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公开(公告)号：US4351933A
公开(公告)日：1982-09-28
申请号：US271745
申请日：1981-06-08
IPC分类号： B01D53/14 , B01J45/00 , C02F1/28 , C07D323/00 , C08F16/26 , C08F20/28 , C08F20/22 , C08F20/26
CPC分类号： B01J45/00 , B01D53/1493 , C02F1/285 , C07D323/00 , C08F16/26 , C08F20/28
摘要： Compounds represented by the formula: ##STR1## and addition polymers thereof where m is an integer from 2 to about 10, X-- is chlorine, hydroxy, carboxy or:--AC--R).dbd.CH.sub.2--R is hydrogen or methyl, --R--' is an ethylene or propylene group and--AC--R).dbd.CH.sub.2is one of: ##STR2## These compounds and their addition polymers form complexes with alkali metal or alkaline earth metal salts and permit the concentration of aqueous solutions of said salts. For example, a compound of the formula: ##STR3## is polymerized with an azobis (isobutyronitrile) catalyst to form addition polymers of the repeating unit ##STR4## When cross-linked, rendering it water-insoluble, such an addition polymer concentrates an aqueous solution of sodium chloride when contacted with same at about 0.degree. C.
摘要翻译： 由下式表示的化合物及其加成聚合物，其中m为2至约10的整数，X-为氯，羟基，羧基或：-AC-R）= CH 2 -R为氢或甲基，-R - '是乙烯或丙烯基，-AC-R）= CH 2是以下之一：这些化合物及其加成聚合物与碱金属或碱土金属盐形成络合物，并允许浓度为 说盐。 例如，下式的化合物与偶氮二（异丁腈）催化剂聚合以形成重复单元的加成聚合物。当交联时，使其不溶于水，这种加成聚合物将水 氯化钠在约0℃下与其接触时的溶液
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2.发明授权Metal salt complexes of vinyl-substituted cyclic polyether addition polymers 失效乙烯基取代的环状聚醚加成聚合物的金属盐络合物
公开(公告)号：US4256855A
公开(公告)日：1981-03-17
申请号：US961159
申请日：1978-11-16
IPC分类号： B01D53/14 , B01J45/00 , C02F1/28 , C07D323/00 , C08F16/26 , C08F20/28 , C08F20/06 , C08F24/00
CPC分类号： C02F1/285 , B01D53/1493 , B01J45/00 , C07D323/00 , C08F16/26 , C08F20/28
摘要： Compounds represented by the formula ##STR1## and addition polymers thereof where m is an integer from 2 to about 10, x--is chlorine, hydroxy, carboxy or--AC--R).dbd.CH.sub.2--R is hydrogen or methyl, --R' is an ethylene or propylene group and--AC--R).dbd.CH.sub.2is one of ##STR2## These compounds and their addition polymers form complexes with alkali metal or alkaline earth metal salts and permit the concentration of aqueous solutions of said salts. For example, a compound of the formula ##STR3## is polymerized with an azobis(isobutyronitrile) catalyst to form addition polymers of the repeating unit ##STR4## When cross-linked, rendering it water-insoluble, such an addition polymer concentrates an aqueous solution of sodium chloride when contacted with same at about 0.degree. C.
摘要翻译： 由下式表示的化合物及其加成聚合物，其中m为2至约10的整数，x为氯，羟基，羧基或-AC-R）= CH 2 -R为氢或甲基，-R'为 乙烯或丙烯基和-AC-R）= CH 2是这些化合物及其加成聚合物与碱金属或碱土金属盐形成络合物并允许浓缩所述盐的水溶液。 例如，将式（IMAGE）化合物与偶氮双（异丁腈）催化剂聚合以形成重复单元的加成聚合物。当交联时，使其不溶于水，这种加成聚合物将水溶液 的氯化钠在约0℃下与其接触
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公开(公告)号：US4331785A
公开(公告)日：1982-05-25
申请号：US107813
申请日：1979-12-28
IPC分类号： B01D53/14 , B01J45/00 , C02F1/28 , C07D323/00 , C08F8/44 , C08F16/26 , C08F20/28 , C08F8/42 , C08K3/10
CPC分类号： C08F20/28 , B01D53/1493 , B01J45/00 , C02F1/285 , C07D323/00 , C08F16/26 , C08F8/44
摘要： Compounds represented by the formula ##STR1## and addition polymers thereof where m is an integer from 2 to about 10, X- is chlorine, hydroxy, carboxy or-AC-R).dbd.CH.sub.2-R is hydrogen or methyl, -R' is an ethylene or propylene group and-AC-R).dbd.CH.sub.2is one of ##STR2## These compounds and their addition polymers form complexes with alkali metal or alkaline earth metal salts and permit the concentration of aqueous solutions of said salts. For example, a compound of the formula ##STR3## is polymerized with an azobis(isobutyronitrile) catalyst to form addition polymers of the repeating unit ##STR4## When cross-linked, rendering it water-insoluble, such an addition polymer concentrates an aqueous solution of sodium chloride when contacted with same at about 0.degree. C.
摘要翻译： 式中的化合物及其加成聚合物，其中m为2-约10的整数，X-为氯，羟基，羧基或-AC-R）= CH 2 -R为氢或甲基，-R'为 乙烯或丙烯基和-AC-R）= CH 2是这些化合物及其加成聚合物与碱金属或碱土金属盐形成络合物并允许浓缩所述盐的水溶液。 例如，将式（IMAGE）化合物与偶氮双（异丁腈）催化剂聚合以形成重复单元的加成聚合物。当交联时，使其不溶于水，这种加成聚合物将水溶液 的氯化钠在约0℃下与其接触
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公开(公告)号：US4139539A
公开(公告)日：1979-02-13
申请号：US751870
申请日：1976-12-17
IPC分类号： C07D323/00 , C08F16/26 , C08F20/28
CPC分类号： C07D323/00 , C08F16/26 , C08F20/28
摘要： Compounds represented by the formula ##STR1## AND ADDITION POLYMERS THEREOF WHERE M IS AN INTEGER FROM 2 TO ABOUT 10, X-- is chlorine, hydroxy, carboxy or--AC--(R).dbd.CH.sub.2--r is hydrogen or methyl, --R-- is an ethylene or propylene group and--AC--(R).dbd.CH.sub.2is one of ##STR2## These compounds and their addition polymers form complexes with alkali metal or alkaline earth metal salts and permit the concentration of aqueous solutions of said salts. For example, a compound of the formula ##STR3## is polymerized with an azobis(isobutyronitrile) catalyst to form addition polymers of the repeating unit ##STR4## When cross-linked, rendering it water-insoluble, such an addition polymer concentrates an aqueous solution of sodium chloride when contacted with same at about 0.degree. C.
摘要翻译： 由下式表示的化合物及其添加聚合物，其中M是从2到约10的整数，X-是氯，羟基，羧基或-AC-（R）= CH 2 -R是氢或甲基，-R- 是乙烯或丙烯基，-AC-（R）= CH 2是
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公开(公告)号：US5167946A
公开(公告)日：1992-12-01
申请号：US784141
申请日：1991-10-29
摘要： Diaryl carbonates are prepared by the catalyzed reaction of an aryl hydroxide with a carbonyl halide in the liquid phase at a temperature from greater than 100.degree. to less than 150.degree. C.
摘要翻译： 碳酸二芳基酯通过在大于100℃至小于150℃的温度下在液相中芳基氢氧化物与羰基卤的催化反应来制备。
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公开(公告)号：US4163718A
公开(公告)日：1979-08-07
申请号：US761555
申请日：1977-01-24
CPC分类号： C02F1/285 , B01J20/22 , Y10S210/909
摘要： Phenolics are complexed with acylated polyamines to form materials which are essentially water-insoluble. This phenomenon makes acylated polyamines particularly useful in removing phenolics from aqueous waste streams.
摘要翻译： 苯酚与酰化多胺络合形成基本上不溶于水的材料。 这种现象使得酰化多胺特别可用于从含水废物流中除去酚类物质。
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7.发明授权
公开(公告)号：US4011160A
公开(公告)日：1977-03-08
申请号：US639152
申请日：1975-12-09
摘要： Novel polymers are described herein which are particularly useful in removing phenolics from waste streams. The polymers are prepared by reacting an oxazoline or oxazine (preferably 2-methyl or ethyl-2-oxazoline) with a cross-linked vinylaromatic polymer bearing pendant halomethyl groups on the aromatic rings. Macroporous beads prepared by reacting cross-linked chloromethylated polystyrene with 2-methyl and/or 2-ethyl-2-oxazoline are particularly useful embodiments in removing phenolics from aqueous waste streams and are used to remove phenolics (e.g. tannins) and other color-bodies from bleached Kraft pulp effluent.
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8.发明授权
公开(公告)号：US4746735A
公开(公告)日：1988-05-24
申请号：US933503
申请日：1986-11-21
IPC分类号： C07D487/22
CPC分类号： C07D487/22
摘要： A process for the nitration of a tetraarylporphyrin compound such as tetraphenylporphyrin by use of a nitrating agent in a suitable solvent in the presence of an amount of sulfuric acid that is less than equimolar relative to the amount of nitrating agent.
摘要翻译： 在相对于硝化剂的量小于等摩尔量的硫酸存在下，通过使用硝化剂在合适的溶剂中硝化四芳基卟啉化合物如四苯基卟啉的方法。
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9.发明授权Novel complexes of polyoxazolines or polyoxazines and halogens, interhalogens or pseudohalogens and process for preparing same 失效聚恶唑啉或多恶嗪和卤素，间卤素或假卤素的新型络合物及其制备方法
公开(公告)号：US4186191A
公开(公告)日：1980-01-29
申请号：US968228
申请日：1978-12-11
CPC分类号： C08L79/04 , C08G73/0233
摘要： Novel solid complexes of 2-oxazoline and 2-oxazine polymers and halogens, interhalogens or pseudo-halogens are prepared by contacting a poly-2-oxazoline or poly-2-oxazine whose backbone comprises a plurality of ring-opened units of an oxazoline or oxazine monomer of the general formula ##STR1## wherein R and R.sub.1 -R.sub.4 are each independently hydrogen, alkyl, aralkyl, phenyl or inertly-substituted phenyl and n is zero or one with a halogen, interhalogen or pseudo-halogen. The complexes are soluble in a variety of conventional solvents (e.g., water, methylene chloride, acetonitrile, methanol, tetrahydrofuran and isopropanol).
摘要翻译： 2-恶唑啉和2-恶嗪聚合物和卤素，间卤素或假卤素的新型固体络合物通过使主链包含多个开环甲基恶唑啉单元的聚-2-恶唑啉或聚-2-恶嗪接触来制备， 恶嗪单体，其中R和R 1 -R 4各自独立地为氢，烷基，芳烷基，苯基或惰性取代的苯基，n为0或1为卤素，卤素或假卤素。 络合物可溶于各种常规溶剂（例如水，二氯甲烷，乙腈，甲醇，四氢呋喃和异丙醇）。
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10.发明授权
公开(公告)号：US3971730A
公开(公告)日：1976-07-27
申请号：US504020
申请日：1974-09-09
摘要： 1,1,1-Trichloroethane is prepared in the novel process comprising reacting by contacting chlorine monoxide with CH.sub. 3 --CH.sub.2 Cl and/or CH.sub.3 --CHCl.sub.2. The reaction is conducted in liquid phase and at a temperature of from about -20.degree. to about 80.degree.C.
摘要翻译： 在新方法中制备1,1,1-三氯乙烷，包括使一氧化氯与CH 3 -CH 2 Cl和/或CH 3 -CHClCl接触。 该反应在液相和约-20℃至约80℃的温度下进行。
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