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    Aromatic polyimide silanol compounds, precursors and polymers thereof
    1.
    发明授权
    Aromatic polyimide silanol compounds, precursors and polymers thereof 失效
    芳族聚酰亚胺硅烷醇化合物，其前体及其聚合物

    公开(公告)号：US5075475A

    公开(公告)日：1991-12-24

    申请号：US615112

    申请日：1990-11-19

    申请人： Thomas K. Dougherty ,  Thomas W. Giants

    发明人： Thomas K. Dougherty ,  Thomas W. Giants

    IPC分类号： C07F7/08 ,  C07F7/10 ,  C08G77/54

    CPC分类号： C07F7/0896 ,  C07F7/0836 ,  C07F7/10 ,  C08G77/54

    摘要： Silanol-terminated aromatic imide compounds of Formula I ##STR1## where R.sub.3 and R.sub.4 are each selected from the group consisting of a C.sub.1 to C.sub.6 alkyl group, an unsubstituted aryl group and a substituted aryl group, Z is a divalent radical.are prepared by:(a) reacting a bromoaniline compound with a chosen silylating agent to form a compound having the formula BrC.sub.6 H.sub.5 NSi(R.sub.1).sub.3 Si(R.sub.2).sub.3, where R.sub.1 and R.sub.2 are each a C.sub.1 to C.sub.4 alkyl group(b) reacting the compound formed in step "a" with n-butyllithium, followed by reaction with a chosen halogenated alkylsilane compound to form a compound having Formula II ##STR2## where R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are as defined above (c) reacting the compound of Formula II formed in step "b" with a dianhydride compound having the formula ##STR3## where Z is as defined above to form a compound having Formula III ##STR4## where R.sub.3, R.sub.4, and Z are as defined above (d) hydrolyzing the compound of Formula III formed in step "c" to form the compound of Formula I.The compound of Formula I may be polymerized. A preferred copolymer in accordance with the present invention is formed by polymerizing the compound of Formula I with a silicon compound having the formula ##STR5## where R.sub.3 and R.sub.4 are as defined above,X=halogen, OH, OR, NRR, or ureido,R is selected from the group consisting of aC.sub.1This invention was made with United States Government support under Contract No. F33615-86-C-5081 awarded by the Department of the Air Force. The United States Government has certain rights in this invention.

    摘要翻译： 式I的硅烷醇封端的芳族酰亚胺化合物其中R 3和R 4各自选自C 1至C 6烷基，未取代的芳基和取代的芳基，Z是二价基团。 通过以下方法制备：（a）使溴苯胺化合物与选择的甲硅烷基化剂反应，形成具有式BrC 6 H 5 NS 1（R 1）3 Si（R 2）3的化合物，其中R 1和R 2各自为C 1至C 4烷基（b） 在步骤“a”中用正丁基锂形成的化合物，然后与选择的卤代烷基硅烷化合物反应以形成具有式II的化合物其中R 1，R 2，R 3和R 4如上所定义（c）使 在步骤“b”中形成的式II化合物与具有式“IMAGE”的二酐化合物，其中Z如上定义，以形成具有式III的化合物其中R3，R4和Z如上定义 （d）水解步骤“c”中形成的式III化合物以形成式I化合物。式I化合物可以聚合。 根据本发明的优选的共聚物是通过将式I化合物与式（III）的硅化合物聚合而形成的，其中R 3和R 4如上定义，X​​ =卤素，OH，OR，NRR或脲基， R选自C1至C6烷基，未取代的芳基和取代的芳基Y = -O-或p = 1-10。

    Aromatic polyimide silanol compounds, precursors and polymers thereof
    3.
    发明授权
    Aromatic polyimide silanol compounds, precursors and polymers thereof 失效
    芳族聚酰亚胺硅烷醇化合物，其前体及其聚合物

    公开(公告)号：US5081201A

    公开(公告)日：1992-01-14

    申请号：US604539

    申请日：1990-10-29

    申请人： Thomas K. Dougherty ,  Thomas W. Giants

    发明人： Thomas K. Dougherty ,  Thomas W. Giants

    IPC分类号： C07F7/08 ,  C07F7/10 ,  C08G77/54

    CPC分类号： C08G77/54 ,  C07F7/0836 ,  C07F7/0896 ,  C07F7/10

    摘要： Polymers of silanol-terminated aromatic imide compounds of Formula I ##STR1## where R.sub.3 and R.sub.4 are each selected from the group consisting of a C.sub.1 to C.sub.6 alkyl group, an unsubstituted aryl group and a substituted aryl group, Z is a divalent radical.A preferred copolymer in accordance with the present invention is formed by polymerizing the compound of Formula I with a silicon compound having the formula ##STR2## where R.sub.3 and R.sub.4 are as defined above, X=halogen, OH, OR, NRR, or ureido,Y=--O-- or ##STR3## p=1 to 10.

    摘要翻译： 式I的硅烷醇封端的芳族酰亚胺化合物的聚合物其中R 3和R 4各自选自C 1 -C 6烷基，未取代的芳基和取代的芳基，Z是二价基团 。 根据本发明的优选的共聚物是通过将式I化合物与式（III）的硅化合物聚合而形成的，其中R 3和R 4如上定义，X​​ =卤素，OH，OR，NRR或脲基， Y = -O-或 p = 1〜10。

    Aromatic polyimide silanol compounds, precursors and polymers thereof
    4.
    发明授权
    Aromatic polyimide silanol compounds, precursors and polymers thereof 失效
    芳族聚酰亚胺硅烷醇化合物，其前体及其聚合物

    公开(公告)号：US5021585A

    公开(公告)日：1991-06-04

    申请号：US365868

    申请日：1989-06-14

    申请人： Thomas K. Dougherty ,  Thomas W. Giants

    发明人： Thomas K. Dougherty ,  Thomas W. Giants

    IPC分类号： G02F1/1337 ,  C07F7/08 ,  C07F7/10 ,  C08G73/10 ,  C08G77/48 ,  C08G77/54 ,  H01L21/027 ,  H01L21/30

    CPC分类号： C08G77/54 ,  C07F7/0836 ,  C07F7/0896 ,  C07F7/10

    摘要： Silanol-terminated aromatic imide compounds of Formula I ##STR1## where R.sub.3 and R.sub.4 are each selected from the group consistsing of a C.sub.1 to C.sub.6 alkyl group, an unsubstituted aryl group and a substituted aryl group, Z is a divalent radical.are prepared by: (a) reacting a bromoaniline compound with a chosen silylating agent to form a compound having the formula BrC.sub.6 H.sub.5 NSi(R.sub.1).sub.3 Si(R.sub.2).sub.3, where R.sub.1 and R.sub.2 are each a C.sub.1 to C.sub.4 alkyl group(b) reacting the compound formed in step "a" with n-butyllithium, followed by reaction with a chosen halogenated alkylsilane compound to form a compound having Formula II ##STR2## where R.sub.1, R.sub.2, R.sub.3, and R.sub.4 are as defined above (c) reacting the compound of Formula II formed in step "b" with a dianhydride compound having the formula ##STR3## where Z is as defined above to form a compound having Formula III ##STR4## where R.sub.3, R.sub.4, and Z are as defined above (d) hydrolyzing the compound of Formula III formed in step "c" to form the compound of Formula I.The compound of Formula I may be polymerized. A preferred copolymer in accordance with the present invention is formed by polymerizing the compound of Formula I with a silicon compound having the formula ##STR5## where R.sub.3 and R.sub.4 are as defined above,X=halogen, OH, OR, NRR, or ureido,R is selected from the group consisting of a C.sub.1 to C.sub.6 alkyl group, an unsubstituted aryl group, and a substituted aryl groupsY=--O-- or ##STR6##This invention was made with United States Government support under Contract No. F336l5-86-C-508l awarded by the Department of the Air Force. The United States Government has certain rights in this invention.

    Ethynyl-substituted s-triazine derivatives, polymers thereof and process for making the same
    5.
    发明授权
    Ethynyl-substituted s-triazine derivatives, polymers thereof and process for making the same 失效
    乙炔基取代的三嗪衍生物，其聚合物及其制备方法

    公开(公告)号：US4442278A

    公开(公告)日：1984-04-10

    申请号：US326792

    申请日：1981-12-03

    申请人： Thomas W. Giants

    发明人： Thomas W. Giants

    IPC分类号： C08F38/00 ,  C08F126/06

    CPC分类号： C08F38/00

    摘要： Acetylene terminated s-triazine oligomers are disclosed which polymerize into stable high temperature resins. The oligomers of this invention are readily prepared from off-the-shelf starting materials, they are soluble in conventional low boiling solvents and exhibit low melting points which facilitate ease of processing.

    摘要翻译： 公开了聚合成稳定的高温树脂的乙炔封端的三嗪低聚物。 本发明的低聚物容易地由现成的原料制备，它们可溶于常规的低沸点溶剂，并且表现出低熔点，这便于加工。

    Integrated solar power module
    6.
    发明授权
    Integrated solar power module 有权
    集成太阳能发电模块

    公开(公告)号：US06300158B1

    公开(公告)日：2001-10-09

    申请号：US09649726

    申请日：2000-08-28

    申请人： Edward J. Simburger ,  James H. Matsumoto ,  Thomas W. Giants ,  Alec Garcia, III ,  Frank R. Jeffrey ,  Paul A. Gierow

    发明人： Edward J. Simburger ,  James H. Matsumoto ,  Thomas W. Giants ,  Alec Garcia, III ,  Frank R. Jeffrey ,  Paul A. Gierow

    IPC分类号： H01L2100

    CPC分类号： H01L21/00 ,  H01L31/042 ,  H01L31/0445 ,  H01L31/048 ,  H02S40/30 ,  H05K1/16 ,  Y02E10/50

    摘要： Multiple layers of a clear insulating material, such as clear polyimide, with horizontal metalization layers therebetween and with vertical feed through metal traces therethrough form a flexible three dimension circuit printed circuit board upon which semiconductor devices, such as thin film solar cell can be directly deposited for forming a flexible electronic module, and upon which electronic discrete component can be bonded and electrically connected. In one exemplar configuration, a flexible thin film solar cell power module has thin film solar cells deposited on one side and power converters bonded on the other for a solar array power system. The flexible printed circuit board is well suited for forming electronic systems about a curved surface such as a power sphere nanosatellite.

    摘要翻译： 多层透明绝缘材料，例如透明聚酰亚胺，其间具有水平金属化层并且穿过穿过金属迹线的垂直进料通过其形成柔性三维电路印刷电路板，半导体器件（例如薄膜太阳能电池）可以直接沉积在其上 用于形成柔性电子模块，并且可以将电子分立元件结合并电连接。 在一个示例性配置中，柔性薄膜太阳能电池功率模块具有沉积在一侧的薄膜太阳能电池和用于太阳能阵列电力系统的另一个电力转换器。 柔性印刷电路板非常适合于围绕弯曲表面形成电子系统，例如功率球纳米卫星。

    Ethynyl-phenylene-substituted-1,3,5-triazine derivatives and process for their production
    8.
    发明授权
    Ethynyl-phenylene-substituted-1,3,5-triazine derivatives and process for their production 失效
    乙炔基 - 亚苯基取代的1,3,5-三嗪衍生物及其制备方法

    公开(公告)号：US4497951A

    公开(公告)日：1985-02-05

    申请号：US487336

    申请日：1983-04-21

    申请人： Thomas W. Giants

    发明人： Thomas W. Giants

    IPC分类号： C08F38/00 ,  C07D253/04 ,  C07D403/10 ,  C07D403/12 ,  C07D403/14

    CPC分类号： C08F38/00

    摘要： Acetylene terminated s-triazine oligomers are disclosed which polymerize into stable high temperature resins. The oligomers of this invention are readily prepared from off-the-shelf starting materials, they are soluble in conventional low boiling solvents and exhibit low melting points which facilitate ease of processing.

    摘要翻译： 公开了聚合成稳定的高温树脂的乙炔封端的三嗪低聚物。 本发明的低聚物容易地由现成的原料制备，它们可溶于常规的低沸点溶剂，并且表现出低熔点，这便于加工。