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1.发明授权Catalyst compositions containing transition metal complexes with thiolate ligands 有权含有硫醇盐配体的过渡金属络合物的催化剂组合物公开(公告)号：US09056930B2
公开(公告)日：2015-06-16
申请号：US14093809
申请日：2013-12-02
发明人： Mark L. Hlavinka
IPC分类号： C08F4/64 , C08F4/76 , B01J31/00 , C08F110/02 , C07F9/00 , C07F15/02 , C07F5/00 , C07F7/00 , C07F7/08 , C07F13/00 , C08F4/60
CPC分类号： C08F110/02 , C07F5/003 , C07F7/003 , C07F7/081 , C07F9/00 , C07F9/005 , C07F13/005 , C07F15/02 , C07F15/025 , C08F4/60141 , C08F4/659 , C08F4/65912 , C08F4/65916 , C08F4/64141 , C08F4/68353 , C08F4/7067 , C08F4/545 , C08F4/69353 , C08F2500/04 , C08F2500/01
摘要： The present invention discloses catalyst compositions employing transition metal complexes with a thiolate ligand. Methods for making these transition metal complexes and for using such compounds in catalyst compositions for the polymerization of olefins also are provided.
摘要翻译： 本发明公开了使用与硫醇盐配体的过渡金属络合物的催化剂组合物。 还提供了制备这些过渡金属配合物和在催化剂组合物中用于烯烃聚合的方法。
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公开(公告)号：US08618229B2
公开(公告)日：2013-12-31
申请号：US13042807
申请日：2011-03-08
申请人： Mark L. Hlavinka
发明人： Mark L. Hlavinka
CPC分类号： C08F110/02 , C07F5/003 , C07F7/003 , C07F7/081 , C07F9/00 , C07F9/005 , C07F13/005 , C07F15/02 , C07F15/025 , C08F4/60141 , C08F4/659 , C08F4/65912 , C08F4/65916 , C08F4/64141 , C08F4/68353 , C08F4/7067 , C08F4/545 , C08F4/69353 , C08F2500/04 , C08F2500/01
摘要： The present invention discloses catalyst compositions employing transition metal complexes with a thiolate ligand. Methods for making these transition metal complexes and for using such compounds in catalyst compositions for the polymerization of olefins also are provided.
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公开(公告)号：US09637425B2
公开(公告)日：2017-05-02
申请号：US13852611
申请日：2013-03-28
发明人： Kevin P. McGowan , Adam S. Veige
CPC分类号： C07C5/2587 , B01J23/24 , B01J31/143 , B01J31/1805 , B01J31/183 , B01J31/2208 , B01J2231/122 , B01J2231/52 , B01J2531/0244 , B01J2531/62 , C07B2200/09 , C07C2/32 , C07C2/34 , C07C5/2581 , C07C2531/22 , C07F11/00 , C07F11/005 , C08F110/02 , C08F4/69353 , C07C11/02
摘要： A catalyst comprising a NCN pincer ligand group VI complex is capable of being used as an olefin polymerization or isomerization catalyst that does not require an expensive cocatalyst. The complex has the NCN pincer ligand in a trianionic form with the group VI in the +3 oxidation state or the +4 oxidation state and complexed to an anionic hydrocarbon group, or the complex has the NCN pincer ligand in a dianionic form with the group VI in the +2 oxidation state. The complex is capable of initiating the polymerization of alkenes without an added activator. The presence of a water scavenger and activator or cocatalyst, such as triisobutylaluminum, increases the catalytic activity. The complex is capable of selectively isomerizing 1-alkenes to cis/trans 2-alkenes.
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4.发明申请NCN TRIANIONIC PINCER COMPLEXES AS CATALYSTS FOR OLEFIN POLYMERIZATION AND ISOMERIZATION 有权NCN三硫键复合物作为烯烃聚合和异构化的催化剂公开(公告)号：US20130289326A1
公开(公告)日：2013-10-31
申请号：US13852611
申请日：2013-03-28
发明人： KEVIN P. MCGOWAN , ADAM S. VEIGE
CPC分类号： C07C5/2587 , B01J23/24 , B01J31/143 , B01J31/1805 , B01J31/183 , B01J31/2208 , B01J2231/122 , B01J2231/52 , B01J2531/0244 , B01J2531/62 , C07B2200/09 , C07C2/32 , C07C2/34 , C07C5/2581 , C07C2531/22 , C07F11/00 , C07F11/005 , C08F110/02 , C08F4/69353 , C07C11/02
摘要： A catalyst comprising a NCN pincer ligand group VI complex is capable of being used as an olefin polymerization or isomerization catalyst that does not require an expensive cocatalyst. The complex has the NCN pincer ligand in a trianionic form with the group VI in the +3 oxidation state or the +4 oxidation state and complexed to an anionic hydrocarbon group, or the complex has the NCN pincer ligand in a dianionic form with the group VI in the +2 oxidation state. The complex is capable of initiating the polymerization of alkenes without an added activator. The presence of a water scavenger and activator or cocatalyst, such as triisobutylaluminum, increases the catalytic activity. The complex is capable of selectively isomerizing 1-alkenes to cis/trans 2-alkenes.
摘要翻译： 包含NCN钳子配体基团VI络合物的催化剂能够用作不需要昂贵助催化剂的烯烃聚合或异构化催化剂。 络合物具有三阴离子形式的NCN钳子配体，其中VI族处于+3氧化态或+4氧化态，并与阴离子烃基络合，或者络合物具有二阴离子形式的NCN钳子配体 VI处于+2氧化态。 络合物能够在没有添加的活化剂的情况下引发烯烃的聚合。 吸水剂和活化剂或助催化剂如三异丁基铝的存在增加了催化活性。 络合物能够选择性地将1-烯烃异构化为顺式/反式2-烯烃。
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5.发明申请Catalyst Compositions Containing Transition Metal Complexes With Thiolate Ligands 审中-公开含有硫醇配体的过渡金属配合物的催化剂组合物公开(公告)号：US20140094577A1
公开(公告)日：2014-04-03
申请号：US14093809
申请日：2013-12-02
发明人： Mark L. Hlavinka
IPC分类号： C08F110/02
CPC分类号： C08F110/02 , C07F5/003 , C07F7/003 , C07F7/081 , C07F9/00 , C07F9/005 , C07F13/005 , C07F15/02 , C07F15/025 , C08F4/60141 , C08F4/659 , C08F4/65912 , C08F4/65916 , C08F4/64141 , C08F4/68353 , C08F4/7067 , C08F4/545 , C08F4/69353 , C08F2500/04 , C08F2500/01
摘要： The present invention discloses catalyst compositions employing transition metal complexes with a thiolate ligand. Methods for making these transition metal complexes and for using such compounds in catalyst compositions for the polymerization of olefins also are provided.
摘要翻译： 本发明公开了使用与硫醇盐配体的过渡金属络合物的催化剂组合物。 还提供了制备这些过渡金属配合物和在催化剂组合物中用于烯烃聚合的方法。
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6.发明申请公开(公告)号：US20120232235A1
公开(公告)日：2012-09-13
申请号：US13042807
申请日：2011-03-08
申请人： Mark L. Hlavinka
发明人： Mark L. Hlavinka
CPC分类号： C08F110/02 , C07F5/003 , C07F7/003 , C07F7/081 , C07F9/00 , C07F9/005 , C07F13/005 , C07F15/02 , C07F15/025 , C08F4/60141 , C08F4/659 , C08F4/65912 , C08F4/65916 , C08F4/64141 , C08F4/68353 , C08F4/7067 , C08F4/545 , C08F4/69353 , C08F2500/04 , C08F2500/01
摘要： The present invention discloses catalyst compositions employing transition metal complexes with a thiolate ligand. Methods for making these transition metal complexes and for using such compounds in catalyst compositions for the polymerization of olefins also are provided.
摘要翻译： 本发明公开了使用与硫醇盐配体的过渡金属络合物的催化剂组合物。 还提供了制备这些过渡金属配合物和在催化剂组合物中用于烯烃聚合的方法。
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