公开(公告)号：US3769307A

公开(公告)日：1973-10-30

申请号：US3769307D

申请日：1970-09-18

Applicant: US AGRICULTURE

Inventor： MOREAU J ,  DRAKE G ,  REEVES W

IPC: C08G73/02 ,  D06M13/408 ,  D06M15/61 ,  C09F7/00

CPC classification number: D06M13/408 ,  C08G73/0213 ,  C08G73/0233 ,  D06M15/61 ,  D06M2101/06 ,  D06M2200/00 ,  D06M2200/11 ,  Y10T442/227

Abstract: CERTAIN NEAT LIQUID PERFLUOROALKYL ESTERS WERE REACTED WITH CERTAIN NEAT L IQUID POLYAMINES CONTAINING A PRIMARY: SECONDARY:TERTIARY AMINE RATIO OF 1:2:1 TO PRODUCE NEW LIQUID POLYMERIC FLUOROAMIDO-AMINO COMPOUNDS. THE NEW COMPOUNDS WERE DISSOLVED IN CERTAIN SOLVENTS AND APPLIED TO COTTON FABRICS THEREBY IMPARTING TO THE TREATED FABRICS OLEOPHOBICITY WITH RETAINED HYDROPHILICITY WHICH WAS DURAABLE TO REPEATED LAUNDERING.

公开(公告)号：US3719448A

公开(公告)日：1973-03-06

申请号：US3719448D

申请日：1971-06-09

Applicant: US AGRICULTURE

Inventor： CHANCE L ,  MOREAU J

IPC: C07F9/38 ,  C07F9/40 ,  C07F9/44 ,  C07F9/564 ,  D06M13/493 ,  D06M15/356 ,  C07F9/56 ,  D06M13/28

CPC classification number: D06M15/3564 ,  C07F9/3808 ,  C07F9/4006 ,  C07F9/44 ,  C07F9/564 ,  D06M13/493 ,  Y10T442/2172

Abstract: Perfluoroalkyl iodide monomer and telomer ester adducts of diethyl vinylphosphonate were prepared by free radical addition. Iodine of these adducts was replaced by hydrogen, and derivatives of the reduced phosphonate adducts were prepared, which include phosphonic acids, acid chlorides, and aziridinyl phosphine oxides. The aziridinyl phosphine oxides are used to impart oil and water repellency to cellulosic textiles. The other derivatives are useful as chemical intermediates as well as potential forming agents.

Abstract translation: 通过自由基加成制备乙烯基膦酸二乙酯的全氟烷基碘单体和调聚酯加成物。 这些加合物的碘被氢代替，并且制备还原膦酸酯加合物的衍生物，其包括膦酸，酰氯和氮丙啶基氧化膦。 氮杂环丙烷氧化膦用于赋予纤维素纺织品防油和防水性能。 其他衍生物可用作化学中间体以及潜在的成形剂。