摘要:
Method for producing an oxidized PAN fiber (OPF) wherein a PAN fiber is subjected to an oxidation process in which reactive oxidizing species are maintained in close enough proximity to the PAN fiber during the oxidation process such that a core of the PAN fiber is converted to a crosslinked thermoset morphology before an oxidized shell of the PAN fiber becomes thick enough to substantially inhibit penetration of the reactive oxidizing species into the core. The resulting OPF possesses a density greater than 1.35 g/cm3 and a substantially homogeneous crosslinked thermoset morphology along a radial dimension of the oxidized PAN fiber. Flame-retarded materials containing the resulting OPF, as well as methods for producing such flame-retarded materials, are also described.
摘要翻译:氧化PAN纤维(OPF)的制造方法,其中PAN纤维进行氧化处理,其中在氧化过程中将活性氧化物质保持在足够接近PAN纤维的位置,使得PAN纤维的芯转变为 在PAN纤维的氧化壳之前的交联的热固性形态变得足够厚以基本上抑制反应性氧化物质渗透到芯中。 所得的OPF具有大于1.35g / cm 3的密度和沿着氧化的PAN纤维的径向尺寸的基本均匀的交联热固性形态。 还描述了含有所得OPF的阻燃材料以及制备这种阻燃材料的方法。
摘要:
Method for producing an oxidized PAN fiber (OPF) wherein a PAN fiber is subjected to an oxidation process in which reactive oxidizing species are maintained in close enough proximity to the PAN fiber during the oxidation process such that a core of the PAN fiber is converted to a crosslinked thermoset morphology before an oxidized shell of the PAN fiber becomes thick enough to substantially inhibit penetration of the reactive oxidizing species into the core. The resulting OPF possesses a density greater than 1.35 g/cm3 and a substantially homogeneous crosslinked thermoset morphology along a radial dimension of the oxidized PAN fiber. Flame-retarded materials containing the resulting OPF, as well as methods for producing such flame-retarded materials, are also described.
摘要翻译:氧化PAN纤维(OPF)的制造方法,其中PAN纤维进行氧化处理,其中在氧化过程中将活性氧化物质保持在足够接近PAN纤维的位置,使得PAN纤维的芯转变为 在PAN纤维的氧化壳之前的交联的热固性形态变得足够厚以基本上抑制反应性氧化物质渗透到芯中。 所得的OPF具有大于1.35g / cm 3的密度和沿着氧化的PAN纤维的径向尺寸的基本均匀的交联热固性形态。 还描述了含有所得OPF的阻燃材料以及制备这种阻燃材料的方法。
摘要:
[Object]To provide a liquid crystal alignment layer that can easily be formed, to which an anchoring force can be efficiently induced with less polarized light for exposure, and that is effective in controlling the orientation and pretilt angle of liquid crystal molecules, and a compound and polymer that can be used for such a liquid crystal alignment layer.[Solution]A compound is represented by general formula (I): where L is a polymerizable group; Sp is a spacer unit containing methylene; Q is a direct bond, —O—, or other group; A contains a group selected from the group consisting of trans-1,4-cyclohexylene and other groups; s is an integer of 1 to 4, where if s is 2 to 4, each A may be the same or different; X and Y are each independently hydrogen or other group; and M is any of general formulas (IIa), (IIb), and (IIc):
摘要:
[Object]To provide a liquid crystal alignment layer that can easily be formed, to which an anchoring force can be efficiently induced with less polarized light for exposure, and that is effective in controlling the orientation and pretilt angle of liquid crystal molecules, and a compound and polymer that can be used for such a liquid crystal alignment layer.[Solution]A compound is represented by general formula (I): where L is a polymerizable group; Sp is a spacer unit containing methylene; Q is a direct bond, —O—, or other group; A contains a group selected from the group consisting of trans-1,4-cyclohexylene and other groups; s is an integer of 1 to 4, where if s is 2 to 4, each A may be the same or different; X and Y are each independently hydrogen or other group; and M is any of general formulas (IIa), (IIb), and (IIc):