Abstract:
The present invention relates to a method for liquefying hydrogen, the method comprises the steps of: cooling a feed gas stream comprising hydrogen with a pressure of at least 15 bar(a) to a temperature below the critical temperature of hydrogen in a first cooling step yielding a liquid product stream. According to the invention, the feed gas stream is cooled by a closed first cooling cycle with a high pressure first refrigerant stream comprising hydrogen, wherein the high pressure first refrigerant stream is separated into at least two partial streams, a first partial stream is expanded to low pressure, thereby producing cold to cool the precooled feed gas below the critical pressure of hydrogen, and compressed to a medium pressure, and wherein a second partial stream is expanded at least close to the medium pressure and guided into the medium pressure first partial stream.
Abstract:
A liquefier system includes: a feed line configured to feed a raw material gas from a raw material supply source such that a pressure of the raw material gas in a predetermined portion of the feed line is kept higher than or equal to a predetermined pressure; a cooling medium circulation line configured to cause a cooling medium to circulate; a static pressure gas bearing configured to be supplied with the gas that has a pressure higher than or equal to the predetermined pressure and to rotatably support a rotating shaft of an expansion turbine; and a bearing supply line configured to connect the predetermined portion of the feed line and a gas inlet of the static pressure gas bearing, such that the gas is supplied to the static pressure gas bearing.
Abstract:
A liquefier system includes: a feed line configured to feed a raw material gas from a raw material supply source such that a pressure of the raw material gas in a predetermined portion of the feed line is kept higher than or equal to a predetermined pressure; a cooling medium circulation line configured to cause a cooling medium to circulate; a static pressure gas bearing configured to be supplied with the gas that has a pressure higher than or equal to the predetermined pressure and to rotatably support a rotating shaft of an expansion turbine; and a bearing supply line configured to connect the predetermined portion of the feed line and a gas inlet of the static pressure gas bearing, such that the gas is supplied to the static pressure gas bearing.
Abstract:
A raw material gas liquefying device includes a feed line which feeds a raw material gas, a refrigerant circulation line which circulates a refrigerant, the refrigerant circulation line including an expansion unit of a turbine type which expands the refrigerant to generate cryogenic energy, and an expansion unit entrance valve provided at an entrance side of the expansion unit, a heat exchanger which exchanges heat between the raw material gas and the refrigerant, a cooler which performs initial cooling of the raw material gas and the refrigerant by heat exchange with liquid nitrogen, and a controller which manipulates the opening rate of the expansion unit entrance value and performs a feedback control so that the rotation speed of the expansion unit reaches a predetermined target value, and outputs the opening rate command to the expansion unit entrance valve, at start-up and stop of the expansion unit.
Abstract:
A raw material gas liquefying device includes a feed line; a refrigerant circulation line; and a controller. In a refrigerant liquefaction route, a refrigerant flows through a compressor, a heat exchanger, a circulation system JT valve, a liquefied refrigerant storage tank, and the heat exchanger, and returns to the compressor. In a cryogenic energy generation route, the refrigerant flows through the compressor, the heat exchanger, an expansion unit, and the heat exchanger, and returns to the compressor. The controller determines if a refrigerant storage tank liquid level is within an allowable range, manipulates a feed system JT valve opening rate to control refrigerant temperature at the high-temperature-side refrigerant flow path exit side of the heat exchanger, and manipulates the opening rate of the feed system JT valve to control the refrigerant storage tank liquid level so that the refrigerant storage tank liquid level falls into the predetermined allowable range.
Abstract:
The boil-off gas discharged from a liquid hydrogen storage tank on a liquid hydrogen transport vessel (16) is introduced into the liquid hydrogen stored within liquid hydrogen storage tanks (19, 20) disposed on the ground by passing through a boil-off gas introduction path (17). At least a portion of the boil-off gas is re-liquefied by means of the cold temperature of the liquid hydrogen. The boil-off gas that was not re-liquefied and the gasified hydrogen generated as a consequence of the liquid hydrogen within the liquid hydrogen storage tanks (19, 20) gasifying are mixed with raw material hydrogen by being supplied to the raw material hydrogen path (11) of a liquid hydrogen production device (HS) by passing through a gasified hydrogen discharge path (21). The boil-off gas and the gasified hydrogen are re-liquefied by means of the liquid hydrogen production device (HS).
Abstract:
The invention relates to a process for liquefying hydrogen. To reduce the specific energy consumption, the following process steps are used: a) the precooling of the hydrogen stream by indirect heat exchange against a pressurized LNG stream to a temperature of between 140 and 130 K, b) the precooling of the hydrogen stream by indirect heat exchange against a coolant to a temperature of between 85 and 75 K, c) where the precooling of the coolant takes place against a pressurized LNG stream, and d) the cooling and at least partial liquefaction of the precooled hydrogen stream takes place by indirect heat exchange against another hydrogen stream channeled through a closed cooling circuit, e) where the precooling of the condensed hydrogen stream, which is channeled through a closed cooling circuit, takes place against a pressurized LNG stream.
Abstract:
The present invention discloses a hydrogen or helium throttling liquefaction system using direct current (DC) flow from the cold and hot ends of the regenerative cryocoolers, which belongs to the technical field of refrigeration and cryogenics. It includes a regenerative cryocooler module, a hot-end DC flow module, a cold-end DC flow module, a throttling liquefaction module, and a gas-phase circulation module. The modules are interconnected to form a closed loop for the flow of hydrogen or helium working fluid. DC flow is introduced from the cold and hot ends of the regenerative cryocooler through the DC flow pipelines and DC flow valves. The hot-end DC flow exchanges heat with the reflowing low-temperature working fluid and is cooled down. After that, it mixes with the cold-end DC flow and enters the throttling liquefaction module to generate liquid phase through throttling and liquefaction. After the liquid phase has output cooling capacity, it flows through the gas-phase circulation module and then enters the back-pressure chamber of the compressor to complete the cycle. Compared with the existing small-scale hydrogen and helium liquefaction technology using regenerative cryocoolers, the present invention has the advantages of simple structure, easy installation, high heat transfer efficiency and liquefaction efficiency of the system.
Abstract:
Disclosed is a device for refrigerating or liquefying a fluid such as natural gas or hydrogen, comprising a circuit for fluid that is to be cooled and has an upstream end for connection to a source of gaseous fluid and a downstream end for connection to a member for collecting the cooled or liquefied fluid, the device comprising a heat exchanger assembly in heat exchange with the circuit of fluid to be cooled, the device comprising a refrigerator in heat exchange with at least a portion of the heat exchanger assembly, the refrigerator being of the type that has a cycle for refrigerating a cycle gas containing at least one of: helium, hydrogen, nitrogen or neon; said refrigerator comprising, arranged in series in a cycle circuit: a mechanism for compressing the cycle gas, at least one member for coding the cycle gas, a mechanism for expanding the cycle gas, and at least one member for reheating the expanded cycle gas, wherein the compression mechanism comprises a plurality of compression stages in series composed of a centrifugal compressor assembly, the compression stages being mounted on a set of shafts rotated by an assembly of one or more motors, the at least one member for cooling the cycle gas comprising at least one heat exchanger arranged at the outlet of at least one compression stage in heat exchange with the cycle circuit, said heat exchanger being cooled by a heat-transfer fluid, characterized in that the compression mechanism comprises at least two compression stages that are arranged successively in series and do not include any member for cooling the cycle gas such as a heat exchanger therebetween.