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公开(公告)号：US4141750A
公开(公告)日：1979-02-27
申请号：US812328
申请日：1977-07-01
申请人： Ralph W. Emerson , Jerome L. Martin
发明人： Ralph W. Emerson , Jerome L. Martin
摘要： Novel sizing compositions comprise an aqueous mixture of the reaction product of urea with selected Lewis acid, and a rosin that is modified with from about 5 to 50 percent based on the weight of the rosin, of an organic acidic compound selected from the group consisting of an .alpha.,.beta.-unsaturated organic acid, an anhydride thereof, and their mixtures. The selected Lewis acids which can be employed are sulfuryl chloride, chlorosulfonic acid, thionyl chloride, benzenesulfonyl chloride, benzenesulfonic acid, ortho- or para-toluenesulfonyl chloride, and ortho- or para-toluenesulfonic acid. Methods for making the sizing compositions and paper which is sized with the sizing compositions are also disclosed.
摘要翻译： 新型上浆组合物包含尿素与选定的路易斯酸的反应产物的水性混合物，和基于松香重量约5至50％改性的松香，选自以下的有机酸性化合物： α，β-不饱和有机酸，其酸酐及其混合物。 可以使用的选择的路易斯酸是磺酰氯，氯磺酸，亚硫酰氯，苯磺酰氯，苯磺酸，邻 - 或对 - 甲苯磺酰氯，以及邻 - 或对 - 甲苯磺酸。 也公开了用上浆料组合物制作上胶组合物和纸的方法。
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公开(公告)号：US4483744A
公开(公告)日：1984-11-20
申请号：US377398
申请日：1982-05-12
CPC分类号： D21H17/62
摘要： Improved sizing compositions for cellulosic products, e.g., paper, are provided by combining first and second composition components while at least the second component is finely divided into fine liquid or solid particles. Component combination in this manner serves to provide especially effective sizing compositions.The first component comprises a material which provides both ammonia and ammonium salt when combined with other materials in the composition. Such ammonia-ammonium salt-providing material comprises at least one material selected from the group consisting of ammonia, or a precursor thereof; ammonium salts, or a precursor thereof; a reaction product of urea and at least one selected Lewis acid; and mixtures of these materials.The second component comprises a saponified, partially saponified or unsaponified rosin that is modified with either an .alpha., .beta.-unsaturated aliphatic acid generally containing from about 3 to 10 carbon atoms, an anhydride of such acids, or mixtures thereof.The improved sizing compositions produced comprise ammonia, ammonium salt and modified rosin, which components are present in sizing-effective or sizing-enhancing amounts, such that a total acidity of the composition of at least about 1000 parts per million is realized.
摘要翻译： 通过组合第一和第二组合物组分而提供用于纤维素产品例如纸的改进的施胶组合物，同时至少将第二组分精细地分成细的液体或固体颗粒。 以这种方式的组分组合用于提供特别有效的施胶组合物。 第一组分包括当与组合物中的其它材料组合时提供氨和铵盐的材料。 这种氨 - 铵盐提供材料包括选自氨或其前体中的至少一种材料; 铵盐或其前体; 脲和至少一种选择的路易斯酸的反应产物; 以及这些材料的混合物。 第二组分包括用通常含有约3至10个碳原子的α，β-不饱和脂肪酸，这种酸的酸酐或其混合物改性的皂化，部分皂化或未皂化的松香。 所生产的改进的施胶组合物包括氨，铵盐和改性松香，该成分以施胶效率或施胶增加量存在，使得组合物的总酸度达到至少约1000ppm。
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公开(公告)号：US4022634A
公开(公告)日：1977-05-10
申请号：US565810
申请日：1975-03-31
摘要： Novel sizing compositions comprising an aqueous mixture of ammonia, an ammonium salt, and a rosin that is modified with from about 5 to 50 percent based on the weight of the rosin, of an organic acidic compound selected from the group consisting of an .alpha., .beta.-unsaturated organic acid, an anhydride thereof, and their mixtures. In one embodiment, the ammonia and ammonium salt are produced as the reaction product of urea and an acid selected from the group consisting of sulfamic acid, phosphoric acid, oxalic acid, methane-sulfonic acid, trichloracetic acid, nitric acid, sulfuric acid, hydrochloric acid, stearic acid, and acetic acid. The method of making the sizing compositions and paper which is sized with the sizing compositions are also provided.
摘要翻译： 新型施胶组合物包含氨，铵盐和松香的水性混合物，其以约5％至50％重量的松香重量的有机酸性化合物修饰，所述有机酸性化合物选自α，β 不饱和有机酸，其酸酐及其混合物。 在一个实施方案中，氨和铵盐作为尿素和选自氨基磺酸，磷酸，草酸，甲磺酸，三氯乙酸，硝酸，硫酸，盐酸的酸的反应产物 酸，硬脂酸和乙酸。 还提供了使用上胶组合物定尺寸的上胶组合物和纸的方法。
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公开(公告)号：US4025354A
公开(公告)日：1977-05-24
申请号：US545537
申请日：1975-01-30
摘要： This invention is directed to novel sizing agent compositions containing urea which is chemically modified and/or combined with other materials which produce desirable sizing properties. These novel agents are used as beater additives in pulp refining for the manufacture of cellulosic products or are applied to finished cellulosic products as surface sizes. The invention is also directed to methods of making the sizing agents. In one preferred embodiment, urea is reacted with sulfamic acid and the resulting reaction product is combined with rosin and further reacted to produce a novel sizing agent.
摘要翻译： 本发明涉及含有尿素的新型施胶剂组合物，其中所述的尿素经过化学改性和/或与其它可产生期望的施胶性质的材料组合。 这些新型试剂用作纸浆精炼中的搅拌添加剂，用于制造纤维素产品，或者作为表面尺寸应用于成品纤维素产品。 本发明还涉及制备上浆剂的方法。 在一个优选的实施方案中，尿素与氨基磺酸反应，并将所得反应产物与松香混合并进一步反应以产生新的上浆剂。
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5.发明授权Sizing compositions containing a formic acid salt, processes, and paper sized wih the compositions 失效含有甲酸盐，方法和纸张尺寸的组合物的上浆组合物
公开(公告)号：US4437894A
公开(公告)日：1984-03-20
申请号：US442319
申请日：1982-11-17
摘要： Novel sizing comprising an aqueous mixture of ammonia, an ammonium salt of formic acid, and a rosin that is modified with from about 5 to 50 percent, based on the weight of the rosin, of an organic acidic compound selected from the group consisting of an .alpha.,.beta.-unsaturated organic acid, an anhydride thereof, and their mixtures. In one embodiment, the ammonia and ammonium salt are produced as the reaction product of urea and formic acid. A method of making the sizing compositions and paper which is sized with the sizing compositions are also provided.
摘要翻译： 新型浆料包含氨，甲酸铵盐和松香的水性混合物，所述松香用基于松香重量的约5至50％改性的选自以下的有机酸性化合物： α，β-不饱和有机酸，其酸酐，及其混合物。 在一个实施方案中，产生氨和铵盐作为尿素和甲酸的反应产物。 还提供了制备尺寸为上胶组合物尺寸的上胶组合物和纸的方法。
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公开(公告)号：US4093779A
公开(公告)日：1978-06-06
申请号：US765610
申请日：1977-02-04
CPC分类号： C08L93/04 , D21H17/62 , Y10T428/31848 , Y10T428/31895 , Y10T428/31899 , Y10T428/31902
摘要： Novel sizing compositions comprising an aqueous mixture of ammonia, an ammonium salt, and a rosin that is modified with from about 5 to 50 percent based on the weight of the rosin, of an organic acidic compound selected from the group consisting of an .alpha.,.beta.-unsaturated organic acid, an anhydride thereof, and their mixtures. In one embodiment, the ammonia and ammonium salt are produced as the reaction product of urea and an acid selected from the group consisting of sulfamic acid, phosphoric acid, oxalic acid, methane-sulfonic acid, trichloracetic acid, nitric acid, sulfuric acid, hydrochloric acid, stearic acid, and acetic acid. The method of making the sizing compositions and paper which is sized with the sizing compositions are also provided.
摘要翻译： 新型施胶组合物包含氨，铵盐和松香的水性混合物，其以约5％至50％重量的松香重量的有机酸性化合物修饰，所述有机酸性化合物选自α，β 不饱和有机酸，其酸酐及其混合物。 在一个实施方案中，氨和铵盐作为尿素和选自氨基磺酸，磷酸，草酸，甲磺酸，三氯乙酸，硝酸，硫酸，盐酸的酸的反应产物 酸，硬脂酸和乙酸。 还提供了使用上胶组合物定尺寸的上胶组合物和纸的方法。
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