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    Flame-retardant electrolytic solution and nonaqueous secondary battery containing the same
    1.
    发明授权
    Flame-retardant electrolytic solution and nonaqueous secondary battery containing the same 失效
    阻燃电解液和含有它的非水二次电池

    公开(公告)号：US06210840B1

    公开(公告)日：2001-04-03

    申请号：US09201667

    申请日：1998-12-01

    申请人： Kyohei Usami ,  Miho Ito ,  Naohiro Kubota ,  Shinya Mashimo

    发明人： Kyohei Usami ,  Miho Ito ,  Naohiro Kubota ,  Shinya Mashimo

    IPC分类号： H01M1026

    CPC分类号： H01M10/0567 ,  C09K21/12 ,  H01M2/1653 ,  H01M4/382 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/4235

    摘要： A flame-retardant electrolytic solution of an electrolyte salt in an organic solvent, wherein the organic solvent contains at least one phosphorus compound represented by formula (I) and a nonaqueous secondary battery containing the flame-retardant electrolytic solution. wherein R1 represents an alkyl group having 1 to 8 carbon atoms, a halogenated alkyl group, an aryl group, an alkylaryl group, an aralkyl group or —CH2—COOR3; R2 represents a methyl group, an ethyl group or a halogenated alkyl group having 1 to 8 carbon atoms; R3 represents an alkyl group having 1 to 8 carbon atoms or a halogenated alkyl group; and m and n each represents 1 or 2 and the sum of m and n is 3.

    摘要翻译： 一种电解质盐在有机溶剂中的阻燃电解液，其中有机溶剂含有至少一种式（I）表示的磷化合物和含有阻燃电解液的非水二次电池。其中R1表示烷基 具有1至8个碳原子，卤代烷基，芳基，烷基芳基，芳烷基或-CH 2 -COOR 3; R2表示甲基，乙基或碳原子数1〜8的卤代烷基。 R3表示碳原子数1〜8的烷基或卤代烷基; m和n各自表示1或2，m和n的和为3。

    Substituted acridine derivatives and application thereof
    2.
    发明授权
    Substituted acridine derivatives and application thereof 失效
    取代的吖啶衍生物及其应用

    公开(公告)号：US5045433A

    公开(公告)日：1991-09-03

    申请号：US529707

    申请日：1990-05-30

    申请人： Hajime Kakumaru ,  Yoshitaka Minami ,  Naohiro Kubota ,  Shinya Mashimo

    发明人： Hajime Kakumaru ,  Yoshitaka Minami ,  Naohiro Kubota ,  Shinya Mashimo

    IPC分类号： C07D401/04 ,  C08F2/50 ,  C08F2/58 ,  G03F7/031

    CPC分类号： C08F2/58 ,  G03F7/031 ,  Y10S430/121

    摘要： A substituted acridine derivative represented by ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7 and R.sub.8 are independently hydrogen atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups, halogen atoms, or alkoxy groups, and Z.sub.1 is a six-membered heteroaromatic group which has one or two nitrogen atoms in its ring and may have an alkyl substituent having 1 to 8 carbon atoms, or a quinolyl group; and a photopolymerizable composition comprising 0.01 to 10 parts by weight of said derivative, 100 parts by weight of a photopolymerizable compound having a boiling point of 100.degree. C. or higher at atmospheric pressure and at least one kind of ethylenic unsaturated group, and 0 to 400 parts by weight of a thermoplastic organic polymer.

    Synthetic resin compositions containing 2,2,6,6-tetramethyl piperidyl ethers
    4.
    发明授权
    Synthetic resin compositions containing 2,2,6,6-tetramethyl piperidyl ethers 失效
    含有2,2,6,6-四甲基哌啶基醚的合成树脂组合物

    公开(公告)号：US4423174A

    公开(公告)日：1983-12-27

    申请号：US401481

    申请日：1982-07-26

    申请人： Motonobu Minagawa ,  Naohiro Kubota ,  Ryoji Kimura

    发明人： Motonobu Minagawa ,  Naohiro Kubota ,  Ryoji Kimura

    IPC分类号： C08K5/00 ,  C07D211/46 ,  C08K5/34 ,  C08K5/3412 ,  C08K5/3432 ,  C08K5/3435 ,  C08L1/00 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L27/00 ,  C08L51/00 ,  C08L51/02 ,  C08L67/00 ,  C08L101/00 ,  C07D401/02 ,  C08K5/51

    CPC分类号： C08K5/3435

    摘要： Synthetic resin compositions of improved resistance to deterioration by heat and light are provided containing a 2,2,6,6-tetramethyl piperidyl ether having the formula: ##STR1## The compounds of the invention can be prepared by the reaction of the 2,2,6,6-tetramethyl piperidyl alcohol R.sub.1 -OH with (poly) trimethylol alkane, (poly) pentaerthritol, or an alcohol containing an oxetane ring, to form the ether.The etherification is carried out by the conventional method, for example, by the reaction of R.sub.1 -OH with the organic sulfonate of the above-mentioned alcohols, or by the reaction of R.sub.1 -OH with the halogenated above-mentioned alcohols in the presence of an alkali or acid acceptor.The compounds where n is equal to 2 or more can be prepared by chain opening polymerization of the corresponding compound containing the oxetane ring.

    摘要翻译： 提供了具有改善的抗热劣化性能的合成树脂组合物，其含有具有下式的2,2,6,6-四甲基哌啶基醚。本发明的化合物可以通过使2,2 （聚）三羟甲基烷烃，（聚）季戊四醇或含有氧杂环丁烷环的醇形成醚的6,6-四甲基哌啶醇R1-OH。 醚化通过常规方法进行，例如通过R1-OH与上述醇的有机磺酸酯的反应，或通过R1-OH与上述卤化的醇的反应，在 碱或酸受体。 其中n等于2或更大的化合物可以通过含有氧杂环丁烷环的相应化合物的开环聚合来制备。

    Glycol carbonate ester stabilizers for synthetic resins
    6.
    发明授权
    Glycol carbonate ester stabilizers for synthetic resins 失效
    用于合成树脂的二醇碳酸酯稳定剂

    公开(公告)号：US4255301A

    公开(公告)日：1981-03-10

    申请号：US904524

    申请日：1978-05-10

    申请人： Motonobu Minagawa ,  Yutaka Nakahara ,  Naohiro Kubota

    发明人： Motonobu Minagawa ,  Yutaka Nakahara ,  Naohiro Kubota

    IPC分类号： C08K5/00 ,  C07C69/96 ,  C08K5/10 ,  C08K5/109 ,  C08L1/00 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L27/00 ,  C08L51/00 ,  C08L51/02 ,  C08L67/00 ,  C08L101/00 ,  C08K5/04

    CPC分类号： C07C69/96 ,  C08K5/109

    摘要： Stabilizer compositions comprising a polymer stabilizer and a carbonate ester of cyclic dihydroxy compounds protect synthetic resins against the harmful effects of light having a wavelength less than 400 nanometers. The carbonate ester can be represented by the formula ##STR1## in which a is a number from 1 to 50, A is hydrogen or ##STR2## B is R' or --G--OH, R and R' are independently alkyl, alkoxyalkyl, cycloalkyl, aryl, aryloxyalkyl, aralkyl, or alkaryl groups, and G in at least one occurrence is a residue of a cycloaliphatic or non-aromatic oxygen heterocyclic dihydroxy compound having 3 to 20 carbon atoms and 1 or 2 rings of 3 to 12 members, of which up to 4 can be oxygen. Additional occurrences of G can be aliphatic glycol or bisphenol residues if desired. The polymer stabilizer included in the stabilizer compositions with carbonate esters of cyclic dihydroxy compounds can include metal carboxylate salts 1,2-epoxides, phenols, organic phosphites, esters of thiodipropionic acid, 2-hydroxybenzophenones, 2(2'-hydroxyaryl)benzotriazoles, nickel phenolates, and carboxylic acids of 2,2,6,6-tetraalkylpiperidine-4-alcohols.There are also provided stabilized synthetic resin compositions comprising a stabilizer composition including a carbonate ester of a cyclic dihydroxy compound as defined.

    摘要翻译： 包含聚合物稳定剂和环状二羟基化合物的碳酸酯的稳定剂组合物保护合成树脂免受波长小于400纳米的光的有害影响。 碳酸酯可由式（Ⅰa）表示，其中a为1至50的数，A为氢或B为R'或-G-OH，R和R'独立地为烷基，烷氧基烷基， 环烷基，芳基，芳氧基烷基，芳烷基或烷芳基，G至少一个为碳原子数为3〜20的脂环族或非芳香族氧杂环二羟基化合物的残基，1〜2个环为3〜12个， 其中多达4个可以是氧气。 如果需要，另外出现的G可以是脂族二醇或双酚残基。 包含在具有环状二羟基化合物的碳酸酯的稳定剂组合物中的聚合物稳定剂可以包括金属羧酸盐，1,2-环氧化物，酚，有机亚磷酸酯，硫代二丙酸的酯，2-羟基二苯甲酮，2（2'-羟基芳基）苯并三唑， 酚盐和2,2,6,6-四烷基哌啶-4-醇的羧酸。 还提供稳定的合成树脂组合物，其包含稳定剂组合物，其包含如所定义的环状二羟基化合物的碳酸酯。

    2,2,6,6-TETRAMETHYL-4-PIPERIDYL THIOCARBOXYLATES AND AMINOCARBOXYLATES AND SYNTHETIC RESIN COMPOSITIONS CONTAINING THE SAME
    10.
    发明授权
    2,2,6,6-TETRAMETHYL-4-PIPERIDYL THIOCARBOXYLATES AND AMINOCARBOXYLATES AND SYNTHETIC RESIN COMPOSITIONS CONTAINING THE SAME 失效
    2,2,6,6-四甲基-4-哌啶羧酸和氨基甲酸酯及其合成树脂组合物

    公开(公告)号：US4102858A

    公开(公告)日：1978-07-25

    申请号：US724793

    申请日：1976-09-20

    申请人： Motonobu Minagawa ,  Naohiro Kubota ,  Toshihiro Shibata

    发明人： Motonobu Minagawa ,  Naohiro Kubota ,  Toshihiro Shibata

    IPC分类号： C07D211/46 ,  C07D211/54 ,  C07D211/94 ,  C08K5/3435 ,  C07D211/06 ,  C08K5/34

    CPC分类号： C08K5/3435 ,  C07D211/46 ,  C07D211/54 ,  C07D211/94

    摘要： 2,2,6,6-TETRAMETHYL-4-PIPERIDYL THIOCARBOXYLATES AND AMINOCARBOXYLATES ARE PROVIDED HAVING THE GENERAL FORMULA: ##STR1## wherein: M.sub.1, M.sub.3, AND M.sub.4 ARE NUMBERS FROM 0 TO 1;m.sub.2 is a number from 1 to 2;n.sub.1 is a number from 0 to 2;n.sub.2 is a number from 0 to 3;n.sub.3 is a number from 0 to 2;R.sub.1 is selected from the group consisting of alkyl, aralkyl, cycloalkyl and 2,2,6,6-tetramethyl-4-piperidyl;R.sub.2 is selected from the group consisting of alkyl, cycloalkyl, alkylaryl, aralkyl, and hydroxy-substituted such radicals;R.sub.1 and R.sub.2 have from one to about twenty carbon atoms;X is hydrogen or O;Y.sub.1 and Y.sub.2 are bivalent linking radicals having from one to about 20 carbon atoms, and selected from the group consisting of alkylene and cycloalkylene; and amino-substituted such radicals;Q is selected from the group consisting of SR.sub.2 and ##STR2## Z is an organic radical having a valence from 2 to 4 and from one to about twenty carbon atoms, and selected from the group consisting of alkylene, alkylidene, aralkylene, aralkylidene, alkarylene, alkarylidene, heterocycloalkylene, heterocycloalkylidene, cycloalkylene and cycloalkylidene; amino-substituted such radicals and 2,2,6,6-tetramethyl-4-piperidylidene;There being from one to four sulfur-containing or nitrogen-containing such groups and at least one ##STR3## ATTACHED TO THE Z radical. Synthetic resin compositions also are provided having their resistance to deterioration in the presence of ultraviolet light enhanced by at least one of these compounds.

    摘要翻译： 2,2,6,6-四甲基-4-哌啶羧酸甲酯和氨基甲酸酯是提供有一般公式的： I. 其中：