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    Production process for glycidyl ether adduct and catalyst used for the process
    1.
    发明申请
    Production process for glycidyl ether adduct and catalyst used for the process 审中-公开
    用于该方法的缩水甘油醚加合物和催化剂的制备方法

    公开(公告)号：US20040077904A1

    公开(公告)日：2004-04-22

    申请号：US10649701

    申请日：2003-08-28

    Applicant: Kao Corporation

    Inventor： Atsushi Nagasawa ,  Mitsuru Uno ,  Tomohito Kitsuki

    IPC: B01J023/02 ,  B01J023/06 ,  C07C041/03

    CPC classification number: C11D1/72 ,  B01J21/10 ,  B01J23/002 ,  B01J23/06 ,  B01J2523/00 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/27

    Abstract: Provided is a catalyst for adding a glycidyl ether to an active hydrogen-containing organic compound, comprising a complex oxide of magnesium and at least one element other than magnesium selected from the group consisting of the elements in the third period and the fourth period in the periodic table. Also provided is a process for producing a glycidyl ether adduct, which comprises subjecting an active hydrogen-containing organic compound and a glycidyl ether to an addition reaction in the presence of the above-mentioned catalyst. In the addition reaction between the active hydrogen-containing organic compound and the glycidyl ether, use of the catalyst of the present invention enables inhibition of an excess addition reaction of the glycidyl ether which is a successive reaction, and a mono- or di-(alkyl, alkenyl or phenyl) ether product in which one or two glycidyl ethers are added is selectively produced by adjusting the mole ratio of the active hydrogen-containing organic compound to the glycidyl ether to a specific range. Accordingly, the mono- or di-(alkyl, alkenyl or phenyl) ether product can be obtained at a high productivity with a high purity.

    Abstract translation: 提供了一种用于向含活性氢的有机化合物中加入缩水甘油醚的催化剂，其包含镁和至少一种除镁以外的元素的复合氧化物，所述复合氧化物选自第三周期和第四周期中的元素组 周期表。 还提供了一种制备缩水甘油醚加合物的方法，其包括在上述催化剂存在下使含活性氢的有机化合物和缩水甘油醚进行加成反应。 在含活性氢的有机化合物和缩水甘油醚之间的加成反应中，使用本发明的催化剂可以抑制作为连续反应的缩水甘油醚的过量加成反应，以及单 - 或二 烷基，烯基或苯基）醚产物，其中加入一个或两个缩水甘油醚是通过将含活性氢的有机化合物与缩水甘油醚的摩尔比调整到特定范围来选择性地制备的。 因此，可以以高纯度的高生产率获得单 - 或二 - （烷基，烯基或苯基）醚产物。

    Desulfurization process and novel bimetallic sorbent systems for same
    3.
    发明申请
    Desulfurization process and novel bimetallic sorbent systems for same 有权
    脱硫工艺和新型双金属吸附剂体系相同

    公开(公告)号：US20030166465A1

    公开(公告)日：2003-09-04

    申请号：US10347915

    申请日：2003-01-21

    Inventor： Gyanesh P. Khare

    IPC: B01J023/00 ,  B01J023/72 ,  B01J023/74 ,  B01J023/70 ,  B01J023/06 ,  B01J023/48 ,  B01J023/50 ,  B01J020/02 ,  B01J020/10 ,  B01J020/06

    CPC classification number: C10G25/003 ,  Y10S502/517

    Abstract: Novel sorbent systems for the desulfurization of cracked-gasoline and diesel fuels are provided which are comprised of a bimetallic promotor on a particulate support such as that formed of zinc oxide and an inorganic or organic carrier. Such bimetallic promotors are formed of at least two metals of the group consisting of nickel, cobalt, iron, manganese, copper, zinc, molybdenum, tungsten, silver, tin, antimony and vanadium with the valence of same being reduced, preferably to zero. Processes for the production of such sorbents are provided wherein the sorbent is prepared from impregnated particulate supports or admixed to the support composite prior to particulation, drying, and calcination. Further disclosed is the use of such novel sorbents in the desulfurization of cracked-gasoline and diesel fuels whereby there is achieved not only removal of sulfur but also an increase in the olefin retention in the desulfurized product. Such sorbents can also be utilized for the treatment of other sulfur-containing streams such as diesel fuels.

    Abstract translation: 提供用于裂化汽油和柴油燃料脱硫的新型吸附剂系统，其由诸如由氧化锌和无机或有机载体形成的颗粒载体上的双金属促进剂组成。 这样的双金属促进剂由镍，钴，铁，锰，铜，锌，钼，钨，银，锡，锑和钒中的至少两种金属形成，其价态被还原，优选为零。 提供了用于生产这种吸附剂的方法，其中吸附剂由浸渍的颗粒载体制备，或在颗粒化，干燥和煅烧之前与载体复合材料混合。 进一步公开的是使用这种新型吸附剂在裂化汽油和柴油燃料的脱硫中，由此不仅实现硫的去除，而且脱硫产物中的烯烃保留量也增加。 这种吸附剂也可用于处理其它含硫物流如柴油燃料。

    Hydrogen sulfide-suppressing catalyst compositions
    4.
    发明申请
    Hydrogen sulfide-suppressing catalyst compositions 有权
    硫化氢抑制催化剂组合物

    公开(公告)号：US20030158037A1

    公开(公告)日：2003-08-21

    申请号：US10079450

    申请日：2002-02-20

    Applicant: ENGELHARD CORPORATION

    Inventor： John S. Foong ,  Harold N. Rabinowitz

    IPC: B01J023/58 ,  B01J023/02 ,  B01J023/06

    CPC classification number: B01D53/945 ,  B01J23/58 ,  B01J23/63 ,  B01J37/0244 ,  B01J37/0248 ,  F01N3/2803 ,  Y02T10/22

    Abstract: Hydrogen sulfide formation is suppressed by a three-way conversion catalyst having an underlayer and a topcoat overlying the under layer. The under layer is prepared by dispersing a Group IIa metal oxide such as an oxide of magnesium, calcium, barium or strontium on a carrier such as a refractory metal oxide monolith. A topcoat overlying the undercoat is comprised of a three-way conversion catalyst material such as a platinum-group metal catalytic component, e.g., platinum, palladium, rhodium or mixtures thereof.

    Abstract translation: 通过具有覆盖在下层上的底层和顶涂层的三元转化催化剂抑制硫化氢形成。 通过将诸如镁，钙，钡或锶的氧化物的IIa族金属氧化物分散在诸如难熔金属氧化物整料的载体上来制备底层。 覆盖底涂层的面漆由三元转化催化剂材料如铂族金属催化组分如铂，钯，铑或其混合物组成。

    Catalyst for decomposition of hydrocarbons, process for producing the catalyst, and process for producing hydrogen using the catalyst
    5.
    发明申请
    Catalyst for decomposition of hydrocarbons, process for producing the catalyst, and process for producing hydrogen using the catalyst 有权
    用于烃分解的催化剂，用于制备催化剂的方法，以及使用该催化剂生产氢的方法

    公开(公告)号：US20040209773A1

    公开(公告)日：2004-10-21

    申请号：US10783021

    申请日：2004-02-23

    Applicant: Tada Kogyo Corporation

    Inventor： Naoya Kobayashi ,  Shinji Takahashi

    IPC: B01J023/02 ,  B01J023/06

    CPC classification number: B01J35/023 ,  B01J23/007 ,  B01J23/78 ,  B01J35/0006 ,  B01J35/006 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/03 ,  B01J37/088 ,  C01B3/40 ,  C01B2203/0233 ,  C01B2203/1041 ,  C01B2203/1052 ,  C01B2203/1082 ,  C01B2203/1241 ,  Y02P20/52

    Abstract: A catalyst for decomposition of hydrocarbons, comprises porous oxide particles containing magnesium and aluminum, and fine metallic nickel particles which are present in the vicinity of surface of the respective porous oxide particles, and have an average particle diameter of 1 to 10 nm, said catalyst having a nickel content of 0.15 to 12% by weight based on the weight of the catalyst and a molar ratio of nickel to a sum of magnesium, nickel and aluminum of 0.001 to 0.12 in which a molar ratio of magnesium to aluminum (Mg:Al) is 4:1 to 1.5:1. The catalyst for decomposition of hydrocarbons, is capable of maintaining as small a particle size of metallic nickel particles as not more than 10 nm at a considerably reduced nickel content, and exhibits an excellent anti-coking property even under a low steam atmosphere.

    Abstract translation: 用于烃分解的催化剂包括含有镁和铝的多孔氧化物颗粒和存在于各个多孔氧化物颗粒表面附近的平均粒径为1至10nm的细金属镍颗粒，所述催化剂 镍的含量相对于催化剂的重量为0.15〜12重量％，镍与镁，镍和铝的摩尔比为0.001〜0.12，其中镁与铝的摩尔比（Mg：Al ）为4:1至1.5:1。 用于烃分解的催化剂能够以显着降低的镍含量将金属镍颗粒的粒径保持为不大于10nm，即使在低蒸气气氛下也显示出优异的抗焦化性。

    Photocatalytic hydrophilifiable material
    9.
    发明申请
    Photocatalytic hydrophilifiable material 审中-公开
    光催化亲水化材料

    公开(公告)号：US20010036897A1

    公开(公告)日：2001-11-01

    申请号：US09772048

    申请日：2001-01-29

    Inventor： Kazuya Tsujimichi ,  Hiroto Hasuo ,  Hideki Kobayashi

    IPC: B01D053/34 ,  B01J023/06 ,  B01J023/02 ,  B01J023/04 ,  B32B018/00

    CPC classification number: B01J21/063 ,  B01J21/06 ,  B01J21/066 ,  B01J23/16 ,  B01J23/40 ,  B01J23/70 ,  B01J35/0006 ,  B01J35/002 ,  B01J35/004 ,  B01J37/0217 ,  Y10T428/2993 ,  Y10T428/31

    Abstract: In a formulation comprising titanium dioxide as a photocatalyst and an amphoteric metal oxide (alumina or the like) or a basic metal oxide (barium oxide, strontium oxide or the like) as a material having a base point, when a nitrogen oxide (nitrogen monoxide) comes into contact with or approaches titanium dioxide, upon exposed to light, the carbon monoxide is oxidized to nitrogen dioxide (gas) by hydroxy radicals as an active oxygen species produced by titanium dioxide. As is apparent from the molecular structure, nitrogen dioxide is an acidic gas, alumina is an amphoteric metal oxide, and barium oxide and strontium oxide are a basic metal oxide. The oxygen atom thereof serves as a base point to an acid gas. Therefore, nitrogen dioxide is attracted and chemically bonded to the oxygen atom, held on the metal oxide, and kept close to titanium dioxide as the photocatalyst.

    Abstract translation: 在作为光催化剂的二氧化钛和作为具有碱点的材料的两性金属氧化物（氧化铝等）或碱性金属氧化物（氧化钡，氧化锶等）的配方中，当氮氧化物 ）与二氧化钛接触或接触二氧化钛，暴露于光时，一氧化碳被羟基自由基氧化成二氧化氮（气体），作为二氧化钛产生的活性氧。 从分子结构可以看出，二氧化氮是酸性气体，氧化铝是两性金属氧化物，氧化钡和氧化锶是碱性金属氧化物。 其氧原子作为酸性气体的基点。 因此，二氧化氮被吸引并化学键合到保持在金属氧化物上的氧原子上，并保持接近二氧化钛作为光催化剂。

    Catalyst for ester production and process for producing ester
    10.
    发明申请
    Catalyst for ester production and process for producing ester 有权
    用于酯生产的催化剂和用于生产酯的方法

    公开(公告)号：US20040242917A1

    公开(公告)日：2004-12-02

    申请号：US10294606

    申请日：2002-11-15

    Applicant: CHISSO CORPORATION

    Inventor： Kanichiro Inui ,  Takayoshi Takahashi ,  Toru Kurabayashi

    IPC: B01J023/06 ,  C07C069/52 ,  C07C069/02

    CPC classification number: B01J21/066 ,  B01J23/72 ,  B01J23/80 ,  B01J23/868 ,  B01J37/03 ,  B01J37/18 ,  C07C67/39 ,  C07C67/40 ,  C07C69/14

    Abstract: A catalyst for ester production which comprises zirconium oxide, copper, and at least one oxide selected from the group consisting of zinc oxide, chromium oxide, aluminum oxide and silicon oxide, and is obtainable by reducing with hydrogen a catalyst precursor prepared by the reaction of a salt containing at least one of metals constituting the oxides, a zirconium salt and a copper salt with an alkali hydroxide; and a process for producing an ester which comprises bringing either an alcohol or an alcohol and an aldehyde into contact with this catalyst in a gas phase.

    Abstract translation: 一种用于酯生产的催化剂，其包含氧化锆，铜和至少一种选自氧化锌，氧化铬，氧化铝和氧化硅的氧化物，并且可以通过用氢还原通过以下方法制备的催化剂前体： 含有构成氧化物的金属中的至少一种的盐，与碱金属氢氧化物的锆盐和铜盐的盐; 以及一种制备酯的方法，其包括使醇或醇和醛在气相中与该催化剂接触。

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