公开(公告)号：US20160101988A1

公开(公告)日：2016-04-14

申请号：US14749212

申请日：2015-06-24

申请人： THE REGENTS OF THE UNIVERSITY OF CALIFORNIA

发明人： Matthew Law ,  Sean Seefeld ,  James Puthussery

IPC分类号： C01G49/12 ,  C23C16/22 ,  B05D1/18 ,  C23C16/56 ,  B05D1/00 ,  B05D1/02

CPC分类号： C01G49/12 ,  B05D1/005 ,  B05D1/02 ,  B05D1/18 ,  B82Y30/00 ,  B82Y40/00 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/32 ,  C01P2004/64 ,  C01P2006/22 ,  C23C16/22 ,  C23C16/305 ,  C23C16/4417 ,  C23C16/56 ,  H01L31/032 ,  H01L31/072 ,  Y02E10/50

摘要： Systems and methods are provided for the fabrication and manufacture of efficient, low-cost p-n heterojunction pyrite solar cells. The p-n heterojunction pyrite solar cells can include a pyrite thin cell component, a window layer component, and a top surface contact component. The pyrite thin cell component can be fabricated from nanocrystal paint deposited onto metal foils or microcrystalline pyrite deposited onto foil by chemical vapor deposition. A method of synthesizing colloidal pyrite nanocrystals is provided. Methods of manufacturing the efficient, low-cost p-n heterojunction pyrite solar cells are also provided.

摘要翻译： 提供了制造和制造高效，低成本的p-n异质结黄铁矿太阳能电池的系统和方法。 p-n异质结黄铁矿太阳能电池可以包括黄铁矿薄电池组件，窗口层组件和顶表面接触部件。 黄铁矿薄电池组件可以由沉积在通过化学气相沉积沉积到箔上的金属箔或微晶黄铁矿上的纳米晶体涂料制成。 提供了一种合成胶体黄铁矿纳米晶体的方法。 还提供了制造有效的低成本p-n异质结黄铁矿太阳能电池的方法。

公开(公告)号：US20150360255A1

公开(公告)日：2015-12-17

申请号：US14728927

申请日：2015-06-02

申请人： THE REGENTS OF THE UNIVERSITY OF CALIFORNIA

发明人： Matthew Law ,  Amanda S. Weber ,  Sean Seefeld ,  James Puthussery

IPC分类号： B05D1/00 ,  B05D1/02

CPC分类号： B05D1/005 ,  B05D1/02 ,  B05D3/0254 ,  B05D3/0453 ,  H01L31/0336 ,  H01L31/0368 ,  H01L31/1864 ,  Y02E10/50 ,  Y02P70/521

摘要： Systems and methods are provided for fabricating pyrite thin films from molecular inks. A process is provided that comprises dissolving simple iron-bearing and sulfur-bearing molecules in an appropriate solvent and then depositing the solution onto an appropriate substrate using one of several methods (roll-to-roll coating, spraying, spin coating, etc.), resulting in a solid film consisting of the molecules. These molecular precursor films are then heated to 200-600° C. in the presence of sulfur-bearing gases (e.g., S2, H2S) to convert the molecular films into films of crystalline iron pyrite (FeS2).

摘要翻译： 提供了从分子油墨制造黄铁矿薄膜的系统和方法。 提供了一种方法，其包括将简单的含铁和含硫分子溶解在合适的溶剂中，然后使用几种方法之一（辊对辊涂布，喷涂，旋涂等）将溶液沉积到合适的基材上， ，得到由分子组成的固体膜。 然后在含硫气体（例如S2，H2S）的存在下将这些分子前体膜加热至200-600℃，以将分子膜转化成结晶铁黄铁矿（FeS 2）的膜。

公开(公告)号：US20140205756A1

公开(公告)日：2014-07-24

申请号：US13799448

申请日：2013-03-13

申请人： The Regents Of The University Of California

发明人： Matthew Law ,  Amanda S. Weber ,  Sean Seefeld ,  James Puthussery

IPC分类号： H01L31/18

CPC分类号： B05D1/005 ,  B05D1/02 ,  B05D3/0254 ,  B05D3/0453 ,  H01L31/0336 ,  H01L31/0368 ,  H01L31/1864 ,  Y02E10/50 ,  Y02P70/521

摘要： Systems and methods are provided for fabricating pyrite thin films from molecular inks. A process is provided that comprises dissolving simple iron-bearing and sulfur-bearing molecules in an appropriate solvent and then depositing the solution onto an appropriate substrate using one of several methods (roll-to-roll coating, spraying, spin coating, etc.), resulting in a solid film consisting of the molecules. These molecular precursor films are then heated to 200-600° C. in the presence of sulfur-bearing gases (e.g., S2, H2S) to convert the molecular films into films of crystalline iron pyrite (FeS2).

摘要翻译： 提供了从分子油墨制造黄铁矿薄膜的系统和方法。 提供了一种方法，其包括将简单的含铁和含硫分子溶解在合适的溶剂中，然后使用几种方法之一（辊对辊涂布，喷涂，旋涂等）将溶液沉积到合适的基材上， ，得到由分子组成的固体膜。 然后在含硫气体（例如S2，H2S）的存在下将这些分子前体膜加热至200-600℃，以将分子膜转化成结晶铁黄铁矿（FeS 2）的膜。

公开(公告)号：US09862617B2

公开(公告)日：2018-01-09

申请号：US14749212

申请日：2015-06-24

申请人： THE REGENTS OF THE UNIVERSITY OF CALIFORNIA

发明人： Matthew Law ,  Sean Seefeld ,  James Puthussery

IPC分类号： B05D5/12 ,  C01G49/12 ,  B82Y30/00 ,  B82Y40/00 ,  C23C16/30 ,  C23C16/44 ,  H01L31/032 ,  H01L31/072 ,  B05D1/00 ,  B05D1/02 ,  B05D1/18 ,  C23C16/22 ,  C23C16/56

CPC分类号： C01G49/12 ,  B05D1/005 ,  B05D1/02 ,  B05D1/18 ,  B82Y30/00 ,  B82Y40/00 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/32 ,  C01P2004/64 ,  C01P2006/22 ,  C23C16/22 ,  C23C16/305 ,  C23C16/4417 ,  C23C16/56 ,  H01L31/032 ,  H01L31/072 ,  Y02E10/50

摘要： Systems and methods are provided for the fabrication and manufacture of efficient, low-cost p-n heterojunction pyrite solar cells. The p-n heterojunction pyrite solar cells can include a pyrite thin cell component, a window layer component, and a top surface contact component. The pyrite thin cell component can be fabricated from nanocrystal paint deposited onto metal foils or microcrystalline pyrite deposited onto foil by chemical vapor deposition. A method of synthesizing colloidal pyrite nanocrystals is provided. Methods of manufacturing the efficient, low-cost p-n heterojunction pyrite solar cells are also provided.

公开(公告)号：US09757765B2

公开(公告)日：2017-09-12

申请号：US14728927

申请日：2015-06-02

申请人： THE REGENTS OF THE UNIVERSITY OF CALIFORNIA

发明人： Matthew Law ,  Amanda S. Weber ,  Sean Seefeld ,  James Puthussery

IPC分类号： B05D3/02 ,  B05D3/04 ,  B05D1/00 ,  H01L31/18 ,  B05D1/02 ,  H01L31/0336 ,  H01L31/0368

CPC分类号： B05D1/005 ,  B05D1/02 ,  B05D3/0254 ,  B05D3/0453 ,  H01L31/0336 ,  H01L31/0368 ,  H01L31/1864 ,  Y02E10/50 ,  Y02P70/521

摘要： Systems and methods are provided for fabricating pyrite thin films from molecular inks. A process is provided that comprises dissolving simple iron-bearing and sulfur-bearing molecules in an appropriate solvent and then depositing the solution onto an appropriate substrate using one of several methods (roll-to-roll coating, spraying, spin coating, etc.), resulting in a solid film consisting of the molecules. These molecular precursor films are then heated to 200-600° C. in the presence of sulfur-bearing gases (e.g., S2, H2S) to convert the molecular films into films of crystalline iron pyrite (FeS2).

公开(公告)号：US09048375B2

公开(公告)日：2015-06-02

申请号：US13799448

申请日：2013-03-13

申请人： THE REGENTS OF THE UNIVERSITY OF CALIFORNIA

发明人： Matthew Law ,  Amanda S. Weber ,  Sean Seefeld ,  James Puthussery

IPC分类号： B05D1/02 ,  B05D3/02 ,  H01L31/18 ,  B05D3/04 ,  B05D1/00

CPC分类号： B05D1/005 ,  B05D1/02 ,  B05D3/0254 ,  B05D3/0453 ,  H01L31/0336 ,  H01L31/0368 ,  H01L31/1864 ,  Y02E10/50 ,  Y02P70/521

摘要： Systems and methods are provided for fabricating pyrite thin films from molecular inks. A process is provided that comprises dissolving simple iron-bearing and sulfur-bearing molecules in an appropriate solvent and then depositing the solution onto an appropriate substrate using one of several methods (roll-to-roll coating, spraying, spin coating, etc.), resulting in a solid film consisting of the molecules. These molecular precursor films are then heated to 200-600° C. in the presence of sulfur-bearing gases (e.g., S2, H2S) to convert the molecular films into films of crystalline iron pyrite (FeS2).

摘要翻译： 提供了从分子油墨制造黄铁矿薄膜的系统和方法。 提供了一种方法，其包括将简单的含铁和含硫分子溶解在合适的溶剂中，然后使用几种方法之一（辊对辊涂布，喷涂，旋涂等）将溶液沉积到合适的基材上， ，得到由分子组成的固体膜。 然后在含硫气体（例如S2，H2S）的存在下将这些分子前体膜加热至200-600℃，以将分子膜转化成结晶铁黄铁矿（FeS 2）的膜。