Process and apparatus for decontaminating exhaust gas from a fusion
reactor fuel cycle of exhaust gas components containing chemically
bonded tritium and/or deuterium
    2.
    发明授权
    Process and apparatus for decontaminating exhaust gas from a fusion reactor fuel cycle of exhaust gas components containing chemically bonded tritium and/or deuterium 失效
    用于从包含化学键合的氚和/或氘的废气组分的聚变反应堆燃料循环中净化废气的方法和装置

    公开(公告)号:US4774065A

    公开(公告)日:1988-09-27

    申请号:US19985

    申请日:1987-02-27

    CPC classification number: G21F9/02 G21B1/115

    Abstract: Process for decontaminating an exhaust gas from a fusion reactor fuel cycle of exhaust gas components containing at least one heavy hydrogen isotope selected from tritium and deuterium in compound form, the compound form being ammonia and hydrocarbon, the exhaust gas containing CO and hydrogen isotopes and in which the at least one heavy hydrogen isotope is liberated from its compound, separated out from the exhaust gas and fed back into the fuel cycle, comprising(a) carrying out a catalytic oxidation reaction at a temperature of from 200.degree. C. to 250.degree. C., to oxidize the exhaust gas components, without changing the ammonia, as follows: CO to CO.sub.2, hydrocarbon to CO.sub.2 +water, and the hydrogen isotopes to water,(b) bringing the gas admixture resulting from step (a) into contact with a metal bed at a temperature in the range of 200.degree. C. to 400.degree. C. to selectively transform the water into hydrogen isotopes and to remove O.sub.2,(c) bringing the gas admixture resulting from step (b) ino contact with a hot membrane made of palladium or a palladium-silver alloy to crack the ammonia at a temperature of 400.degree. C. to 450.degree. C., and to pass all liberated hydrogen isotopes through the membrane to separate out the liberated hydrogen isotopes from the flow of the remaining exhaust gas, and(d) discharging the remaining decontaminated exhaust gas into the surrounding air.

    Abstract translation: 从含有至少一种选自氚和氘的至少一种重氢同位素的废气组分的聚合反应堆燃料循环中净化废气的方法,化合物形式为氨和烃,所述废气含有CO和氢同位素,并且在 其中所述至少一种重氢同位素从其化合物中释放出来,从废气中分离并反馈到燃料循环中,包括(a)在200℃至250℃的温度下进行催化氧化反应 在不改变氨的情况下氧化废气组分如下:CO至CO 2,烃与CO 2 +水和氢同位素至水,(b)将由步骤(a)得到的气体混合物接触 用金属床在200℃至400℃的温度范围内选择性地将水转化为氢同位素并除去O 2,(c)将由步骤(b)得到的气体混合物 与由钯或钯 - 银合金制成的热膜接触,在400℃至450℃的温度下裂解氨,并将所有释放的氢同位素通过膜,以将释放的氢同位素从 剩余废气的流动,和(d)将剩余的净化废气排放到周围的空气中。

    Apparatus for removal and recovery of tritium from light and heavy water
    3.
    发明授权
    Apparatus for removal and recovery of tritium from light and heavy water 失效
    用于从轻质和重水中去除和回收氚的设备

    公开(公告)号:US4190515A

    公开(公告)日:1980-02-26

    申请号:US907105

    申请日:1978-05-18

    Abstract: A method and apparatus for removing tritium from heavy water and light water comprising contacting tritiated feed water in a catalyst column in countercurrent flow with hydrogen gas originating from an electrolysis cell so as to enrich this feed water with tritium from the electrolytic hydrogen gas and passing the tritium enriched water to an electrolysis cell wherein the electrolytic hydrogen gas is generated and then fed upwards through the catalyst column. The tritium content of the hydrogen gas leaving the top of the enricher catalyst column is further reduced in a stripper column containing catalyst which transfers the tritium to a countercurrent flow of liquid water.

    Abstract translation: 一种用于从重水和轻水中除去氚的方法和装置,其包括将来自电解槽的氢气与逆流流动的催化剂塔中的氚化进料水与来自电解槽的氢气接触,以使来自电解氢气的氚浓缩, 将富含氚的水加到电解池中,其中产生电解氢气,然后向上通过催化剂塔。 离开富集催化剂塔顶部的氢气的氚含量在含有催化剂的汽提塔中进一步降低,催化剂将氚转移到逆流的液态水流中。

    Method and a device for purifying a gas containing hydrogen isotopes
    7.
    发明授权
    Method and a device for purifying a gas containing hydrogen isotopes 失效
    用于纯化含有氢同位素的气体的方法和装置

    公开(公告)号:US4867762A

    公开(公告)日:1989-09-19

    申请号:US200148

    申请日:1988-05-26

    CPC classification number: G21F9/08 G21B1/115 Y02C10/08

    Abstract: The invention concerns a method and a device for purifying a gas containing hydrogen isotopes, and for recovering the different isotopes, in particular for treating a gas coming from a thermonuclear fusion reactor. According to the invention, the gas is firstly dried in a water and CO.sub.2 adsorption stage (2), the dried gas then passes through a stage (3) in which a selective adsorption of sulphur compounds takes place and finally, the gas leaving this stage, which still contains at least some of the compounds (H,D,T).sub.2, N.sub.2, O.sub.2, CO, C(H,D,T).sub.4, is processed in a hydrogen adsorption/separation stage (4) of the zeolite type.

    Abstract translation: 本发明涉及用于净化含有氢同位素的气体并用于回收不同同位素的方法和装置,特别是用于处理来自热核聚变反应器的气体。 根据本发明,气体首先在水和CO 2吸附阶段(2)中干燥,然后干燥的气体通过其中发生硫化合物的选择性吸附的阶段(3),最后,离开该阶段的气体 ,其还含有至少一些化合物(H,D,T)2,N 2,O 2,CO,C(H,D,T)4,在沸石的氢吸附/分离阶段(4) 类型。

    DETRITIATION DEVICE AND METHOD
    10.
    发明申请
    DETRITIATION DEVICE AND METHOD 审中-公开
    检测装置和方法

    公开(公告)号:US20140044624A1

    公开(公告)日:2014-02-13

    申请号:US14113129

    申请日:2012-04-23

    CPC classification number: G21F9/308 G21B1/115 G21F9/007 G21F9/02 G21F9/28 G21F9/30

    Abstract: The invention relates to a detritiation device comprising i) a furnace (1) for melting tritiated waste, said furnace comprising a hearth for receiving tritiated waste and a bubbling device for introducing a hydrogenated bubbling gas into the hearth during the melting and treatment of the tritiated waste in the furnace (1), and ii) a catalytic reactor with a quadrupole membrane (2) for treating the gas resulting from the melting and treatment of the tritiated waste in the furnace (1), said reactor comprising a membrane (20) for separating two flows of gas, the membrane (20) being permeable to the hydrogen isotopes. The invention also relates to an associated detritiation method.

    Abstract translation: 本发明涉及一种除渣装置,包括:i)用于熔化氚化废物的炉子(1),所述炉子包括用于接收氚化废物的炉膛和用于在熔融和处理氚化废物的过程中将氢化鼓泡气体引入炉膛的鼓泡装置 在炉(1)中的废物,和ii)具有四极膜(2)的催化反应器,用于处理由熔融和处理炉(1)中的氚化废物产生的气体,所述反应器包括膜(20) 为了分离两个气体流,膜(20)对氢同位素是可渗透的。 本发明还涉及相关的脱粒方法。

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