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    Method for producing a catalyst for homo-or co-polymerization of ethylene
    1.
    发明授权
    Method for producing a catalyst for homo-or co-polymerization of ethylene 失效
    制备乙烯均相或共聚合催化剂的方法

    公开(公告)号：US06914028B2

    公开(公告)日：2005-07-05

    申请号：US10416692

    申请日：2001-11-09

    申请人： Chun-Byung Yang ,  Sang-Yull Kim ,  Weon Lee

    发明人： Chun-Byung Yang ,  Sang-Yull Kim ,  Weon Lee

    IPC分类号： C08F4/656 ,  C08F4/64 ,  C08F10/00 ,  C08F10/02 ,  C08F110/02 ,  B01J31/00 ,  B01J37/00 ,  C08F4/02 ,  C08F4/60

    CPC分类号： C08F10/02 ,  C08F110/02 ,  C08F4/651 ,  C08F4/6365 ,  C08F4/6493 ,  C08F4/6465 ,  C08F2500/18 ,  C08F2500/12

    摘要： A method of making an olefin polymerization catalyst is disclosed. The method first combines a magnesium halide with an alcohol, then adds a hydroxylated ester and a silicon alkoxide, followed by a titanium compound and another silicon compound to result in a solid composition. This solid composition is then reacted with an aluminum compound and an alkyl halide, followed by reaction with a second titanium compound which may be the same as or different from the first. The second silicon compound is preferably a silicon halide, and the titanium compounds are preferably halides and alkoxides. The aluminum compounds preferably have chloride and alkyl ligands bonded to them.

    摘要翻译： 公开了一种制备烯烃聚合催化剂的方法。 该方法首先将卤化镁与醇组合，然后加入羟基化酯和烷氧基硅烷，然后加入钛化合物和另一种硅化合物以产生固体组合物。 然后将该固体组合物与铝化合物和烷基卤反应，然后与可与第一钛化合物相同或不同的第二钛化合物反应。 第二硅化合物优选为卤化硅，钛化合物优选为卤化物和醇盐。 铝化合物优选具有键合到它们上的氯化物和烷基配体。

    Catalysts for the polymerization of olefins
    3.
    发明授权
    Catalysts for the polymerization of olefins 失效
    用于烯烃聚合的催化剂

    公开(公告)号：US06699814B2

    公开(公告)日：2004-03-02

    申请号：US10455898

    申请日：2003-06-06

    申请人： Giampiero Morini ,  Giulio Balbontin ,  Yuri V. Gulevich

    发明人： Giampiero Morini ,  Giulio Balbontin ,  Yuri V. Gulevich

    IPC分类号： C08F4649

    CPC分类号： C08F10/06 ,  C07C69/63 ,  C08F4/6365 ,  C08F4/651

    摘要： The present invention relates to catalysts particularly suitable for the sterospecific polymermerization of olefins, comprising Ti, Mg, halogen and an electron donor compound selected from heteroatoms containing esters of malonic acids. Polymers produced by the catalysts have high isotactic index expressed in terms of high xylene insolubility.

    摘要翻译： 本发明涉及特别适用于包含Ti，Mg，卤素和选自含有丙二酸酯的杂原子的电子给体化合物的烯烃的固相特异性聚酯化的催化剂。 由催化剂生产的聚合物具有高的二甲苯不溶性高的全同立构指数。

    Process for the preparation of a catalyst component for the polymerization of an olefin
    4.
    发明授权
    Process for the preparation of a catalyst component for the polymerization of an olefin 有权
    制备用于烯烃聚合的催化剂组分的方法

    公开(公告)号：US06799568B2

    公开(公告)日：2004-10-05

    申请号：US10106795

    申请日：2002-03-27

    申请人： Vladimir A. Zakharov ,  Gennady D. Bukatov ,  Sergei A. Sergeev

    发明人： Vladimir A. Zakharov ,  Gennady D. Bukatov ,  Sergei A. Sergeev

    IPC分类号： C08F458

    CPC分类号： C08F10/06 ,  C08F4/6365

    摘要： The invention is directed to a process for the preparation of a catalyst component for the polymerization of an olefin by: a) contacting metallic magnesium with an organic halide RX, where R is an organic group containing up to 20 carbon atoms and X is a halide, whereupon the dissolved reaction product I is separated from the solid residual products and whereafter, b) an alkoxy group or aryloxy group containing silane compound is added to the obtained reaction product I, whereupon the precipitate formed is purified to obtain reaction product II, c) which reaction product II is subsequently contacted with TiCl4 and the resulting product is purified to obtain the catalyst component. The invention is characterized in that in step b) the silane compound and reaction product I are introduced simultaneously to a mixing device.

    摘要翻译： 本发明涉及通过以下方法制备用于烯烃聚合的催化剂组分的方法：a）使金属镁与有机卤化物RX接触，其中R是含有至多20个碳原子的有机基团，X是卤化物 然后将溶解的反应产物I与固体残余物分离，然后将b）在所得反应产物I中加入含烷氧基或含芳氧基的硅烷化合物，由此将形成的沉淀物纯化得到反应产物II，c ）该反应产物II随后与TiCl 4接触，并将所得产物纯化以获得催化剂组分。本发明的特征在于在步骤b）中，将硅烷化合物和反应产物I同时引入混合装置。

    Process for the polymerization of olefins
    5.
    发明授权
    Process for the polymerization of olefins 失效
    烯烃聚合方法

    公开(公告)号：US06689850B2

    公开(公告)日：2004-02-10

    申请号：US10455899

    申请日：2003-06-06

    申请人： Giampiero Morini ,  Giulio Balbontin ,  Yuri V. Gulevich

    发明人： Giampiero Morini ,  Giulio Balbontin ,  Yuri V. Gulevich

    IPC分类号： C08F4649

    CPC分类号： C08F10/06 ,  C07C69/63 ,  C08F4/6365 ,  C08F4/651

    摘要： The present invention relates to a process for the polymerization of olefins using catalyst components and catalysts obtained therefrom comprising Ti, Mg, halogen and an electron donor compound selected from heteroatoms containing esters of malonic acids. The catalysts are particularly suitable for the sterospecific polymermerization of olefins having high isotactic index expressed in terms of high xylene insolubility.

    摘要翻译： 本发明涉及一种使用催化剂组分和由其获得的催化剂聚合烯烃的方法，其包含Ti，Mg，卤素和选自含有丙二酸酯的杂原子的电子给体化合物。 催化剂特别适用于以高二甲苯不溶性表示的具有高全同立构指数的烯烃的固相特异性聚酯化。

    High activity catalyst prepared with alkoxysilanes
    6.
    发明授权
    High activity catalyst prepared with alkoxysilanes 失效
    用烷氧基硅烷制备的高活性催化剂

    公开(公告)号：US06291384B1

    公开(公告)日：2001-09-18

    申请号：US08901816

    申请日：1997-07-28

    申请人： Robert I. Mink ,  Thomas E. Nowlin

    发明人： Robert I. Mink ,  Thomas E. Nowlin

    IPC分类号： C08F402

    CPC分类号： B01J31/143 ,  B01J21/08 ,  B01J31/0274 ,  B01J31/122 ,  B01J31/128 ,  C08F10/00 ,  C08F10/02 ,  C08F210/16 ,  Y02P20/52 ,  C08F4/6565 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/03 ,  C08F4/6365

    摘要： An ethylene-alpha-olefin copolymerization catalyst is prepared by impregnating a silica calcined at elevated temperature sequentially with an organomagnesium compound such as dialkylmagnesium compound, a silane compound which is free of hydroxyl groups, such as tetraethyl orthosilicate. A transition metal component such as titanium tetrachloride is then incorporated into the support. Unexpectedly, the calcination temperature of the silica used to prepare the catalyst precursors has a strong influence on polymer product properties. By increasing the calcination temperature of the silica from 600° to 700° C. or higher temperatures, a catalyst precursor when activated produced ethylene/1-hexene copolymers with narrower molecular weight distributions (MWD) as manifested by a decrease of resin MFR values of ˜3-4 units. Activation of this catalyst precursor with a trialkylaluminum compound results in a catalyst system which is effective for the production of ethylene copolymers.

    摘要翻译： 乙烯-α-烯烃共聚催化剂是通过用有机镁化合物如二烷基镁化合物，不含羟基的硅烷化合物如原硅酸四乙酯依次浸渍在高温下煅烧的二氧化硅来制备的。 然后将过渡金属组分如四氯化钛加入到载体中。 出乎意料的是，用于制备催化剂前体的二氧化硅的煅烧温度对聚合物产物性能有很大的影响。 通过将二氧化硅的煅烧温度从600℃提高到700℃或更高的温度，当活化时催化剂前体产生具有较窄分子量分布（MWD）的乙烯/ 1-己烯共聚物，这表现为树脂的MFR值的降低 〜3-4个单位。 这种催化剂前体与三烷基铝化合物的活化导致催化剂体系对生产乙烯共聚物是有效的。

    Process for the polymerization of olefins
    7.
    发明申请
    Process for the polymerization of olefins 失效
    烯烃聚合方法

    公开(公告)号：US20030207754A1

    公开(公告)日：2003-11-06

    申请号：US10455899

    申请日：2003-06-06

    发明人： Giampiero Morini ,  Giulio Balbontin ,  Yuri V. Gulevich

    IPC分类号： C08F004/44

    CPC分类号： C08F10/06 ,  C07C69/63 ,  C08F4/6365 ,  C08F4/651

    摘要： The present invention relates to catalyst components for the polymerization of olefins, and to the catalyst obtained therefrom, particularly suitable for the stereospecific polymerization of olefins, comprising Ti, Mg, halogen and an electron donor compound selected from heteroatom containing esters of malonic acids (heteroatom containing malonates). Said catalyst components when used in the polymerization of olefins, and in particular of propylene, are capable to give polymers in high yields and with high isotactic index expressed in terms of high xylene insolubility.

    摘要翻译： 本发明涉及用于烯烃聚合的催化剂组分和由其获得的催化剂，特别适用于包含Ti，Mg，卤素和选自含杂原子的丙二酸酯（杂原子）的电子给体化合物的烯烃的立体有择聚合 含有丙二酸酯）。 当用于烯烃聚合，特别是丙烯时，所述催化剂组分能够以高产率和高二甲苯不溶性表现的高全同立构指数得到聚合物。

    Process for the preparation of a catalyst component for the polymerization of an olefin
    8.
    发明申请
    Process for the preparation of a catalyst component for the polymerization of an olefin 有权
    制备用于烯烃聚合的催化剂组分的方法

    公开(公告)号：US20030008983A1

    公开(公告)日：2003-01-09

    申请号：US10106795

    申请日：2002-03-27

    发明人： Vladimir A. Zakharov ,  Gennady D. Bukatov ,  Sergei A. Sergeev

    IPC分类号： C08F004/44 ,  B01J031/00

    CPC分类号： C08F10/06 ,  C08F4/6365

    摘要： The invention is directed to a process for the preparation of a catalyst component for the polymerization of an olefin by: a) contacting metallic magnesium with an organic halide RX, where R is an organic group containing up to 20 carbon atoms and X is a halide, whereupon the dissolved reaction product I is separated from the solid residual products and whereafter, b) an alkoxy group or aryloxy group containing silane compound is added to the obtained reaction product I, whereupon the precipitate formed is purified to obtain reaction product II, c) which reaction product II is subsequently contacted with TiCl4 and the resulting product is purified to obtain the catalyst component. The invention is characterized in that in step b) the silane compound and reaction product I are introduced simultaneously to a mixing device.

    摘要翻译： 本发明涉及通过以下方法制备用于烯烃聚合的催化剂组分的方法：a）使金属镁与有机卤化物RX接触，其中R是含有至多20个碳原子的有机基团，X是卤化物 然后将溶解的反应产物I与固体残余物分离，然后将b）在所得反应产物I中加入含烷氧基或含芳氧基的硅烷化合物，由此将形成的沉淀物纯化得到反应产物II，c ）该反应产物II随后与TiCl 4接触，并将所得产物纯化以获得催化剂组分。 本发明的特征在于，在步骤b）中，将硅烷化合物和反应产物I同时引入混合装置。