Abstract:
The present invention provides a method for producing an aqueous carbodiimide having excellent crosslinking reactivity with a crosslinking group, such as an alcoholic hydroxy group of an aqueous resin. The method for producing an aqueous carbodiimide-containing liquid includes a step (1) of mixing an isocyanate group-containing carbodiimide (A), a terminal blocking agent, and at least one organic metal compound selected from an organic titanium compound, an organic zirconium compound, and an organic aluminum compound and allowing them to react with each other, to obtain a terminal-blocked carbodiimide (B) in which the isocyanate group is blocked with the terminal blocking agent; and a step (2) of dissolving or dispersing the terminal-blocked carbodiimide (B) in an aqueous solvent, to obtain an aqueous carbodiimide-containing liquid, wherein the terminal blocking agent contains a hydrophilic compound (X) having a functional group having reactivity with the isocyanate group and a hydrophilic group other than the functional group.
Abstract:
A powder coating composition which comprises at least one solid resin and at least one polyisocyanate compound having an average of at least two isocyanate groups per molecule, in a weight ratio of from 99 : 1 to 30 : 70 is provided. The composition has excellent storage stability and affords a coating film with excellent properties.
Abstract:
Inorganic-organic compositions obtained from a mixture of components comprising:A. from 5-98% by weight of an organic polyisocyanateB. from 2-95% by weight of an aqueous alkali metal silicate solution containing about 20-70% by weight of said alkali metal silicateC. from 0-93% by weight of a water-binding component andD. from 1-30% by weight of a halogen or phosphorus containing compound,Based on the total weight of (a), (b), (c) with the proviso that when (c) is 0-20% by weight (a) contains 2-200 milliequivalents of ionic groups per 100 grams of said polyisocyanate. The products of the invention may be used in many forms including both porous and non-porous products as surface coatings having good adhesion and resistance to abrasion, as a mortar, and as a foam concrete for making molded products particularly in construction engineering and civil engineering as for building walls, igloos, road building and the like.
Abstract:
Liquid organic polyisocyanates containing carboxyl and/or carboxylate groups are prepared by reacting liquid multicomponent mixtures of aromatic polyisocyanates having an isocyanato content of about 10 to about 20% by weight and a viscosity of about 8 cP to about 10,000 cP at 25.degree.C withA. a compound which contains carboxylate groups and hydrogen atoms which are reactive with isocyanate groups; orB. a hydroxycarboxylic or mercaptocarboxylic acid, wherebyBa. at least partial conversion of the carboxyl group into the corresponding carboxylate group by neutralization with a base is carried out simultaneously with or after the isocyanate addition reaction orBb. the hydroxycarboxylic acid or mercaptocarboxylic acid is of the kind in which the carboxyl groups are much less reactive with the isocyanate groups than are the hydroxyl or mercapto groups, the quantitative proportion of the reactants being so chosen that the products of the process have an isocyanate content of 10 to 40% by weight and a carboxyl or carboxylate group content of 0.1 to 10% by weight. The polyisocyanates can be used to make inorganic-organic plastics.
Abstract:
STABILIZED LIQUID NON-POLYMERIC FOAM PRECURSORS ARE PRODUCED WHEN FLUORINE SUBSTITUTED ALKANES BOILING ABOVE 60*F. ARE ADDED TO A LIQUID NON-POLYMERIC FOAM PRECURSOR PREPARED BY MIXING A POLYFUNCTIONAL AROMATIC CARBOXYLIC ACID DERIVATIVE WITH A LIQUID POLYARYLPOLYISOCYANATE. THESE FOAM PRECURSORS ARE REACTED WITH A POLYOL HAVING A MOLECULAR WEIGHT BELOW 2,000 AND CONTAINING AT LEAST THREE HYDROXYL GROUPS. THE RESULTING FOAMS PRODUCED ARE USEFUL FOR INSULATION OF WALLS, FOR FIREPROOFING BUILDINGS AND THE LIKE.
Abstract:
The invention relates to novel compositions for coating purposes comprising(A) polyvinyl plastisols,(B) surface modified, finely divided, stabilized polyisocyanates with retarded reactivity, in which 0.1 to 25 equivalents-% of the isocyanate groups of the unstabilized polyisocyanate have been deactivated on the surface, preferably by a reaction with polyamines, hydrazine, alkylhydrazines, polyhydrazide compounds and/or selected amidine and/or guanidine compounds; and(C) plasticizers and/or lightly branched, relatively high molecular weight polyhydroxyl compounds having melting points below 60.degree. C. and compatible with PVC plastisol.The invention also relates to the use of these storage stable but heat curable mixtures as primers for PVC coatings on plastics, foils, textile sheet products or filaments and as primer coats for flocking.
Abstract:
Storage stable heterogeneous systems which may be processed at low temperatures to form polyurethanes are made by mixing a specific quantity of a high molecular weight polyhydroxyl compound with a specified quantity of a 4,4'-diphenyl methane uret dione diisocyanate corresponding to a specified formula or a corresponding modified diisocyanate. A lead and/or tin catalyst is also included.
Abstract:
Inorganic-organic compositions obtained from a mixture of components comprising: (a) from 5-98% by weight of an organic polyisocyanate; (b) from 2-95% by weight of an aqueous alkali metal silicate solution containing about 20-70% by weight of said alkali metal silicate; and (c) from 0-93% by weight of a water-binding component Based on the total weight of (a), (b) and (c) with the proviso that when (c) is 0-20% by weight (a) contains 2-200 milliequivalents of ionic groups per 100 grams of said polyisocyanate. Flexible inorganic-organic plastics which have a low calorific value and improved fire characteristics are prepared from a reaction mixture containing (a) 30 to 70 percent by weight of one or more compounds with Zerewittinoff-active hydrogen atoms which have an average molecular weight of 400 to 6000, preferably 1000 to 6000, and a glass temperature below 10.degree. C, preferably below -20.degree. C; (b) 10 to 30 percent by weight of an organic polyisocyanate; and (c) 20 to 60 percent by weight of an aqueous alkali metal silicate solution which has a solids content of between 30 and 70 percent by weight. The organic polyisocyanate may be one which contains a phenolic hydroxyl group. The products of the invention may be used in many forms including both porous and non-porous products as surface coatings having good adhesion and resistance to abrasion, as a mortar, as a flexible elastomer, and as a foam concrete for making molded products particularly in construction engineering and civil engineering as for building walls, igloos, road buildings and the like.
Abstract:
A process for the preparation of modified N,N'-substituted-2,4,5-triketoimidazolidines which comprises reacting a precondensate having terminal isocyanate groups, prepared by reacting (a) a polybasic carboxylic acid, containing from 4 to 70 carbon atoms and from 2 to 6 carboxyl groups, with an excess of (b) one or more isocyanates or isocyanate forming compounds in the presence of a solvent, with (c) at least one oxamidic ester containing the group NH--CO--CO--OR.sup.v wherein R.sup.v represents an aliphatic hydrocarbon group containing up to 18 carbon atoms, a cycloaliphatic hydrocarbon group containing up to 8 carbon atoms or a mononuclear aromatic hydrocarbon group being unsubstituted or substituted by at least one hydrocarbon group and having a total of up to 14 carbon atoms in the presence of a solvent, a product prepared by said process and a shaped article comprising such a product.