摘要:
Quaternized azo dyes made by coupling an appropriate diazotized benzenoid base with an N-dialkylaminoalkylene [.alpha.(N-alkylanilino)] m- or p-toluenesulfonamide. Quaternization of the pendant dialkylamino group of the coupling component is carried out before or after coupling. The water soluble quaternary azo dyes are especially useful for coloring acrylic fibers.
摘要:
Azo dyes for dyeing polyester fabric are made by coupling an appropriate diazotized amino heterocyclic base into an .alpha.-(N-alkylanilino)-m-toluene sulfonamide, typified by .alpha.-(N-ethyl anilino)-m-toluene sulfonamide. This class of azo dye, when appropriately dispersed, produces dyeings on aromatic polyester fabrics with excellent substantivity, outstanding sublimation fastness, and good fastness to light. The dyes are applied to polyesters, such as polyethylene terephthalate, by carrier dyeing, pressure dyeing, and thermofixation methods.
摘要:
The present invention relates to disperse azo dyes based on a phthalimido-substituted aniline coupling component and an aromatic-carbocyclic or an aromatic-heterocyclic diazo component, to a process for the preparation of such dyes and to their use in the dyeing or printing of semi-synthetic and, especially, synthetic hydrophobic fiber materials, more especially textile materials.
摘要:
The invention provides an azo metal chelate dye suitable for use in a recording layer of an optical recording medium capable of high-speed recording or an optical recording medium having plural recording layers, and an optical recording medium. The azo metal chelate dye comprises an azo dye compound represented by general formula (1) and a metal: (wherein R1 represents a linear or branched alkyl group that may be substituted or a cycloalkyl group that may be substituted; R2 and R3 each independently represents a hydrogen atom, a linear or branched alkyl group that may be substituted, an aryl group that may be substituted, or a heterocyclic group that may be substituted; R4, R5, R6, R7, and R8 each independently represents a hydrogen atom or a linear or branched alkyl group that may be substituted, and R4 and R5, R4 and R6, or R5 and R7 may be bonded to each other to form a ring; Y represents a linear or branched alkyl group substituted with at least two fluorine atoms; and the chelate dye is constituted of the compound represented by general formula (1) from which a proton is released, and the metal).
摘要:
The dyestuffs of the formula ##STR1## in which D is the radical of a diazo component,SO.sub.2 X is the radical of a fibre-reactive group,and the remaining substituents have the meaning given in the descriptionare suitable for dyeing and printing hydroxyl- and amido-containing materials.
摘要:
Basic azo dyes are made by coupling an appropriate diazotized benzenoid or heterocyclic base with an N-dialkylaminoalkylene ( Alpha (N-alkylanilino))m- or p-toluenesulfonamide. Quarternization of the pendant dialkylamino group in the coupler may be carried out before or after coupling if desired to yield quaternary structures. The unquaternized structures, when properly dispersed, are applied to polyesters with excellent substantivity, outstanding fastness to sublimation and good fastness to light. The disperse unquaternized dyes are applied to polyacrylonitrile fabrics from a neutral or acidic bath; the water soluble quaternary structures are especially useful for coloring acrylic fibers.
摘要:
The present invention relates to disperse azo dyes based on a phthalimido-substituted aniline coupling component and an aromatic-carbocyclic or an aromatic-heterocyclic diazo component, to a process for the preparation of such dyes and to their use in the dyeing or printing of semi-synthetic and, especially, synthetic hydrophobic fibre materials, more especially textile materials.
摘要:
The invention provides an azo metal chelate dye suitable for use in a recording layer of an optical recording medium capable of high-speed recording or an optical recording medium having plural recording layers, and an optical recording medium. The azo metal chelate dye comprises an azo dye compound represented by the general formula (1) and Zn2+: (wherein R1 represents a linear or branched alkyl group that may be substituted, or a cycloalkyl group that may be substituted; Y represents a linear or branched alkyl group substituted with at least two fluorine atoms; R2, R3, R4, R5 and R6 each independently represents a hydrogen atom or a linear or branched alkyl group that may be substituted, and R3 and R4, R4 and R5, or R5 and R6 may be bonded with each other to form a ring; and a proton is released from the compound of formula (1) to form the chelate dye together with Zn2+).
摘要:
Disclosed are azo compounds having the formula ##STR1## in which R.sup.4 is straight or branched lower alkylene, Z is 1-3 groups selected from such heteroatom groups as --OH, lower alkanoyloxy, lower alkoxy, lower alkoxycarbonyl, lower alkoxyalkoxy, mono- or dialkylamino, --CN, carbamoyl, formamide, lower alkyl substituted carbamoyl, lower alkoxycarbonylamino, lower alkanoylamino, hydroxy substituted lower alkoxy, halogen, lower alkylthio, lower alkylsulfonyl, and various heterocyclic groups such as furyl and pyrrolidono, R is selected from straight or branched lower alkyl, phenyl and phenyl substituted with straight or branched lower alkyl, halogen, or straight or branched lower alkoxy, R.sup.2 is hydrogen or lower alkyl, and A is an aniline, tetrahydroquinoline, or benzomorpholine coupler component which may be substituted with a wide variety of groups. These azo compounds produce red to blue shades on polyamide, polyester and cellulose acetate fibers and exhibit markedly improved properties such as fastness and dyeability, particularly on synthetic polyamide fibers.
WHEREIN R12 IS HYDROGEN, AMINO, LOWER ALKANOYLAMINO OR LOWER ALKYLSULFONAMIDO; R13 IS HYDROGEN, LOWER ALKYL, PHENYL OR PHENYL SUBSTITUTED WITH LOWER ALKYL, LOWER ALKOXY OR HALOGEN; R14 IS HYDROGEN, LOWER ALKYL, LOWER ALKOXY, HALOGEN, NITRO, LOWER ALKYLSULFONYL, CYANO OR THIOCYANATO; X IS -O-, -S-, OR -NH-; R5 IS HYDROGEN, CHLORINE, BROMINE, CYANO OR NITRO; R6 IS NITRO, LOWER ALKYLSULFONYL, CYANO, CHLORINE, BROMINE, SULFAMOYL, OR PHENYLAZOL; AND R7 IS HYDROGEN, CHLORINE, BROMINE, NITRO, FORMYL, LOWER ALKANOYL, LOWER ALKOXYCARBONYL, TRIFLUOROMETHYL, LOWER ALKYLSULFONYL, CYANO, SULFAMOYL, OR CARBAMOYL.
(=N-(1,2-PHENYLENE(-R14))-X-)>C-
2-R13-1,3,4-OXADIAZOL-5-YL, OR
2-R12-1,3,4-THIADIAZOL-5-YL,
WHEREIN A IS ACYLAMIDE SELECTED FROM FORMYL; LOWER ALKANOYL; LOWER ALKANOYL SUBSTITUTED WITH HALOGEN, CYANO, LOWER ALKOXY, HYDROXY, LOWER ALKYLSULFONYL, OR PHENYL; BENZOYL; BENZOYL SUBSTITUTED WITH LOWER ALKYL, LOWER ALKOXY OR HALOGEN; CYCLOHEXYLCARBONYL; LOWER ALKOXYCARBONYL; LOWER ALKOXYCARBONYL SUBSTITUTED WITH HYDROXY OR CYANO; PHENOXYCARBONYL; PHENOXYCARBONYL SUSTITITUTED WITH LOWER ALKYL, LOWER ALKOXY OR HALOGEN; LOWER ALKYLSULFONYL; LOWER ALKYLSULFONYL SUBSTITUTED WITH CYANO, HY DROXY OR HALOGEN; PHENYLSULFONYL; PHENYLSULFONYL SUBSTITUTED WITH LOWER ALKYL, LOWER ALKOXY, OR HALOGEN; CARBAMOYL; LOWER ALKYLCARBAMOYL; DI-LOWER ALKYLCARBAMOYL; PHENYLCARBAMOYL; PHENYLCARBAMOYL SUBSTITUTED WITH LOWER ALKYL, LOWER ALKOXY OR HALOGEN; OR FUROYL; R1 IS HYDROGEN, LOWER ALKYL, LOWER ALKOXY OR HALOGEN; R2 IS HYDROGEN; LOWER ALKYL; LOWER ALKYL SUBSTITUTED WITH HYDROXY, LOWER ALKOXY, CYANO, LOWER CYANOALKOXY, LOWER ALKANOYLOXY, LOWER ALKOXYCARBONYL, HALOGEN, LOWER ALKANOYLAMINO, CARBAMOYL, LOWER ALKYLCARBAMOYL, PHENYLCARBAMOYLOXY, LOWER ALKYLSULFONYL, LOWER ALKOXYCARBONYLOXY, LOWER ALKYLSULFONAMIDO, PHTHALIMIDO, GLUTARAMIDO, SUCCINIMIDO, PHENOXY, PYRROLIDINONO, PIPERIDINO OR PHTHALIMIDINO; CYCLOHEXYL; LOWER ALKYLCYCLOHEXYL; PHENYL; PHENYL SUBSTITUTED WITH LOWER ALKYL, LOWER ALKOXY, HYDROXY, HALOGEN OR NITRO; ARALKYL IN WHICH THE ALKYL MOIETY CONTAINS 1 TO 2 CARBON ATOMS AND THE ARYL MOIETY IS PHENYL OR PHENYL SUBSTITUTED WITH LOWER ALKYL, LOWER ALKOXY, HALOGEN, HYDROXY, CYANO OR LOWER ALKOXYCARBONYL; OR THE GROUP -R3-S-R4; R3 IS LOWER ALKYLENE OR LOWER ALKYLENE SUBSTITUTED WITH HYDROXY, LOWER ALKOXY, HALOGEN OR LOWER ALKANOYLOXY; AND R4 IS A GROUP HAVING THE FORMULA: