Odor free hydroxymethanesulfonic acid
    2.
    发明授权
    Odor free hydroxymethanesulfonic acid 失效
    无气味的羟丙基磺酸

    公开(公告)号:US3878123A

    公开(公告)日:1975-04-15

    申请号:US40497973

    申请日:1973-10-10

    Applicant: US AGRICULTURE

    Abstract: The preparation of odorless hydroxymethanesulfonic acid by reaction of equivalent amounts of sulfurous acid and paraformaldehyde is disclosed. This sulfur dioxide odor free sulfurous acid based substance is an excellent catalyst for the treatment of cellulose with N-methylol-type finishing agents to produce durable press properties. Its use offers several advantages over the use of hydroxymethanesulfonic acid prepared in situ in the pad bath by addition of sulfurous acid to react with the free formaldehyde present. Exact quantities of the catalyst can be dispensed and workers are not exposed to the discomfort and health hazard of the choking, noxious fumes of sulfur dioxide that are given off by sulfurous acid.

    Abstract translation: 公开了通过等量的亚硫酸和多聚甲醛反应制备无味羟基甲磺酸。 这种无二氧化硫气味的亚硫酸基物质是用N-羟甲基型整理剂处理纤维素以产生耐久冲压性能的优异催化剂。 其使用提供了优于使用通过加入亚硫酸与游离甲醛存在反应而在垫浴中原位制备的羟基甲磺酸的优点。 可以分配精确量的催化剂,并且工人不会受到窒息的不适和健康危害,由亚硫酸释放的二氧化硫的有害烟雾。

    Surface-active compounds of the sulfobetaines family, their manufacture
and use, particularly for enhanced oil recovery
    4.
    发明授权
    Surface-active compounds of the sulfobetaines family, their manufacture and use, particularly for enhanced oil recovery 失效
    磺基甜菜碱家族的表面活性化合物,其制备和用途,特别是用于提高采收率

    公开(公告)号:US4704229A

    公开(公告)日:1987-11-03

    申请号:US767402

    申请日:1985-08-20

    CPC classification number: C07D265/08 C09K8/584 Y10S507/938 Y10S516/912

    Abstract: New surface-active compounds of the sulfobetaines group are manufactured. They comply with the general formula: ##STR1## wherein each of R.sub.1, R.sub.2 and R.sub.3 is substantially a hydrocarbon radical, each of R.sub.4 and R.sub.5 is a hydrogen atom or substantially a hydrocarbon radical and R.sub.6 is a hydrogen atom or a hydrocarbon radical, R.sub.1 to R.sub.6 radicals containing together from 12 to 30 carbon atoms, n is an integer equal to 2 to 3, Z may be a CH.sub.3 radical or a hydroxy group, p may be 0 or 1 with, when Z is a hydroxy group and p is equal to 1, a value of 1 for m and for q; when Z is a methyl radical, with a value of 1 for p, a value of 2 for m and a value of 0 or 1 for q and, when p=0, a value of 2, 3 or 4 for the sum (m+q).These new surfactants are useful in enhanced oil recovery as micellar systems consisting of aqueous solutions and microemulsions.

    Abstract translation: 制备磺基甜菜碱基团的新的表面活性化合物。 它们符合以下通式:其中R 1,R 2和R 3各自基本上是烃基,R 4和R 5各自为氢原子或基本上烃基,R 6为氢原子或烃基,R 1 包含含有12至30个碳原子的R6基团,n是等于2至3的整数,Z可以是CH 3基或羟基,当Z是羟基时,p可以是0或1,p是 等于1,m和q的值为1; 当Z是甲基时,对于p,值为1,对于m,值为2,对于q,值为0或1,当p = 0时,对于和(m)为2,3或4 + q)。 这些新的表面活性剂可用于强化油回收,因为由水溶液和微乳液组成的胶束体系。

    Purification of sodium isethionate
    8.
    发明授权
    Purification of sodium isethionate 失效
    纯化羟乙基磺酸钠

    公开(公告)号:US4003925A

    公开(公告)日:1977-01-18

    申请号:US586323

    申请日:1975-06-12

    CPC classification number: C07C303/42

    Abstract: Glycol impurities in aqueous sodium isethionate solutions are readily removed by extraction with an aliphatic alcohol containing three to four carbon atoms. The use of the purified sodium isethionate results in improved processing of detergent bars containing coconut acyl isethionate prepared by direct esterification of sodium isethionate with coconut fatty acids.

    Abstract translation: 通过用含有3至4个碳原子的脂肪醇萃取,可容易地除去羟乙磺酸钠水溶液中的二醇杂质。 纯化的羟乙基磺酸钠的使用导致通过使用椰子脂肪酸直接酯化羟乙基磺酸钠而制备的含有椰子酰基羟乙基磺酸盐的洗涤剂棒的加工。

    Improved process for the preparation of ethoxylated isethionates
    10.
    发明授权
    Improved process for the preparation of ethoxylated isethionates 失效
    改进乙氧基异丁酸盐的制备方法

    公开(公告)号:US3823185A

    公开(公告)日:1974-07-09

    申请号:US37089973

    申请日:1973-06-18

    Inventor: SCHLOSSMAN I

    CPC classification number: C07C303/02 C08G65/2636 C07C309/10

    Abstract: A PROCESS IS PROVIDED WHEREBY IMPROVEMENT OF THE PRODUCTION OF ETHOXYLATED ISETHIONATES IN AN AQUEOUS MEDIUM IS ACHIEVED. IN THIS IMPROVED PROCESS THE SELECTIVITY OF ETHYLENE OXIDE TO THE DESIRED ETHOXYLATED PRODUCTS IS SIGNIFICANTLY INCREASED BY REMOVAL OF ALL OR A SUBSTANTIAL PART OF THE WATER PRESENT IN THE EARLY STAGES OF THE REACTION AFTER A SMALL AMOUNT OF ETHYLENE OXIDE HAS REACTED. ADDITIONALLY, ETHOXYLATED ISETHIONATES HAVING FROM ABOUT 2 TO ABOUT 30 ETHYLENE OXIDE REPEATING UNITS AND CONTAINING LESS THAN 25% UNDESIRABLE GLYCOL-ETHER BY-PRODUCTS ARE PROVIDED.

Patent Agency Ranking