Abstract:
A polyethylene glycol (PEG) aerogel particles having an average particle diameter not substantially above about 2μ, a volumetric porosity of greater than about 50%, and pore sizes capable of retaining drug molecules. A method for preparing such polyethylene glycol (PEG) aerogel particles includes initiating a catalyzed reaction using a catalyst of PEG forming ingredients to form PEG particles; partially drying the formed PEG particles under conditions to control pore size; and subjecting the partially dried formed PEG particles to CO2 supercritical extraction for form the PEG aerogel particles. Drug molecules include chemotherapeutic agents. The surface of the PEG aerogel particles are reactable with a variety of agents, for example, to selectively target tumors, protects irreversible damage to labile proteins, and protects degradation of sensitive drugs with subsequent loss of biological efficacy.
Abstract:
Disclosed is a method for making a polymer or copolymer aerogel product by forming an aerogel polymer or copolymer solution in the presence of a polymer or copolymer catalyst and solvent therefor. The aerogel polymer or copolymer solution is drained onto a spinning disk or cup. The solvent is removed under aerogel forming conditions to produce the aerogel fiber web or yarn product.
Abstract:
A method for making polyethylene aerogels, including high molecular weight aerogels, commences by in a hydrocarbon solvent (e.g., toluene or benzene) in which polyethylene is insoluble at room temperature, adding polyethylene to the solvent heated to a temperature at which said polyethylene is soluble to form a reaction mixture. A free-radical catalyst is added to the reaction mixture and the reaction mixture is held until the desired gelation of the polyethylene has been achieved. The reaction mixture is cooled to about room temperature; and the hydrocarbon solvent is replaced with a gas (e.g., CO2 or air) to form the polyethylene aerogel. Optionally, the cooled reaction mixture can be contacted with an anti-solvent for polyethylene to replace the hydrocarbon solvent with the anti-solvent. Silica aerogel particles can be encapsulated in polyethylene aerogel by adding the particles to the polyethylene gelation reaction mixture.
Abstract:
Disclosed is a method for separating a vaporous or gaseous contaminant from an air stream contaminated therewith. This method includes the steps of: (a) passing said contaminated air into a contact zone in which is disposed an aerogel material capable of selecting adsorbing said contaminant from air and therein contacting said contaminated air with an aerogel material; and (b) withdrawing from said zone, air depleted of said contaminant. For present purposes, "contaminant" means a material not naturally occurring in ambient air and/or a material naturally occurring in air but present at a concentration above that found in ambient air. Thus, the present invention scrubs (or treats) air for the purpose of returning it to its ambient composition. Also disclosed herein is a process for the photocatalytic destruction of contaminants from an air stream wherein the contaminated air stream is passed into a control cell or contact zone in which is disposed a photocatalytic aerogel and exposing said aerogel to ultraviolet (UV) radiation for photocatalytically destroying the adsorbed contaminant, and withdrawing from said cell an exhaust air stream depleted in said contaminant.
Abstract:
The invention relates to the desulfurization of high sulfur coal, and specifically to the removal of pyrite from high sulfur coal via separation processes based on relative hydrophobicity. The surfaces of the pyrite particles are modified so as to be more hydrophilic by pre-conditioning of the coal with a culture of thiophilic bacteria such as Thiobacillus ferroxidans, and the coal is then subjected to the separation process. The bacterial culture is preadapted to pyrite and to the pyrite surface modification step conditions for a period of several weeks which allows the commercial preconditioning step to be accomplished in less than one hour and typically in five to fifteen minutes.
Abstract:
Disclosed is a method for making a polymer or copolymer aerogel product by forming an aerogel polymer or copolymer solution in the presence of a polymer or copolymer catalyst and solvent therefor. The aerogel polymer or copolymer solution is drained onto a spinning disk or cup. The solvent is removed under aerogel forming conditions to produce the aerogel fiber web or yarn product.
Abstract:
Polyethylene aerogels and aerogel fiber webs have a high degree of molecular alignment and interconnected fibers, which offer good mechanical strength and high porosity with open interconnected three-dimensional pore structure of the aerogel fibers. The high porosity of the aerogel fibers forming the web, offer a distinct advantage over solid fibers and fiber webs formed from polymer melts, or other non-gel form of polymer solutions. In this procedure, the polymer in solution is made into cross-linked gel with three-dimensional open pore structure before introducing it to the fiber web making process.
Abstract:
A concentrate containing precious metals is produced from a particulate feed material containing particles of various sizes by a size fractionation step, a gravity separation step performed on each size fraction separately, a magnetic separation step and a second gravity separation step. The process is especially intended for separating gold and other metals from so-called "black sand" placer deposits.
Abstract:
A method for making polyethylene aerogels, including high molecular weight aerogels, commences by in a hydrocarbon solvent (e.g., toluene or benzene) in which polyethylene is insoluble at room temperature, adding polyethylene to the solvent heated to a temperature at which said polyethylene is soluble to form a reaction mixture. A free-radical catalyst is added to the reaction mixture and the reaction mixture is held until the desired gelation of the polyethylene has been achieved. The reaction mixture is cooled to about room temperature; and the hydrocarbon solvent is replaced with a gas (e.g., CO2 or air) to form the polyethylene aerogel. Optionally, the cooled reaction mixture can be contacted with an anti-solvent for polyethylene to replace the hydrocarbon solvent with the anti-solvent. Silica aerogel particles can be encapsulated in polyethylene aerogel by adding the particles to the polyethylene gelation reaction mixture.
Abstract:
Polyethylene aerogels and aerogel fiber webs have a high degree of molecular alignment and interconnected fibers, which offer good mechanical strength and high porosity with open interconnected three-dimensional pore structure of the aerogel fibers. The high porosity of the aerogel fibers forming the web, offer a distinct advantage over solid fibers and fiber webs formed from polymer melts, or other non-gel form of polymer solutions. In this procedure, the polymer in solution is made into cross-linked gel with three-dimensional open pore structure before introducing it to the fiber web making process.