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公开(公告)号：US12103991B2
公开(公告)日：2024-10-01
申请号：US17712286
申请日：2022-04-04
申请人： The Boeing Company
摘要： Disclosed herein are methods and apparatuses for curing a polymerizable material capable of cure through a redox reaction by electrically contacting the polymerizable material with an anode and a cathode to create a voltage bias that promotes curing of the polymerizable material.
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2.发明授权
公开(公告)号：US5578188A
公开(公告)日：1996-11-26
申请号：US221378
申请日：1994-03-31
CPC分类号： C08F2/58 , C09D5/4476 , H01B1/122
摘要： A film of a composite material is deposited by electropolymerization onto electrically conductive surface. A mixture comprising a monomer, a substance forming a dopant, a supporting electrolyte and a solvent is subjected to electrolysis in which the conductive surface to be coated is used as either cathode or anode. The cathode or anode is polarized to a potential between the electron transfer between the electrically conductive surface and the monomer. Prior to electrolysis, a solution is made from the mixture containing the substance forming a dopant either as anion, cation, molecule, and/or as undissociated complex.
摘要翻译： 通过电聚合将复合材料的膜沉积到导电表面上。 将包含单体，形成掺杂剂的物质，支持电解质和溶剂的混合物进行电解，其中待涂覆的导电表面用作阴极或阳极。 阴极或阳极被极化到导电表面和单体之间的电子转移之间的电位。 在电解之前，由含有形成掺杂剂的物质的混合物作为阴离子，阳离子，分子和/或作为未解离的络合物制成溶液。
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3.发明授权Thermoplastic composites formed by electropolymerization of N-substituted methacrylamide monomers 失效通过N-取代的甲基丙烯酰胺单体的电聚合形成的热塑性复合材料
公开(公告)号：US5549807A
公开(公告)日：1996-08-27
申请号：US396671
申请日：1995-03-01
申请人： James P. Bell , Jude O. Iroh , Daniel A. Scola , Jengli Liang
发明人： James P. Bell , Jude O. Iroh , Daniel A. Scola , Jengli Liang
CPC分类号： C09D5/4476 , C08F2/58 , C08F20/54 , C08J5/24 , C09D4/00 , Y10T428/12569 , Y10T428/31678 , Y10T428/31681
摘要： In accordance with the present invention, electropolymerization in a substantially aqueous solution is used to form thick (e.g. greater than 2 microns or 30 weight %) and thermally stable coatings of thermoplastic materials onto electrically conductive filler materials (e.g. rods, plates, fibers). In a first preferred embodiment, the thick thermoplastic matrix comprises a copolymer of 3-carboxyphenyl meleimde and styrene. In a second preferred embodiment, cyclic (and preferably aromatic) N-substituted methacrylamide monomers are electropolymerized onto electrically conductive (e.g., graphite) filler (e.g., fibers, plates, film or cloth) to form a novel polymer composite exhibiting high Tg as well as a controlled degree of cross-linking which can prevent flow at high temperature. This invention is particularly will suited for direct preparation of thermoplastic prepregs containing commercially available bundles of graphite fibers. These prepregs are then molded under heat and pressure so as to form a thermoplastic matrix composite with good fiber distribution, uniformity and high temperature resistance.
摘要翻译： 根据本发明，在基本上水溶液中的电聚合用于在导电填料（例如棒，板，纤维）上形成厚（例如大于2微米或30重量％）和热稳定的热塑性材料涂层。 在第一优选实施方案中，厚的热塑性基质包含3-羧基苯基苯乙烯和苯乙烯的共聚物。 在第二优选实施方案中，环状（优选芳族）N-取代的甲基丙烯酰胺单体电聚合到导电（例如石墨）填料（例如，纤维，板，膜或布）上以形成显示出高Tg的新型聚合物复合材料 作为可以防止高温流动的可控程度的交联。 本发明特别适用于直接制备含有市售的石墨纤维束的热塑性预浸料。 然后将这些预浸料在热和压力下成型，以形成具有良好纤维分布，均匀性和耐高温性的热塑性基质复合材料。
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公开(公告)号：US5045433A
公开(公告)日：1991-09-03
申请号：US529707
申请日：1990-05-30
IPC分类号： C07D401/04 , C08F2/50 , C08F2/58 , G03F7/031
CPC分类号： C08F2/58 , G03F7/031 , Y10S430/121
摘要： A substituted acridine derivative represented by ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 are independently hydrogen atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups, halogen atoms, or alkoxy groups, and Z.sub.1 is a six-membered heteroaromatic group which has one or two nitrogen atoms in its ring and may have an alkyl substituent having 1 to 8 carbon atoms, or a quinolyl group; and a photopolymerizable composition comprising 0.01 to 10 parts by weight of said derivative, 100 parts by weight of a photopolymerizable compound having a boiling point of 100.degree. C. or higher at atmospheric pressure and at least one kind of ethylenic unsaturated group, and 0 to 400 parts by weight of a thermoplastic organic polymer.
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5.发明授权
公开(公告)号：US4012295A
公开(公告)日：1977-03-15
申请号：US273903
申请日：1972-07-21
申请人： Steven Levinos
发明人： Steven Levinos
摘要： Polymerization of an ethylenically unsaturated compound is achieved by means of free radical initiators derived from the reaction of an aldehyde/bisulfite adduct with cupric ions resulting from electrolysis involving a copper anode. By including a photoconductive cathode in the system image-wise light exposure effects the formation of polymeric images in the polymerizable composition.
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公开(公告)号：US3965276A
公开(公告)日：1976-06-22
申请号：US539147
申请日：1975-01-07
CPC分类号： G03G17/02 , C08F2/58 , G03G17/08 , H05K3/0079 , H05K3/065
摘要： A liquid to solid addition polymerization imaging method comprises providing between two electrodes, one of which is in imagewise configuration, a polymerizable composition comprising unsaturated vinyl containing compounds; and, in the absence of chemical initiators, catalysts and electrolytes, applying an imagewise configured electrical field across the composition to polymerize the composition.
摘要翻译： 液体与固体加成聚合成像方法包括提供两个电极之一，其中一个是成像构型，包含不饱和乙烯基化合物的可聚合组合物; 并且在不存在化学引发剂，催化剂和电解质的情况下，在整个组合物上施加成像配置的电场以聚合组合物。
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公开(公告)号：US3879275A
公开(公告)日：1975-04-22
申请号：US24877072
申请日：1972-04-28
申请人： XEROX CORP
CPC分类号： C08F2/58 , G03G17/08 , H05K3/0079 , H05K3/065
摘要： Polymerization of monofunctional monomers and multifunctional monomers and polymers is initiated by application of electrical field. No solutions containing electrolytes are required. Imagewise field application provides raised polymeric images which may be used for printing plates or lithographic masters.
摘要翻译： 通过施加电场引发单官能单体和多官能单体和聚合物的聚合。 不需要含有电解质的溶液。 图像场应用提供可用于印刷板或平版印刷机的凸起的聚合物图像。
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8.发明授权Electrolytic polymerization process for preparing polymers of acetylenic compounds containing nickel 失效用于制备含镍镍的乙烯基化合物的聚合物的电解聚合方法
公开(公告)号：US3474012A
公开(公告)日：1969-10-21
申请号：US3474012D
申请日：1965-07-30
申请人： MONSANTO CO
发明人： KORNICKER WALTER A
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9.发明授权
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公开(公告)号：US20170301947A1
公开(公告)日：2017-10-19
申请号：US15636001
申请日：2017-06-28
申请人： FUJIFILM Corporation
IPC分类号： H01M10/056 , H01M4/62 , H01M4/587 , H01M4/505 , H01M10/0525 , H01M4/525
CPC分类号： H01M10/056 , C08F2/58 , C08F38/02 , C08G61/10 , C08G61/12 , C08G73/00 , H01M4/13 , H01M4/139 , H01M4/505 , H01M4/525 , H01M4/587 , H01M4/62 , H01M4/622 , H01M4/624 , H01M10/0525 , H01M10/0562 , H01M2300/0065 , H01M2300/0071 , H01M2300/0082 , H01M2300/0091
摘要： Provided are an all solid state secondary battery having a positive electrode active material layer, an inorganic solid electrolyte layer, and a negative electrode active material layer in this order, in which at least one layer of the positive electrode active material layer, the inorganic solid electrolyte layer, or the negative electrode active material layer includes an electrolytic polymerizable compound and an inorganic solid electrolyte, in which the electrolytic polymerizable compound is an electrolytic polymerizable compound having a molecular weight of less than 1,000 which is represented by any one of Formulae (1) to (5) below, and the inorganic solid electrolyte contains a metal belonging to Group I or II of the periodic table and has an ion conductivity of the metal being contained, an electrode sheet for a battery, and method for manufacturing an electrode sheet for a battery and an all solid state secondary battery. Reference signals each independently represent a specific atom, substituent, or linking group.
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