Photopolymerizable compositions containing polymeric binding agents
    6.
    发明授权
    Photopolymerizable compositions containing polymeric binding agents 失效
    含有聚合物粘合剂的可光聚合组合物

    公开(公告)号:US3887450A

    公开(公告)日:1975-06-03

    申请号:US31515372

    申请日:1972-12-14

    Applicant: DYNACHEM CORP

    Abstract: In a photopolymerizable composition which comprises an addition polymer, an initiation system, and a polymerizable inhibitor, the improvement of using a preformed macromolecular binding agent which is a copolymer of a first monomer of a styrene-type material or a non-acidic vinyl compound and an unsaturated carboxyl-containing monomer, wherein the ratio of the first monomer to the unsaturated carboxyl-containing monomer is sufficient to render the binding agent soluble in a dilute alkaline solution. The composition may be developed in an alkaline aqueous solution and the resist formed thereby is impervious to conventional plating and etching solutions.

    Abstract translation: 在包含加成聚合物,引发体系和可聚合抑制剂的光聚合组合物中,使用作为苯乙烯类材料或非酸性乙烯基化合物的第一单体与非酸性乙烯基化合物的共聚物的预成型大分子结合剂的改进,以及 不饱和含羧基单体,其中第一单体与不饱和含羧基单体的比例足以使粘合剂溶于稀碱溶液中。 组合物可以在碱性水溶液中显影,并且由此形成的抗蚀剂不受常规电镀和蚀刻溶液的影响。

    Core-shell vinyl halide polymers having a long-chain vinyl ether containing shell
    7.
    发明授权
    Core-shell vinyl halide polymers having a long-chain vinyl ether containing shell 失效
    具有长链含乙烯壳的壳聚乙烯醇聚合物

    公开(公告)号:US3673282A

    公开(公告)日:1972-06-27

    申请号:US3673282D

    申请日:1970-05-15

    Applicant: MONSANTO CO

    Inventor: BAER MASSIMO

    CPC classification number: C08F259/00 Y10S525/902 C08F214/00

    Abstract: There is disclosed a process for the preparation of copolymers of a vinyl halide and a long-chain aliphatic vinyl monomer. In accordance with the process, an aqueous dispersion is formed of a preformed vinyl halide polymer, a vinyl halide monomer and a long-chain aliphatic ether monomer capable of copolymerizing with the vinyl halide monomer. Copolymerization of said monomers in the presence of the aqueous dispersion of the preformed polymer leads to a polymeric particle whose shell contains a major proportion of the polymeric long-chain aliphatic ether monomer and whose core is essentially devoid of this monomer. This preferential concentration of a lubricating monomer on the outer shell of the particle leads to greatly improved flow with only a minor loss in glass temperature.

    Abstract translation: 公开了一种制备乙烯基卤化物和长链脂肪族乙烯基单体的共聚物的方法。 根据该方法,水分散体由预先形成的乙烯基卤聚合物,乙烯基卤单体和能够与卤代乙烯单体共聚的长链脂族醚单体形成。 所述单体在预成型聚合物的水分散体存在下的共聚导致聚合物颗粒,其外壳含有主要部分的聚合长链脂族醚单体,其核心基本上不含该单体。 润滑单体在颗粒外壳上的这种优先浓缩导致流动性大大改善,而玻璃温度仅有轻微的损失。

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