翻译: 包括具有最小含量的低分子量有机聚硅氧烷作为基础聚合物的二有机聚硅氧烷和作为交联剂的链烯氧基硅烷的除酮类型的室温可固化的有机聚硅氧烷组合物基本上不发射低分子量的硅氧烷和有机物质 固化后经过时间,适用于洁净室中的密封剂,电气和电子部件上的密封剂或粘合剂。