Organic electroluminescent materials and devices

    公开(公告)号:US10128450B2

    公开(公告)日:2018-11-13

    申请号:US15720314

    申请日:2017-09-29

    摘要: A compound having a structure according to formula (I) is disclosed. In formula (I), Cu is a monovalent copper atom; *C is a carbene carbon; X1 and X2 are selected from alkyl, cycloalkyl, alkoxy, amino, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, heteroalkynyl, arylalkyl, aryloxy, aryl, heteroalkyl, heteroaryl, and combinations thereof; X1 is bonded to *C by a C atom, and X2 is bonded to *C by an N atom; X1 and X2 are optionally joined to form a ring; and Y is selected halide, alkyl, cycloalkyl, alkoxy, amino, phosphine, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, heteroalkynyl, arylalkyl, aryloxy, aryl, heteroalkyl, heteroaryl, and combinations thereof. A formulation containing compound having a structure according to formula (I), and a device with an organic layer comprising disposed between an anode and a cathode, that includes a compound having a structure according to formula (I) are also described.

    Organic electroluminescent materials and devices

    公开(公告)号:US10199582B2

    公开(公告)日:2019-02-05

    申请号:US14475257

    申请日:2014-09-02

    摘要: A compound comprising a ligand LA according to formula (I) as well as, a first device and a formulation including the same are disclosed. In the structure of formula (I): ring A is a 5- or 6-membered heteroaryl ring; X1 is C or N; RA is mono-, bi-, tri-, tetradentate, or unsubstituted; RA, R10, R11, R12, R13, R14, R15, R16, and R17 are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof, any adjacent substituents of RA, R10, R11, R12, R13, R14, R15, R16, and R17 are optionally joined to form a fused ring; the dashed lines represent bonds to a metal M; and metal M has an atomic number greater than 40.