Method for producing aqueous carbodiimide-containing liquid

    公开(公告)号:US11926694B2

    公开(公告)日:2024-03-12

    申请号:US16970831

    申请日:2019-01-18

    CPC classification number: C08G18/8003 C08G18/808 C09D11/102 C09D175/08

    Abstract: The present invention provides a method for producing an aqueous carbodiimide having excellent crosslinking reactivity with a crosslinking group, such as an alcoholic hydroxy group of an aqueous resin. The method for producing an aqueous carbodiimide-containing liquid includes a step (1) of mixing an isocyanate group-containing carbodiimide (A), a terminal blocking agent, and at least one organic metal compound selected from an organic titanium compound, an organic zirconium compound, and an organic aluminum compound and allowing them to react with each other, to obtain a terminal-blocked carbodiimide (B) in which the isocyanate group is blocked with the terminal blocking agent; and a step (2) of dissolving or dispersing the terminal-blocked carbodiimide (B) in an aqueous solvent, to obtain an aqueous carbodiimide-containing liquid, wherein the terminal blocking agent contains a hydrophilic compound (X) having a functional group having reactivity with the isocyanate group and a hydrophilic group other than the functional group.

    Liquid organic polyisocyanates containing carboxyl and/or carboxylate
groups
    4.
    发明授权
    Liquid organic polyisocyanates containing carboxyl and/or carboxylate groups 失效
    含羧基和/或羧酸酯基的液体有机多异氰酸酯

    公开(公告)号:US3959348A

    公开(公告)日:1976-05-25

    申请号:US527389

    申请日:1974-11-26

    Abstract: Liquid organic polyisocyanates containing carboxyl and/or carboxylate groups are prepared by reacting liquid multicomponent mixtures of aromatic polyisocyanates having an isocyanato content of about 10 to about 20% by weight and a viscosity of about 8 cP to about 10,000 cP at 25.degree.C withA. a compound which contains carboxylate groups and hydrogen atoms which are reactive with isocyanate groups; orB. a hydroxycarboxylic or mercaptocarboxylic acid, wherebyBa. at least partial conversion of the carboxyl group into the corresponding carboxylate group by neutralization with a base is carried out simultaneously with or after the isocyanate addition reaction orBb. the hydroxycarboxylic acid or mercaptocarboxylic acid is of the kind in which the carboxyl groups are much less reactive with the isocyanate groups than are the hydroxyl or mercapto groups, the quantitative proportion of the reactants being so chosen that the products of the process have an isocyanate content of 10 to 40% by weight and a carboxyl or carboxylate group content of 0.1 to 10% by weight. The polyisocyanates can be used to make inorganic-organic plastics.

    Abstract translation: 含有羧基和/或羧酸酯基团的液体有机多异氰酸酯是通过使具有约10至约20重量%的异氰酸酯基含量的芳族多异氰酸酯的液体多组分混合物与25℃下的约8cP至约10,000cP的粘度与A 含有与异氰酸酯基团反应的羧酸酯基团和氢原子的化合物; 或B.羟基羧基或邻甲氧基苯甲酸,其中BA。 通过与基质中和的羧基相对于羧酸酯基团的至少部分转化与异氰酸酯添加反应或BB同时进行。 羟基羧基酸或羧甲氧基酸是这样的种类,其中羧酸基团与异羟基化合物没有反应,而不是羟基或甘油聚糖组,反应物的定量比例表明该方法的产物具有异氰酸酯的含量 10-40重量%,羧基或羧酸酯基含量为0.1〜10重量%。 多异氰酸酯可用于制备无机 - 有机塑料。

    Storage stable compositions based on polyvinyl chloride plastisols and
stabilized isocyanates
    6.
    发明授权
    Storage stable compositions based on polyvinyl chloride plastisols and stabilized isocyanates 失效
    基于聚氯乙烯增塑溶胶和稳定的异氰酸酯的储存稳定组合物

    公开(公告)号:US4623686A

    公开(公告)日:1986-11-18

    申请号:US694562

    申请日:1985-01-24

    Abstract: The invention relates to novel compositions for coating purposes comprising(A) polyvinyl plastisols,(B) surface modified, finely divided, stabilized polyisocyanates with retarded reactivity, in which 0.1 to 25 equivalents-% of the isocyanate groups of the unstabilized polyisocyanate have been deactivated on the surface, preferably by a reaction with polyamines, hydrazine, alkylhydrazines, polyhydrazide compounds and/or selected amidine and/or guanidine compounds; and(C) plasticizers and/or lightly branched, relatively high molecular weight polyhydroxyl compounds having melting points below 60.degree. C. and compatible with PVC plastisol.The invention also relates to the use of these storage stable but heat curable mixtures as primers for PVC coatings on plastics, foils, textile sheet products or filaments and as primer coats for flocking.

    Abstract translation: 本发明涉及用于涂覆目的的新型组合物,其包含(A)聚乙烯基增塑溶胶,(B)具有延迟反应性的表面改性,细碎,稳定的多异氰酸酯,其中未稳定的多异氰酸酯的异氰酸酯基团的0.1至25当量已被去活化 表面上优选通过与多胺,肼,烷基肼,聚酰肼化合物和/或选择的脒和/或胍化合物的反应; 和(C)具有熔点低于60℃并与PVC增塑溶胶相容的增塑剂和/或轻支化的相对高分子量的多羟基化合物。 本发明还涉及这些储存稳定但可热固化的混合物作为塑料,箔,纺织品产品或长丝上的PVC涂料的底漆以及用于植绒的底漆涂层的用途。

    Inorganic-organic compositions
    8.
    发明授权
    Inorganic-organic compositions 失效
    无机 - 有机组合物

    公开(公告)号:US4097423A

    公开(公告)日:1978-06-27

    申请号:US527476

    申请日:1974-11-26

    Inventor: Dieter Dieterich

    Abstract: Inorganic-organic compositions obtained from a mixture of components comprising: (a) from 5-98% by weight of an organic polyisocyanate; (b) from 2-95% by weight of an aqueous alkali metal silicate solution containing about 20-70% by weight of said alkali metal silicate; and (c) from 0-93% by weight of a water-binding component Based on the total weight of (a), (b) and (c) with the proviso that when (c) is 0-20% by weight (a) contains 2-200 milliequivalents of ionic groups per 100 grams of said polyisocyanate. Flexible inorganic-organic plastics which have a low calorific value and improved fire characteristics are prepared from a reaction mixture containing (a) 30 to 70 percent by weight of one or more compounds with Zerewittinoff-active hydrogen atoms which have an average molecular weight of 400 to 6000, preferably 1000 to 6000, and a glass temperature below 10.degree. C, preferably below -20.degree. C; (b) 10 to 30 percent by weight of an organic polyisocyanate; and (c) 20 to 60 percent by weight of an aqueous alkali metal silicate solution which has a solids content of between 30 and 70 percent by weight. The organic polyisocyanate may be one which contains a phenolic hydroxyl group. The products of the invention may be used in many forms including both porous and non-porous products as surface coatings having good adhesion and resistance to abrasion, as a mortar, as a flexible elastomer, and as a foam concrete for making molded products particularly in construction engineering and civil engineering as for building walls, igloos, road buildings and the like.

    Abstract translation: 由组分混合物得到的无机 - 有机组合物包括:

    N,N'-substituted 2,4,5-triketoimidazolidines
    9.
    发明授权
    N,N'-substituted 2,4,5-triketoimidazolidines 失效
    N,N {40-取代的2,4,5-三酮咪唑烷

    公开(公告)号:US3969290A

    公开(公告)日:1976-07-13

    申请号:US435885

    申请日:1974-01-23

    Abstract: A process for the preparation of modified N,N'-substituted-2,4,5-triketoimidazolidines which comprises reacting a precondensate having terminal isocyanate groups, prepared by reacting (a) a polybasic carboxylic acid, containing from 4 to 70 carbon atoms and from 2 to 6 carboxyl groups, with an excess of (b) one or more isocyanates or isocyanate forming compounds in the presence of a solvent, with (c) at least one oxamidic ester containing the group NH--CO--CO--OR.sup.v wherein R.sup.v represents an aliphatic hydrocarbon group containing up to 18 carbon atoms, a cycloaliphatic hydrocarbon group containing up to 8 carbon atoms or a mononuclear aromatic hydrocarbon group being unsubstituted or substituted by at least one hydrocarbon group and having a total of up to 14 carbon atoms in the presence of a solvent, a product prepared by said process and a shaped article comprising such a product.

    Abstract translation: 一种制备改性N,N'-取代-2,4,5-三酮咪唑烷的方法,其包括使具有末端异氰酸酯基团的预缩合物反应,所述预缩合物通过使(a)含有4-70个碳原子的多元羧酸和 2至6个羧基,过量的(b)一种或多种异氰酸酯或异氰酸酯形成化合物在溶剂存在下,和(c)至少一种含有NH-CO-CO-ORV基团的草酰胺,其中Rv 代表含有至多18个碳原子的脂族烃基,含有至多8个碳原子的脂环族烃基或未被取代的或被至少一个烃基取代的单核芳烃基团,其中总共具有多至14个碳原子 溶剂的存在,由所述方法制备的产品和包含这种产品的成型制品。

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