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    Preparation of nitroalcohol
    3.
    发明授权
    Preparation of nitroalcohol 失效
    硝基醇的制备

    公开(公告)号：US3560575A

    公开(公告)日：1971-02-02

    申请号：US3560575D

    申请日：1966-09-07

    Applicant: COMMERCIAL SOLVENTS CORP

    Inventor： TINDALL JOHN B

    IPC: C07C205/15 ,  C07C79/18 ,  C07C91/06

    CPC classification number: C07C201/12 ,  C07C205/15

    Abstract: NITROALCOHOLS ARE PRODUCED BY REACTING A NITROPARAFFIN WITH A STOICHIOMETRIC EXCESS OF FORMALDEHYDE, SAID EXCESS BEING FROM ABOUT 5 TO 60% EQUIVALENTS, DEIONIZING THE REACTION PRODUCT THEREOF TO REMOVE THE METAL ION OF SAID CATALYST FRACTIONATING SAID DEIONIZED REACTION PRODUCT WITH METHANOL IN THE PRESENCE OF A MINERAL ACID, TOLUENE SULFONIC ACID OR CATION EXCHANGE RESIN IN AN AMOUNT SUFFICIENT TO CATALYZE THE REACTION OF THE EXCESS OF THE FORMALDEHYDE AND METHANOL, THE METHANOL BEING USED IN AN AMOUNT SUFFICIENT TO REACT WITH THE ALDEHYDE REMAINING IN SAID FRACTIONATED PRODUCT, AND REMOVING THE REACTION PRODUCT OF SAID FORMALDEHYDE AND METHANOL FROM THE RESULTING MIXTURE.

    Ring opening of cyclic nitro ketones
    4.
    发明授权
    Ring opening of cyclic nitro ketones 失效
    环状硝基酮的开环

    公开(公告)号：US4554387A

    公开(公告)日：1985-11-19

    申请号：US604891

    申请日：1984-04-27

    Applicant: Paul D. Seemuth

    Inventor： Paul D. Seemuth

    IPC: C07C201/12 ,  C07C205/15 ,  C07C79/18

    CPC classification number: C07C201/12

    Abstract: Macrocyclic ring opening reaction. The 2-nitro cycloalkan-1-ones and similar 2-nitro heterocyclic compounds are ring opened by reduction of the carbonyl oxygen with an anionic species such as NaBH.sub.4. An .alpha.,.omega.-nitro alcohol is recovered.

    Abstract translation: 大环开环反应。 2-硝基环烷-1-酮和类似的2-硝基杂环化合物通过用阴离子物质如NaBH 4还原羰基氧来开环。 回收α，ω-硝基醇。

    Preparation of 2-nitro-2-methyl-1-propanol
    5.
    发明授权
    Preparation of 2-nitro-2-methyl-1-propanol 失效
    2-硝基-2-甲基-1-丙醇的制备

    公开(公告)号：US4241226A

    公开(公告)日：1980-12-23

    申请号：US12440

    申请日：1979-02-15

    Applicant: Guy Adrian ,  Marcel-Xavier Sion ,  Andre Benattar

    Inventor： Guy Adrian ,  Marcel-Xavier Sion ,  Andre Benattar

    IPC: C07C67/00 ,  C07C201/00 ,  C07C205/15 ,  C07C79/18

    CPC classification number: C07C201/12

    Abstract: The known compound 2-nitro-2-methyl-1-propanol is prepared by formylation,n crystalline form of high purity and in high yields, by reacting 2-nitropropane and formaldehyde in a molar ratio between 0.9:1 and 1.1:1, in a concentrated medium and in the presence of 1 to 10 milli-equivalents of an inorganic basic catalyst per mole of 2-nitropropane, with agitation, at a temperature between 40.degree. and 58.degree. C.; the pH of the reaction medium being between 7 and 11.

    Abstract translation: 已知的化合物2-硝基-2-甲基-1-丙醇是通过2-羟基丙烷和甲醛以0.9:1至1.1:1的摩尔比反应，以高纯度和高收率的结晶形式进行甲酰化制备的， 在浓缩介质中，在每摩尔2-硝基丙烷存在1至10毫当量的无机碱性催化剂的情况下，在40至58℃的温度下搅拌。 反应介质的pH在7和11之间。

    Production of nitroalkanols
    6.
    发明授权
    Production of nitroalkanols 失效
    硝基甘油的生产

    公开(公告)号：US3564062A

    公开(公告)日：1971-02-16

    申请号：US3564062D

    申请日：1968-03-15

    Applicant: COMMERCIAL SOLVENTS CORP

    Inventor： TINDALL JOHN B

    IPC: C07C201/12 ,  C07C205/15 ,  C07C79/18 ,  C07C89/00

    CPC classification number: C07C201/12 ,  C07C205/15

    Abstract: A PROCESS FOR THE PRODUCTION OF NITROALKANOLS CORRESPONDING TO THE FORMULA

    R-CH(-NO2)-CH2-OH

    WHERE R IS METHYL, ETHYL OR HYDROXYMETHYL, BY ADDING A MIXTURE OF A PRIMARY NITROALKANE AND FORMALDEHYDE, TO A SUSPENSION OF A CALCIUM OR BARIUM BASE, ADDING THE RESULTING MIXTURE TO AN AQUEOUS SOLUTION CONTAINING AN EXCESS OF CARBON DIOXIDE, SEPARATING THE PRECIPITATED CALCIUM OR BARIUM CARBONATE THEREBY PRODUCING THE NITROALKANOL.

    Production of dibromonitro compound
    8.
    发明授权
    Production of dibromonitro compound 失效
    二溴硝基化合物的生产

    公开(公告)号：US4723044A

    公开(公告)日：1988-02-02

    申请号：US874144

    申请日：1986-06-13

    Applicant: Michio Watanabe ,  Kiyoshi Ishii ,  Mie Namiki ,  Takeshi Fukuda

    Inventor： Michio Watanabe ,  Kiyoshi Ishii ,  Mie Namiki ,  Takeshi Fukuda

    IPC: C07C67/00 ,  C07C201/00 ,  C07C201/12 ,  C07C205/26 ,  C07C79/18

    CPC classification number: C07C201/12 ,  C07C201/16

    Abstract: A process for producing a dibromonitro compound represented by the general formula ##STR1## wherein R represents a hydrogen atom or a methyl group, which comprises condensing nitromethane with formaldehyde or acetaldehyde in the presence of an alkali, the amount of the aldehyde being at least 1.5 moles per mole of nitromethane; and thereafter without isolating the product, treating the reaction mixture with bromine to brominate the product.

    Abstract translation: 一种制备由通式（I）表示的二溴硝基化合物的方法，其中R表示氢原子或甲基，其包括在碱存在下将硝基甲烷与甲醛或乙醛缩合，醛的量为 每摩尔硝基甲烷至少1.5摩尔; 然后不分离产物，用溴处理反应混合物以溴化产物。

    Preparation of nitroalcohols
    9.
    发明授权
    Preparation of nitroalcohols 失效
    硝基醇的制备

    公开(公告)号：US4496772A

    公开(公告)日：1985-01-29

    申请号：US512081

    申请日：1983-07-08

    Applicant: John T. Lai

    Inventor： John T. Lai

    IPC: C07C201/12 ,  C07C205/15 ,  C07C79/18

    CPC classification number: C07C201/12

    Abstract: In a process for preparing a nitroalcohol by reacting a nitroparaffin and an aldehyde in a solvent, the improvement comprising the use of 0.5 to 5 mole percent of a trialkyl phosphine, based on the nitroparaffin, which greatly reduces reaction time to 0.1 to 5 hours.

    Abstract translation: 在通过硝基石蜡和醛在溶剂中反应制备硝基醇的方法中，改进包括使用0.5至5摩尔％的基于硝基石蜡的三烷基膦，其大大减少了0.1至5小时的反应时间。

    Substituted nitroalkyl peroxynitrate
    10.
    发明授权
    Substituted nitroalkyl peroxynitrate 失效
    取代硝基烷基过氧化硝酸盐

    公开(公告)号：US3910987A

    公开(公告)日：1975-10-07

    申请号：US43030574

    申请日：1974-01-02

    Applicant: TEXACO INC

    Inventor： CUMMINGS WILLIAM M

    IPC: C07C205/40 ,  C07C409/40 ,  C10L1/23 ,  C07C77/02 ,  C07C79/18

    CPC classification number: C10L1/231 ,  C07C205/40 ,  C07C409/40 ,  C10M2215/16 ,  C10M2215/202

    Abstract: Nitroalkyl nitrate and peroxynitrates characterized by the formula:

    where R and R1 are hydrogen or alkyl of from 1 to 10 carbons, where X is R2O-, -CN, Cl, phenyl, -ONO2,

    where R2 is alkyl of from 1 to 10 carbons or phenyl and R3 is hydrogen, phenyl or alkyl of from 1 to 10 carbons, and where Y is -OONO2 or -ONO2, said nitroalkyl nitrates being prepared by first contacting a substituted alkene of the formula:

    where R, R1 and X are as heretofore defined with a mixture of dinitrogen tetroxide and oxygen to form substituted nitroalkyl peroxynitrate of the formula:

    where R, R1 and X are as heretofore defined and second contacting said peroxynitrate with a reducing agent to form said substituted nitroalkyl nitrate, the first and second contacting being conducted in the presence of inert liquid. The nitroalkyl nitrate final products of the invention are useful as fuel additives to increase power output of petroleum distillates such as gasoline and kerosene. Further, they are useful as intermediates in the preparation of surfactants, fuel and lubricant additives, insecticides, fungicides (e.g. controlling early blight in bean plants), pharmaceuticals and polymers.

    Abstract translation: 硝基硝基硝酸盐和过氧硝酸盐，其特征在于以下结构式：Y | R-CH-C-CH 2 -NO 2 || XR1其中R和R 1是氢或1至10个碳的烷基，其中X是R 2 O-，-CN，Cl，苯基 ，其中R 2是1至10个碳的烷基或苯基且R 3是氢，苯基或1至10个碳的烷基，并且其中Y是-OONO 2 或-ONO 2，所述硝基烷基硝酸盐是通过首先使下式的取代烯与R-CH-C = CH 2 || XR1接触而制备的，其中R，R 1和X如前面所定义，与四氧化二氮和氧的混合物形成取代的 硝基烷基过氧化硝酸盐，其具有下式：OONO 2 | R-CH-C-CH 2 NO 2 || XR1其中R，R 1和X如前所定义，并且使所述过硝酸盐与还原剂接触以形成所述取代的硝基烷基硝酸盐，第一和第二接触是 在惰性液体存在下进行。 本发明硝酸烷基硝酸盐最终产品可用作燃料添加剂以增加石油馏出物如汽油和煤油的功率输出。 此外，它们可用作制备表面活性剂，燃料和润滑剂添加剂，杀虫剂，杀真菌剂（例如控制豆类植物中的早疫病），药物和聚合物的中间体。

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