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    Sulphonation of phenols
    1.
    发明申请
    Sulphonation of phenols 失效
    酚的磺化

    公开(公告)号：US20050054876A1

    公开(公告)日：2005-03-10

    申请号：US10490361

    申请日：2002-09-18

    申请人： Jonathan Hill ,  Bernard Capai ,  Carlo Neri

    发明人： Jonathan Hill ,  Bernard Capai ,  Carlo Neri

    IPC分类号： C07C303/08 ,  C07C309/42 ,  C07C309/44 ,  C07C309/00

    CPC分类号： C07C303/08 ,  C07C309/42 ,  C07C309/44

    摘要： A process for the preparation of sulphonated phenols of general formula (I) where R1 is hydrogen, a C1-C20 alkyl group which is unsubstituted or substituted by halogen, cyano, hydroxyl, C1-C20 alkoxy, C2-C20 alkoxycarbonyl, acyloxy and/or phenyl which is unsubstituted or substituted by C1-C4 alkyl, C1-C4 alkoxy and/or halogen, R2 is hydrogen, C1-C20 alkyl or benzoyl of general formula (II) where R3 and R4 independently of one another are each hydrogen, halogen, C1-C12 alkyl, C1-C12 alkoxy, C1-C4 haloalkyl, C3-C8 cycloalkyl, C4-C12 cycloalkylalkyl, cyano, hydroxyl, or hydroxyethyl or are each phenoxy, C7-C10 phenylalkyl or phenyl which is unsubstituted or substituted by C1-C4 alkyl, C1-C4 alkoxy and/or halogen, and R5 is hydrogen or the group SO3X where X can be hydrogen, a monovalent metal or a group —N(R6)3, where each of the three radicals R6 can be independently of one another hydrogen, C1-C6 alkyl or C1-C6 hydroxy alkyl, which process comprises reacting a phenol of general formula (III) where R1 and R2 are as defined above, with a halosulphonic acid in a solvent which is a mixture of a C5-C10 aliphatic or cycloaliphatic hydrocarbon and a dialkyl carbonate of general formula (IV) R7—O—CO—O—R8 where R7 and R8 each represent independently a C1-C4 alkyl group.

    摘要翻译： 制备通式（I）的磺化酚的方法，其中R 1为氢，未被取代或被卤素，氰基，羟基，C 1 -C 20烷氧基，C 2 -C 20烷氧基羰基，酰氧基和/或C 1 -C 20烷氧基取代的C 1 -C 20烷基， 或未被取代或被C 1 -C 4烷氧基和/或卤素取代的苯基，R 2是氢，通式（II）的C 1 -C 20烷基或苯甲酰基，其中R 3和R 4彼此独立地为氢， 卤素，C 1 -C 12烷基，C 1 -C 12烷氧基，C 1 -C 4卤代烷基，C 3 -C 8环烷基，C 4 -C 12环烷基烷基，氰基，羟基或羟乙基，或者各自为苯氧基，未被取代或被 C1-C4烷基，C1-C4烷氧基和/或卤素，R5是氢或X3可以是氢的基团SO3X，一价金属或基团-N（R6）3，其中三个基团R6可以是 独立于氢，C 1 -C 6烷基或C 1 -C 6羟基烷基，该方法包括使通式为酚 （III）其中R 1和R 2如上所定义，与卤代磺酸在溶剂中是C5-C10脂族或脂环族烃和通式（Ⅳ）的二烷基碳酸酯的混合物，R7-O-CO-O- R8，其中R7和R8各自独立地表示C1-C4烷基。

    Continuous process for the production of acyloxybenzenesulfonic acids
    3.
    发明授权
    Continuous process for the production of acyloxybenzenesulfonic acids 失效
    用于生产酰氧基苯磺酸的连续方法

    公开(公告)号：US4803015A

    公开(公告)日：1989-02-07

    申请号：US922275

    申请日：1986-10-23

    申请人： Werner Wellbrock ,  Adolf Studeneer

    发明人： Werner Wellbrock ,  Adolf Studeneer

    IPC分类号： C07C309/42 ,  C07C20060101 ,  C07C67/00 ,  C07C301/00 ,  C07C303/06 ,  C07C303/08 ,  C07C309/28 ,  C07C143/90

    CPC分类号： C07C309/00

    摘要： A process for the continuous production of C.sub.7 -Cl.sub.2 -acyloxybenzenesulfonic acids, wherein phenol and a sulfonating reagent, diluted with an aliphatic C.sub.7 -Cl.sub.2 -carboxylic acid, is charged to the top of a continuous-flow reactor heated to 80.degree.-100.degree. and the mixture of phenolsulfonic acid and the aliphatic carboxylic acid, leaving the bottom end of this continuous-flow reactor, and a chlorinating reagent are charged to the top of a second continuous-flow reactor, nitrogen being passed in counter-current through both continuous-flow reactors.

    摘要翻译： 将连续生产C7-Cl2-酰氧基苯磺酸的方法，其中将用脂肪族C 7 -C 12羧酸稀释的苯酚和磺化试剂装入加热至80℃-100℃的连续流动反应器的顶部 并将留下该连续流动反应器的底端的苯酚磺酸和脂族羧酸的混合物和氯化试剂装入第二连续流动反应器的顶部，使氮气逆流通过两个连续流 流反应堆。

    Process for reducing sulfur-containing contaminants in sulfonated hydrocarbons
    4.
    发明授权
    Process for reducing sulfur-containing contaminants in sulfonated hydrocarbons 失效
    减少磺化烃中含硫污染物的方法

    公开(公告)号：US4677074A

    公开(公告)日：1987-06-30

    申请号：US622921

    申请日：1984-06-21

    申请人： Thomas F. Holden ,  Albert F. Baumann

    发明人： Thomas F. Holden ,  Albert F. Baumann

    IPC分类号： C07C67/00 ,  C07C301/00 ,  C07C303/06 ,  C07C303/08 ,  C07C303/32 ,  C07C303/42 ,  C10L1/24 ,  C10L10/08 ,  C10M135/10 ,  C10M159/24 ,  C10N30/04 ,  C10N40/25 ,  C01B17/50 ,  C01C1/24 ,  C07B45/02 ,  C07C143/24

    CPC分类号： C07C303/42 ,  C10L1/2437 ,  C10M135/10 ,  Y10S516/03

    摘要： Processes of reducing the inorganic sulfur-containing acid and the low equivalent weight organic sulfonic acid content of an acid mass comprising organic sulfonic components and inorganic sulfonating agent contaminants are described. In general, the process comprises the steps of(a) treating the acid mass with ammonia in the presence of water to neutralize the acids in said acid mass and to form a mixture containing the ammonium salts of said acids.(b) allowing separation of the mixture to provide a lower aqueous phase containing water-soluble ammonium salts and an upper phase comprising the oleophilic alcohol and ammonium salts of the organic sulfonic acids, and(c) recovering at least a portion of said upper phase.The efficiency of the reduction of undesirable materials from the acid mass can be increased by subjecting the recovered upper phase to additional water extractions in the presence of the oleophilic alcohol.The ammonium salts of the organic sulfonic acids recovered by the above process can be converted to oil-soluble metal salts by reacting said ammonium salts with a basically reacting metal compound in such amounts and under such conditions as to form metal salts of said organic sulfonic acids. The metals salts prepared in this manner may be neutral metal salts or highly basic metal salts. The neutral and metal basic salts are useful in a variety of applications including lubricants and fuels.

    摘要翻译： 描述了包含有机磺酸组分和无机磺化剂污染物的酸性物质的还原无机含硫酸和低当量有机磺酸含量的方法。 通常，该方法包括以下步骤：（a）在水存在下用氨处理酸性物质以中和酸性物质中的酸，并形成含有所述酸的铵盐的混合物。 （b）允许分离混合物以提供含有水溶性铵盐的下层水相和包含有机磺酸的亲油醇和铵盐的上层，和（c）回收至少一部分所述上相 。 可以通过在亲油醇的存在下使回收的上相进行额外的水提取来增加从酸性物质中减少不需要的物质的效率。 通过上述方法回收的有机磺酸的铵盐可以通过使所述铵盐与基本上反应的金属化合物反应，以这样的量和在这样的条件下形成所述有机磺酸的金属盐来转化为油溶性金属盐 。 以这种方式制备的金属盐可以是中性金属盐或高碱性金属盐。 中性和金属碱性盐可用于各种应用，包括润滑剂和燃料。

    Process for the production of 2-amino-1-naphthalenesulfonic acid
    6.
    发明授权
    Process for the production of 2-amino-1-naphthalenesulfonic acid 失效
    2-氨基-1-萘磺酸的制备方法

    公开(公告)号：US4510100A

    公开(公告)日：1985-04-09

    申请号：US559149

    申请日：1983-12-07

    申请人： Eric Plattner ,  Sebastian Staubli ,  Fred von Kaenel

    发明人： Eric Plattner ,  Sebastian Staubli ,  Fred von Kaenel

    IPC分类号： C07C309/47 ,  C07C67/00 ,  C07C301/00 ,  C07C303/08 ,  C07C303/32 ,  C07C143/60

    CPC分类号： C07C309/00

    摘要： The invention relates to an improved process for the production of 2-amino-1-naphthalenesulfonic acid (Tobias acid). This improved process makes it possible to obtain Tobias acid which has only a very low content of 2-aminonaphthalene and in high space-time yield. The process starts from 2-hydroxynaphthalene and comprises the following main reaction steps:(a) the sulfonation of 2-hydroxynaphthalene to 2-hydroxynaphthalene-1-sulfonic acid (oxy-Tobias acid) with chlorosulfonic acid, in an inert organic solvent;(b) the neutralization of the liberated hydrochloric acid and excess chlorosulfonic acid still present in the reaction medium and conversion of the 2-hydroxynaphthalene-1-sulfonic acid obtained into the corresponding ammonium salt with ammonia;(c) conversion of the 2-hydroxy group into the 2-amino group by the Bucherer reaction; and(d) the subsequent precipitation of the Tobias acid with dilute sulfuric acid.

    摘要翻译： 本发明涉及一种生产2-氨基-1-萘磺酸（托比亚酸）的改进方法。 这种改进的方法使得可以获得仅具有非常低的2-氨基萘含量和高空时收率的托比亚酸。 该方法从2-羟基萘开始，包括以下主要反应步骤：（a）在惰性有机溶剂中用氯磺酸将2-羟基萘磺化为2-羟基萘-1-磺酸（氧 - 托比酸）; （b）中和反应介质中仍然存在的游离的盐酸和过量的氯磺酸，并将得到的2-羟基萘-1-磺酸转化为相应的铵盐与氨; （c）通过Bucherer反应将2-羟基转化为2-氨基; 和（d）随后用稀硫酸沉淀托比亚酸。

    Phenol phosphorus compounds as polyolefin stabilizers
    7.
    发明授权
    Phenol phosphorus compounds as polyolefin stabilizers 失效
    酚类磷化合物作为聚烯烃稳定剂

    公开(公告)号：US4246170A

    公开(公告)日：1981-01-20

    申请号：US4612

    申请日：1979-01-18

    申请人： Samuel Evans

    发明人： Samuel Evans

    IPC分类号： C07C67/00 ,  C07C69/96 ,  C07C301/00 ,  C07C301/02 ,  C07C303/06 ,  C07C303/08 ,  C07C303/24 ,  C07C305/22 ,  C07C325/00 ,  C07C329/00 ,  C07C329/04 ,  C07F9/08 ,  C07F9/12 ,  C07F9/145 ,  C07F9/32 ,  C07F9/40 ,  C07F9/48 ,  C08K5/00 ,  C08K5/10 ,  C08K5/13 ,  C08K5/36 ,  C08K5/51 ,  C08K5/52 ,  C08L23/00 ,  C08L101/00 ,  C09K15/08 ,  C09K15/14 ,  C09K15/32

    CPC分类号： C09K15/322 ,  C07C301/02 ,  C07C305/24 ,  C07C323/16 ,  C07C329/04 ,  C07F9/12 ,  C07F9/145 ,  C07F9/4075 ,  C07F9/4084 ,  C07F9/4875 ,  C08K5/005 ,  C08K5/51 ,  C09K15/14

    摘要： Phenols of the formula I ##STR1## wherein n has a value from 1 to 15,each of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently is a hydrogen atom, a C.sub.1 - .sub.18 -alkyl group, an aryl group, a C.sub.5 -C.sub.12 -cycloalkyl group or a C.sub.7 -C.sub.13 -aralkyl group,R.sub.5 is a hydrogen atom or a C.sub.1 -C.sub.18 -alkyl group,Y is a carbonyl, thiocarbonyl, sulphinyl, sulphonyl, -P(OR.sub.7)-, -P(.dbd.O) (OR.sub.7)-, -P(.dbd.O) (R.sub.7)- or -P(R.sub.7)- group, andR.sub.6 is a radical --CHR.sub.8 --CHR.sub.9 --S--CR.sub.10 R.sub.11 R.sub.12, wherein each of R.sub.8 and R.sub.9 independently is a hydrogen atom or a C.sub.1 -C.sub.6 -alkyl group, R.sub.10 is a hydrogen atom, a C.sub.1 -C.sub.19 -alkyl group, a C.sub.2 -C.sub.4 -alkenyl group or an aryl group, R.sub.11 is a hydrogen atom or a methyl group and R.sub.12 is a hydrogen atom or a methyl group, or, if R.sub.11 is a hydrogen atom, is a C.sub.2 -C.sub.6 -alkyl group, or, if R.sub.10 is a hydrogen atom, R.sub.11 and R.sub.12 together with the carbon atom to which they are attached represent a cycloalkyl group, or R.sub.10, R.sub.11 and R.sub.12 together with the carbon atom to which they are attached represent an aryl group, or if Y is a thiocarbonyl, sulphinyl or sulphonyl group,R.sub.6 can also be a hydrogen atom or a C.sub.1 -C.sub.18 -alkyl group or an aryl group, andR.sub.7 is a hydrogen atom, a C.sub.1 -C.sub.18 -alkyl group or an aryl group,as stabilizers for organic material.

    摘要翻译： 式I的苯酚（1）其中n具有1至15的数值，R 1，R 2，R 3和R 4各自独立地为氢原子，C 1 -C 18 - 烷基，芳基，C 5 -C 12 - 环烷基或C 7 -C 13 - 芳烷基，R 5为氢原子或C 1 -C 18烷基，Y为羰基，硫代羰基，亚磺酰基，磺酰基，-P（OR 7） - ， - P（= O）（OR 7） - ， - P（= O）（R 7） - 或-P（R 7） - 基团，R 6是基团-CHR 8 -CHR 9 -S-CR 10 R 11 R 12，其中R 8和R 9各自独立地为氢 原子或C1-C6-烷基，R10是氢原子，C1-C19 - 烷基，C2-C4-烯基或芳基，R11是氢原子或甲基，R12是氢 或者如果R 11为氢原子，则为C2-C6-烷基，或者，如果R10为氢原子，则R11和R12与它们所连接的碳原子一起代表环烷基 ，或R 10，R 11和R 12与它们所连接的碳原子一起表示芳基，或者如果Y是硫代羰基，则硫 正丁基或磺酰基，R 6也可以是氢原子或C 1 -C 18烷基或芳基，R 7是氢原子，C 1 -C 18烷基或芳基作为有机材料的稳定剂。

    Organic polyisocyanates
    8.
    发明授权
    Organic polyisocyanates 失效
    有机多异氰酸酯

    公开(公告)号：US4144267A

    公开(公告)日：1979-03-13

    申请号：US527473

    申请日：1974-11-26

    申请人： Dieter Dieterich ,  Peter Markusch

    发明人： Dieter Dieterich ,  Peter Markusch

    IPC分类号： C08G18/00 ,  C07C67/00 ,  C07C241/00 ,  C07C265/14 ,  C07C301/00 ,  C07C303/06 ,  C07C303/08 ,  C07C303/32 ,  C07C309/28 ,  C07C309/45 ,  C07C309/72 ,  C08G18/08 ,  C08G18/77 ,  C07C143/24 ,  C08F18/24 ,  C08G63/12

    CPC分类号： C08G18/0828 ,  C08G18/775

    摘要： Aromatic polyisocyanates containing sulphonic acid or sulphonate groups which are substantially free from crystalline product and a method for making them are provided wherein a mixture of aromatic polyisocyanates having an isocyanato content of from about 10% to about 42% by weight is sulphonated, the improvement which comprises mixing and reacting liquid aromatic polyisocyanates having a viscosity of from about 8 cP to about 49 cP at 25.degree. C. and containing at least 40% by weight of phosgenation products of an aniline-phosgenation condensate and at least about 20% by weight of 2,6-tolylene diisocyanate, 2,4'-diphenylmethane diisocyanate, 2,2'-diphenylmethane diisocyanate or a mixture thereof, based on the weight of said liquid aromatic polyisocyanates with a sulphonating agent in an amount equivalent to from about 0.1% to about 40% by weight sulphur trioxide, based on the weight of said liquid aromatic polyisocyanates.

    摘要翻译： 提供含有基本上不含结晶产物的磺酸或磺酸盐基团的芳族多异氰酸酯及其制备方法，其中将异氰酸酯基含量为约10重量％至约42重量％的芳族多异氰酸酯的混合物磺化， 包括在25℃下粘度为约8cP至约49cP的液体芳族聚异氰酸酯混合和反应，并含有至少40重量％的苯胺 - 光气化缩合物的光气化产物和至少约20重量％ 2,6-二甲苯二异氰酸酯，2,4'-二苯基甲烷二异氰酸酯，2,2'-二苯基甲烷二异氰酸酯或其混合物，基于所述液体芳族聚异氰酸酯与磺化剂的重量，其量相当于约0.1％ 约40重量％的三氧化硫，基于所述液体芳族聚异氰酸酯的重量。