摘要:
MONOAZO COMPOUNDS CONTAINING A SUBSTITUTED PHENYL DIAZO COMPONENT AND AN N,N-DI-ARALKYL-ANILINE COUPLING COMPONENT IN WHICH A RING CARBON ATOM OF THE ANILINE COUPLING COMPONENT BEARS AN ACYLAMIDO GROUP. THE MONOAZO COMPOUNDS ARE USEFUL AS DYES FOR POLYESTER TEXTILE MATERIALS.
摘要:
MONOAZO COMPOUNDS HAVING A 2-CYANO-4,6-DINITROPHENYL DIAZO COMPONENT AND A 2-AMINO-4-ARYL-5-THIAZOLYL COUPLING COMPONENT PRODUCE BLUE TO GREEN SHADES ON POLYESTER TEXTILE MATERIALS AND EXHIBIT GOOD FASTNESS AND DYEABILITY PROPERTIES.
摘要:
Polyester fibers are dyed bright, fast yellow to blue shades with a monoazo compound containing a substituted phenyl diazo component and an N,N-di-aralkyl-m-acylamidoaniline coupling component.
IN WHICH T IS A DISPERSE DYE 1,3,4-THIADIAZOL-2-YL OR 1,3,5THIADIAZOL-2-YL DIAZO COMPONENT; R1 IS ARYL; R2 IS HYDROGEN, ALKYL, CYANOALKYL, UNSUBSTITUTED OR SUBSTITUTED CARBAMOYLALKYL OR ACYLAMIDOALKYL; AND R3 IS HYDROGEN ALKL, ALKOXY OR HALOGEN. THE COMPOUNDS ARE USEFUL FOR DYEING CELLULOSE ACETATE, POLYESTER AND, ESPECIALLY. POLYAMIDE FIBERS ON WHICH THE COMPOUNDS PRODUCE YELLOW TO ORANGE SHADES AND EXHIBIT GOOD DYEABILITY AND FASTNESS TO LIGHT AND WASHING.
摘要:
AZO COMPOUNDS USEFUL AS DYES FOR POLYESTER TEXTILE MATERIALS HAVE AN ANILINE OR A 1,2,3,4-TETRAHYDROQUINOLINE COUPLING COMPONENT AND A 2-THIAZOLYL DIAZO COMPONENT WHICH, AT THE 5-POSITION IS SUBSTITUTED WITH A GROUP HAVING THE FORMULA
N*C-C(-X)=CH-
IN WHICH X IS A SUBSTITUENT SUCH AS CYANO, ALKOXYCARBONYL, ALKYLSULFONUL, OR CARBAMOYL. THE AZO COMPOUNDS PRODUCE BLUE SHADES ON POLYESTER FIBERS AND EXHIBIT IMPROVED FASTNESS TO LIGHT AND SUBLIMATION.
摘要:
AZO COMPOUNDS CONSISTING OF A DISPERSE DYE, PHENYL DIAZO COMPONENT AND AN ANILINE COUPLING COMPONENT SUBSTITUTED WITH AN IMIDOALKANOYLAMINO GROUP PRODUCE YELLOW TO BLUE SHADES ON POLYESTER FIBERS AND EXHIBIT EXCELLENT FASTNESS TO LIGHT AND RESISTANCE TO SUBLIMATION.
WHERE A IS A PHENYL OR PHENYL OR PHENYLAZOPHENYL DISPERSE DYE DIAZO COMPONENT; B IS AN ANILINE) NAPHTHYLAMINO, TETRAHYDROQUINOLINE OR INDOLE DISPERSE DYE COUPLING COMPONENT, T IS A 1,2,4-TRIAZOL-3-YL RADICAL AND T IS 1, 2 OR 3 ARE USED IN DYEING CELLULOSE ACETATE POLYESTER AND POLYAMIDE FIBERS IN BRIGHT YELLOW TO BLUE SHADES WHICH ARE DEEP AND LEVEL AND EXCELLENT FASTNESS TO WASHING, CRACKING, LIGHT GAS AND SUBLIMATION.
摘要:
THHIAZOLYL-AZO-TETRAHYDROQUINOLINE COMPOUNDS IN WHICH THE NITROGEN ATOM OF THE TETRAHYDROQUINOLINE COUPLING COMPONENT IS SUBSTITUTED WITH A GROUP HAVING THE FORMULA
-R1-N(-R3)-SO2-R2
WHEREIN R1 IS ALKYLENE AND R2 AND R3 EACH IS ALKYL, CYCLOALKYL OR ARYL. THE DISCLOSED COMPOUNDS ARE USEFUEL FOR DYEING HYDROPHOBIC TEXTILE MATERIALS SUCH AS POLYESTER FIBERS.
WHEREIN R12 IS HYDROGEN, AMINO, LOWER ALKANOYLAMINO OR LOWER ALKYLSULFONAMIDO; R13 IS HYDROGEN, LOWER ALKYL, PHENYL OR PHENYL SUBSTITUTED WITH LOWER ALKYL, LOWER ALKOXY OR HALOGEN; R14 IS HYDROGEN, LOWER ALKYL, LOWER ALKOXY, HALOGEN, NITRO, LOWER ALKYLSULFONYL, CYANO OR THIOCYANATO; X IS -O-, -S-, OR -NH-; R5 IS HYDROGEN, CHLORINE, BROMINE, CYANO OR NITRO; R6 IS NITRO, LOWER ALKYLSULFONYL, CYANO, CHLORINE, BROMINE, SULFAMOYL, OR PHENYLAZOL; AND R7 IS HYDROGEN, CHLORINE, BROMINE, NITRO, FORMYL, LOWER ALKANOYL, LOWER ALKOXYCARBONYL, TRIFLUOROMETHYL, LOWER ALKYLSULFONYL, CYANO, SULFAMOYL, OR CARBAMOYL.
(=N-(1,2-PHENYLENE(-R14))-X-)>C-
2-R13-1,3,4-OXADIAZOL-5-YL, OR
2-R12-1,3,4-THIADIAZOL-5-YL,
WHEREIN A IS ACYLAMIDE SELECTED FROM FORMYL; LOWER ALKANOYL; LOWER ALKANOYL SUBSTITUTED WITH HALOGEN, CYANO, LOWER ALKOXY, HYDROXY, LOWER ALKYLSULFONYL, OR PHENYL; BENZOYL; BENZOYL SUBSTITUTED WITH LOWER ALKYL, LOWER ALKOXY OR HALOGEN; CYCLOHEXYLCARBONYL; LOWER ALKOXYCARBONYL; LOWER ALKOXYCARBONYL SUBSTITUTED WITH HYDROXY OR CYANO; PHENOXYCARBONYL; PHENOXYCARBONYL SUSTITITUTED WITH LOWER ALKYL, LOWER ALKOXY OR HALOGEN; LOWER ALKYLSULFONYL; LOWER ALKYLSULFONYL SUBSTITUTED WITH CYANO, HY DROXY OR HALOGEN; PHENYLSULFONYL; PHENYLSULFONYL SUBSTITUTED WITH LOWER ALKYL, LOWER ALKOXY, OR HALOGEN; CARBAMOYL; LOWER ALKYLCARBAMOYL; DI-LOWER ALKYLCARBAMOYL; PHENYLCARBAMOYL; PHENYLCARBAMOYL SUBSTITUTED WITH LOWER ALKYL, LOWER ALKOXY OR HALOGEN; OR FUROYL; R1 IS HYDROGEN, LOWER ALKYL, LOWER ALKOXY OR HALOGEN; R2 IS HYDROGEN; LOWER ALKYL; LOWER ALKYL SUBSTITUTED WITH HYDROXY, LOWER ALKOXY, CYANO, LOWER CYANOALKOXY, LOWER ALKANOYLOXY, LOWER ALKOXYCARBONYL, HALOGEN, LOWER ALKANOYLAMINO, CARBAMOYL, LOWER ALKYLCARBAMOYL, PHENYLCARBAMOYLOXY, LOWER ALKYLSULFONYL, LOWER ALKOXYCARBONYLOXY, LOWER ALKYLSULFONAMIDO, PHTHALIMIDO, GLUTARAMIDO, SUCCINIMIDO, PHENOXY, PYRROLIDINONO, PIPERIDINO OR PHTHALIMIDINO; CYCLOHEXYL; LOWER ALKYLCYCLOHEXYL; PHENYL; PHENYL SUBSTITUTED WITH LOWER ALKYL, LOWER ALKOXY, HYDROXY, HALOGEN OR NITRO; ARALKYL IN WHICH THE ALKYL MOIETY CONTAINS 1 TO 2 CARBON ATOMS AND THE ARYL MOIETY IS PHENYL OR PHENYL SUBSTITUTED WITH LOWER ALKYL, LOWER ALKOXY, HALOGEN, HYDROXY, CYANO OR LOWER ALKOXYCARBONYL; OR THE GROUP -R3-S-R4; R3 IS LOWER ALKYLENE OR LOWER ALKYLENE SUBSTITUTED WITH HYDROXY, LOWER ALKOXY, HALOGEN OR LOWER ALKANOYLOXY; AND R4 IS A GROUP HAVING THE FORMULA:
摘要:
R1, R2, R3, R4, R5 AND R6 ARE THE USUAL DYESTUFF SUBSTITUENTS. THE COMPOUNDS ARE PARTICULARLY USEFUL FOR DYEING POLYAMIDE FIBERS BRIGHT RED TO BLUISH-RED SHADES AND ON WHICH THE COMPOUNDS EXHIBIT IMPROVED FASTNESS TO LIGHT AND CROCKING AND IMPROVED MIGRATION PROPERTIES.
MONOAZO COMPOUNDS HAVING A 2-BENZOTHIAZOLYL DIAZO COMPONENT AND AN ANILINE OR TETRAHYDROQUINOLINE COUPLING COMPONENT IN WHICH THE NITROGEN ATOM OF THE COUPLING COMPONENT BEARS A CARBOXYLIC ACYLAMIDOALKYL GROUP OF THE FORMULA