摘要:
An electrochemical separation device includes a first electrode, a second electrode, and a cell stack including a plurality of sub-blocks each having alternating depleting compartments and concentrating compartments and each including frame and channel portions disposed between the first electrode and the second electrode. An internal seal formed of a first material is disposed between and in contact with the channel portions between adjacent sub-blocks in the cell stack and configured to prevent leakage between depleting compartments and concentrating compartments in the adjacent sub-blocks. An external seal formed of a second material having at least one material parameter different from the first material is disposed between and in contact with the frames of the adjacent sub-blocks in the cell stack and configured to prevent leakage from an internal volume of the electrochemical separation device to outside of the electrochemical separation device.
摘要:
A dual-pathway system for CO2 capture in both acidified and basified streams is provided. The system may be embodied in an off-shore stand-alone facility to allow for the operation of oceanic CO2 capture to be more efficient and cost effective. Systems maintain high environmental standards by containing all intermediate acidic and alkaline solutions in a closed system so that the effluent discharged back into the ocean is at the similar pH and salinity as the feed oceanwater, with only CO2 removed. Acid and base produced by an electrodialyzer unit is used to achieve oceanwater decarbonization via gaseous CO2 removal and solid CaCO3 precipitates removal. The system is configured to require the processing of a very small fraction of the total oceanwater intake for the acid-base generation process.
摘要:
The present disclosure provides an ion-exchange membrane that includes a supporting substrate impregnated with an ion-exchange material. The supporting substrate includes an imprinted non-woven layer, and the imprinting includes a plurality of deformations at a surface density of at least 16 per cm2. The supporting substrate may lack a reinforcing layer. In some examples, the supporting substrate may include only a single layer of the imprinted non-woven fabric.
摘要:
A two-stage electrodialysis system and a method for recovering waste CO2-lean amine solvent are provided. The system includes an amine solution pretreatment filtering system, a C-A homogeneous membrane electrodialysis device, a BP-A bipolar membrane electrodialysis system, and a CO2 recovery and capture system. The C-A homogeneous membrane electrodialysis system includes a material chamber, a C-A homogeneous membrane electrodialysis device, a concentrated HSSs waste solution chamber, an electrode solution chamber, and corresponding pipelines and peristaltic pumps. The BP-A bipolar membrane electrodialysis system includes a secondary feed chamber, a BP-A bipolar membrane electrodialysis device, an acid liquor chamber, an electrode solution chamber, and corresponding pipelines and peristaltic pumps. The waste CO2-lean amine solvent enters the material chamber after passing through the amine solution pretreatment filtering system. The concentrated HSSs waste solution chamber is connected to the secondary feed chamber by a buffer tank.
摘要:
An electrolytic device includes four channels separated by three charged barriers. The device can be used to suppress an eluent stream containing separated sample analyte ions and/or to pretreat a sample stream containing unseparated analyte ions.
摘要:
Apparatus for purifying a liquid, which comprises a container housing multiple closed cells, each delimited by an anionic membrane and by a cationic membrane, and multiple open cells, susceptible of being traversed by a liquid to be treated and each interposed between two adjacent closed cells. The apparatus also comprises two electrodes which are supplied with supply voltages with reversed polarities in order to push the ionized particles of the liquid into the closed cells during an operating phase, and in order to bring the ionized particles back into the open cells during a regeneration phase. The apparatus also comprises a polymer substance having functional groups with non-zero electric charge, which is contained inside the closed cells in order to create chemical bonds with the ionized particles of the liquid that enter therein.
摘要:
An electrical purification apparatus and methods of making same are disclosed. The electrical purification apparatus may provide for increases in operation efficiencies, for example, with respect to current efficiencies and membrane utilization.
摘要:
Electrochemical separation devices are configured for lower energy consumption. Techniques for reducing shadow effect may involve providing distance between a spacer screen and an adjacent ion-selective membrane. A spacer having a screen that is thin relative to a surrounding frame may be used. Mild pressure may also be applied to a compartment to promote distance between a spacer screen and an adjacent ion-selective membrane.
摘要:
A device and process are disclosed for the separate removal of oppositely charged ions from electrolyte solutions and recombining them to form new chemical compositions. The invention provides the ability to create multiple ion flow channels and then form new chemical compositions therefrom. The process is accomplished by selectively combining oppositely charged ions of choice from different electrolyte solutions via the capacitive behavior of high electrical capacitance electrodes confined in insulated containers.
摘要:
An electrodialysis unit comprises a plurality of cathodes, a plurality of anodes and a plurality of membranes; the cathodes and anodes being arranged alternately in an electrode stack, with membranes in between each cathode and anode, anode flow paths formed between the membranes and anodes and cathode flow paths formed between the membranes and cathodes; the electrodialysis unit further comprising: an inlet manifold for distributing water to the anode flow paths or to the cathode flow paths, wherein the inlet manifold comprises a first tube provided with holes along its length, the holes being connected to the flow paths, and a second tube located within and enclosed by the first tube, the second tube having an inlet at one end and being closed at its second end and the second tube being provided with holes along its length that open into the first tube.