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公开(公告)号：US4271320A
公开(公告)日：1981-06-02
申请号：US71670
申请日：1979-08-31
IPC分类号： C07C29/141 , C07C45/30 , C07C45/34 , C07C45/80 , C07C45/83 , C07C29/136 , C07C29/14 , C07C45/27 , C07C45/36
CPC分类号： C07C45/80 , C07C29/141 , C07C45/30 , C07C45/34 , C07C45/83 , Y02P20/584
摘要： An industrially suitable process for producing a higher carbonyl compound by the oxidation of an olefinic compound having at least six carbon atoms is provided. Said improved process comprises oxidizing the olefinic compound in aqueous medium containing palladium or salt thereof and a copper salt in the presence of a specific water-soluble polyoxyalkylene compound in an amount of from about 1/4 to about 3 parts by weight per 1 part by weight of water contained in the reaction mixture. The improvement is demonstrated in terms of yield, selectivity, separation of the product, and recycle of the catalyst.
摘要翻译： 提供了通过氧化具有至少6个碳原子的烯属化合物来生产高级羰基化合物的工业上合适的方法。 所述改进的方法包括在特定水溶性聚氧化烯化合物存在下，将含有钯或其盐和铜盐的水性介质中的烯烃化合物氧化为约1/3〜3重量份/ 1份/ 包含在反应混合物中的水的重量。 在产率，选择性，产物分离和催化剂循环方面证明了改进。
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公开(公告)号：US5100854A
公开(公告)日：1992-03-31
申请号：US620211
申请日：1990-11-30
IPC分类号： B01J31/02 , B01J31/20 , B01J31/22 , B01J31/24 , B01J31/28 , B01J31/40 , C07C2/74 , C07C29/36 , C07C33/02 , C07C41/06 , C07F9/54
CPC分类号： B01J31/28 , B01J31/0268 , B01J31/24 , C07C2/74 , C07C29/36 , C07C33/02 , C07C41/06 , C07C67/055 , C07F9/5428 , B01J2231/20 , B01J2531/824 , B01J31/20 , B01J31/2208 , B01J31/40 , C07C2531/02 , Y02P20/584
摘要： Novel phosphonium salts of the general formula ##STR1## wherein R.sup.1 and R.sup.2 each is a hydrogen atom or a hydrocarbon group of 1 to 12 carbon atoms which may optionally be substituted; R.sup.3 is a hydrogen atom or a hydrocarbon group of 1 to 5 carbon atoms which may optionally be substituted; R.sup.4, R.sup.5 and R.sup.6 each is a hydrocarbon group of 1 to 8 carbon atoms which may optionally be substituted; X is a hydroxyl group, a hydroxycarbonyloxy group or a lower alkylcarbonyloxy group, and processes for production of the salts are described. Telomerization catalysts containing said phosphonium salts and processes for production of straight-chained alkadienyl compounds using the same catalysts are also provided.
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公开(公告)号：US4992609A
公开(公告)日：1991-02-12
申请号：US492882
申请日：1990-03-13
IPC分类号： B01J31/02 , B01J31/20 , B01J31/22 , B01J31/24 , B01J31/28 , B01J31/40 , C07C2/74 , C07C29/36 , C07C33/02 , C07C41/06 , C07F9/54
CPC分类号： B01J31/28 , B01J31/0268 , B01J31/24 , C07C2/74 , C07C29/36 , C07C33/02 , C07C41/06 , C07C67/055 , C07F9/5428 , B01J2231/20 , B01J2531/824 , B01J31/20 , B01J31/2208 , B01J31/40 , C07C2531/02 , Y02P20/584
摘要： Novel phosphonium salts of the general formula ##STR1## wherein R.sup.1 and R.sup.2 each is a hydrogen atom or a hydrocarbon group of 1 to 12 carbon atoms which may optionally be substituted; R.sup.3 is a hydrogen atom or a hydrocarbon group of 1 to 5 carbon atoms which may optionally be substituted; R.sup.4, R.sup.5 and R.sup.6 each is a hydrocarbon group of 1 to 8 carbon atoms which may optionally be substituted; X is a hydroxyl group, a hydroxycarbonyloxy group or a lower alkylcarbonyloxy group, and processes for production of the salts are described. Telomerization catalysts containing said phosphonium salts and processes for production of straight-chain alkadienyl compounds using the same catalysts are also provided.
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公开(公告)号：US4871880A
公开(公告)日：1989-10-03
申请号：US198860
申请日：1988-05-26
IPC分类号： B01J31/24 , C07B61/00 , C07C45/00 , C07C45/49 , C07C45/50 , C07C47/12 , C07C47/19 , C07C47/21 , C07C47/263 , C07C67/00
CPC分类号： C07C47/12 , C07C45/49 , C07C47/263
摘要： A hydroformylation process is provided which comprises reacting a compound of the general formulaCH.sub.2 .dbd.CH--CH.sub.2 --A--CH.sub.2 --Xwherein X is a hydroxyl or formyl group and A is a group of the formula--(CH.sub.2).sub.n -- or --(CH.sub.2).sub.m --CH.dbd.CH--in which n is an integer of 3-8 and m is an integer of 0-5, with a mixture of hydrogen and carbon monoxide in the presence of a rhodium compound and a specific tris(substituted phenyl) phosphite.
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公开(公告)号：US4927960A
公开(公告)日：1990-05-22
申请号：US211034
申请日：1988-06-24
IPC分类号： B01J31/02 , B01J31/20 , B01J31/22 , B01J31/24 , B01J31/28 , B01J31/40 , C07C2/74 , C07C29/36 , C07C33/02 , C07C41/06 , C07F9/54
CPC分类号： B01J31/28 , B01J31/0268 , B01J31/24 , C07C2/74 , C07C29/36 , C07C33/02 , C07C41/06 , C07C67/055 , C07F9/5428 , B01J2231/20 , B01J2531/824 , B01J31/20 , B01J31/2208 , B01J31/40 , C07C2531/02 , Y02P20/584
摘要： Novel phosphonium salts of the general formula ##STR1## wherein R.sup.1 and R.sup.2 each is a hydrogen atom or a hydrocarbon group of 1 to 12 carbon atoms which may optionally be substituted; R.sup.3 is a hydrogen atom or a hydrocarbon group of 1 to 5 carbon atoms which may optionally be substituted; R.sup.4, R.sup.5 and R.sup.6 each is a hydrocarbon group of 1 to 8 carbon atoms which may optionally be substituted; X is a hydroxyl group, a hydroxycarbonyloxy group or a lower alkylcarbonyloxy group, and processes for production of the salts are described. Telomerization catalysts containing said phosphonium salts and processes for production of straight-chain alkadienyl compounds using the same catalysts are also provided.
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公开(公告)号：US4808756A
公开(公告)日：1989-02-28
申请号：US104988
申请日：1987-10-06
申请人： Yasuo Tokitoh , Noriaki Yoshimura
发明人： Yasuo Tokitoh , Noriaki Yoshimura
摘要： The method for producing .alpha.,.omega.-dialdehydes from .alpha.,.omega.-diolefins or .alpha.,.omega.-alkenals in good yield and with high efficiency. The expensive rhodium catalyst for hydroformylation can be reused without any substantial attrition of activity. Moreover, since the loses of the catalyst, monodentate phosphine and sulfolane used in the hydroformylation reaction are minimal, the method is commercially advantageous.
摘要翻译： 从α，ω-二烯烃或α，ω-链烷醇生产α，ω-二醛的方法，产率高，效率高。 用于加氢甲酰化的昂贵的铑催化剂可以重复使用而没有任何实质性的活性消耗。 此外，由于催化剂的损失，加氢甲酰化反应中使用的单齿膦和环丁砜是最小的，所以该方法在商业上是有利的。
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公开(公告)号：US5118885A
公开(公告)日：1992-06-02
申请号：US634514
申请日：1990-12-27
IPC分类号： C07C29/36
CPC分类号： C07C29/36
摘要： An improved process for producing octa-2,7-dien-1-ol which comprises reacting butadiene with water in an aqueous sulfolane solution containing a carbonate and/or bicarbonate of a monodentate tertiary amine in the presence of a palladium compound and a phosphonium salt.
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公开(公告)号：US5057631A
公开(公告)日：1991-10-15
申请号：US478744
申请日：1990-02-12
申请人： Yasuo Tokitoh , Noriaki Yoshimura
发明人： Yasuo Tokitoh , Noriaki Yoshimura
摘要： Butadiene and water are reacted continuously in the presence of a solvent capable of dissolving both reactants and a palladium catalyst with the mole ratio of butadiene to the reaction product octa-2,7-dien-1-ol in the reaction mixture being maintained at 0.6 or more. By this process, octa-2,7-dien-1-ol can be produced continuously without reductions in reaction rate and selectivity and with decreased insoluble polymer formation.
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公开(公告)号：US4935488A
公开(公告)日：1990-06-19
申请号：US340791
申请日：1989-04-20
申请人： Toshihiro Omatsu , Yasuo Tokitoh , Noriaki Yoshimura , Masao Ishida , Makoto Yano , Koji Hirai , Yoichi Matsumoto , Keiji Kubo
发明人： Toshihiro Omatsu , Yasuo Tokitoh , Noriaki Yoshimura , Masao Ishida , Makoto Yano , Koji Hirai , Yoichi Matsumoto , Keiji Kubo
IPC分类号： C07C31/22 , C08G63/16 , C08G63/48 , C09D167/00
CPC分类号： C09D167/00 , C07C31/22 , C08G63/16 , C08G63/48
摘要： Novel trimethylolheptanes having three highly reactive hydroxyl groups are provided. They are useful as raw materials for the production of polyesters for use in or as raw materials or modifiers for paints, inks, adhesives, coating compositions and molding resins. Uses for the trimethylolheptanes are also provided.
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10.发明授权Hydroformylation of 3-methyl-3-buten-1-ol and analogs thereof and use of such hydroformylation products 失效3-甲基-3-丁烯-1-醇及其类似物的加氢甲酰化和使用这种加氢甲酰化产物
公开(公告)号：US4861922A
公开(公告)日：1989-08-29
申请号：US13535
申请日：1987-02-11
申请人： Yasuo Tokitoh , Noriaki Yoshimura
发明人： Yasuo Tokitoh , Noriaki Yoshimura
IPC分类号： C07C29/10 , C07C29/16 , C07D309/10 , C07D315/00
CPC分类号： C07D315/00 , C07C29/10 , C07C29/16 , C07D309/10
摘要： There is disclosed a method of hydroformylating 3-methyl-3-buten-1-ol and analogs thereof with carbon monoxide and hydrogen in the presence of a rhodium compound free from modification by a ligand containing an element belonging to the group V of the periodic table as well as a method of producing 3-methylpentane-1,5-diol and .beta.-methyl-.delta.-valerolactone using such hydroformylation product.
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