公开(公告)号：US5631341A

公开(公告)日：1997-05-20

申请号：US570473

申请日：1995-12-11

申请人： Takeshi Morishima ,  Shin Konishi ,  Shinjiro Hama

发明人： Takeshi Morishima ,  Shin Konishi ,  Shinjiro Hama

IPC分类号： C08G18/65 ,  C08G18/08 ,  C08G18/28 ,  C08G18/36 ,  C08G18/70 ,  C08G18/79 ,  C08G18/80 ,  C09D5/00 ,  C09D175/00 ,  C09D175/04 ,  C09D175/08 ,  C09J175/08 ,  C08G18/10

CPC分类号： C08G18/283 ,  C08G18/0823 ,  C08G18/36 ,  C08G18/706 ,  C08G18/79 ,  C08G18/798 ,  C08G18/8009 ,  C08G18/8012 ,  C08G18/8064 ,  C08G2170/80 ,  Y10S528/905

摘要： A self-emulsifiable polyisocyanate mixture having a hexamethylene diisocyanate monomer content of not more than 1.0% by weight and an average NCO functionality of 2.0 to 3.7 obtained by subjecting hexamethylene diisocyanate to urethanation with a branched dihydric alcohol having overall 4 to 35 carbon atoms, of which 2 to 33 carbon atoms are a total number of the carbon atoms possessed by one or more branches, a hydrophilic surfactant having one or more active hydrogen atoms capable of reacting with NCO group and 3 to 90 alkylene oxide units, an aliphatic compound having one or more active hydrogen atoms capable of reacting with NCO group and 8 or more carbon atoms and an unbranched glycol having 1 to 10 carbon atoms; uretdione-forming reaction; and isocyanurate-forming reaction. Said self-emulsifiable polyisocyanate mixture is excellent in compatibility, dispersion stability and NCO group-stability and can be combined with water or a water-soluble resin and/or an aqueous emulsion, and if necessary, an additive to provide an aqueous coating or adhesive composition excellent in heat resistance, workability, coating film appearance, weather resistance and adhesion to substrate.

摘要翻译： 具有六亚甲基二异氰酸酯单体含量不大于1.0重量％且平均NCO官能度为2.0-3.7的自乳化多异氰酸酯混合物，其通过使六亚甲基二异氰酸酯与具有总共4至35个碳原子的支化二元醇进行氨基甲酸酯化反应得到 其中2至33个碳原子是一个或多个分支具有的碳原子总数，具有一个或多个能够与NCO基团反应的活性氢原子和3至90个环氧烷单元的亲水性表面活性剂，具有一个 或更多能够与NCO基团和8个或更多个碳原子反应的活性氢原子和具有1-10个碳原子的未分支的二醇; 脲二酮形成反应; 和异氰脲酸酯形成反应。 所述自乳化多异氰酸酯混合物的相容性，分散稳定性和NCO基团稳定性优异，并且可以与水或水溶性树脂和/或水乳液组合，并且如果需要，可提供添加剂以提供水性涂料或粘合剂 耐热性，加工性，涂膜外观，耐候性和与基材的粘合性优异的组合物。

公开(公告)号：US6080812A

公开(公告)日：2000-06-27

申请号：US373543

申请日：1999-08-13

申请人： Takeshi Morishima ,  Shogo Itoh ,  Shin Konishi

发明人： Takeshi Morishima ,  Shogo Itoh ,  Shin Konishi

IPC分类号： C08G18/70 ,  C08G18/80 ,  C08J3/00 ,  C08G18/81 ,  C08K3/20 ,  C08L75/00

CPC分类号： C08G18/706 ,  C08G18/8016 ,  C08G18/8051 ,  C08G18/807 ,  C08G2105/02 ,  C08G2170/80

摘要： A water-dispersible blocked isocyanate composition, including an isocyanate group-terminated precursor and a blocking agent for blocking a free isocyanate group of the precursor, wherein the precursor includes at least an organic diisocyanate, a low-molecular glycol, and a hydrophilic surfactant having at least one active hydrogen group. The precursor also has an isocyanurate ring structure; an average functional group number (f) satisfying 2.0.ltoreq.f.ltoreq.4.2; a low-molecular glycol content (X) satisfying 0.5 wt. %.ltoreq..times..ltoreq.15 wt. %; and a hydrophilic surfactant content(Y) satisfying 0.1 wt. %.ltoreq.Y.ltoreq.50 wt. %.

摘要翻译： 一种水分散性封端异氰酸酯组合物，其包括异氰酸酯基封端的前体和用于封闭前体的游离异氰酸酯基的封闭剂，其中前体包括至少一种有机二异氰酸酯，低分子量二醇和亲水性表面活性剂，其具有 至少一个活性氢基团。 前体还具有异氰脲酸酯环结构; 平均官能团数（f）满足2.0

公开(公告)号：US06306947B1

公开(公告)日：2001-10-23

申请号：US09320718

申请日：1999-05-27

申请人： Takeshi Morishima ,  Shunsuke Murakami ,  Toshiaki Sasahara ,  Shin Konishi ,  Kazuya Sugimoto

发明人： Takeshi Morishima ,  Shunsuke Murakami ,  Toshiaki Sasahara ,  Shin Konishi ,  Kazuya Sugimoto

IPC分类号： C08F26108

CPC分类号： C09D11/10 ,  C08F283/006 ,  C08G18/0819 ,  C08G18/3876 ,  C08G18/4277 ,  C08G18/6659 ,  C09D175/04 ,  Y10S525/92

摘要： An aqueous emulsion which comprises as a resin component a self-emulsifiable copolymer in which at least one ethylenically unsaturated monomer and at least one urethane prepolymer having at least one mercapto group and at least one hydrophilic, polar group are bonded by radical polymerization or in which at least one ethylenically unsaturated monomer, at least one organic polyisocyanate, at least one compound having at least one mercapto group and at least one active hydrogen-containing group and at least one compound having at least one hydrophilic, polar group and at least one active hydrogen-containing group are bonded by urethanization reaction and radical polymerization. The aqueous emulsion is better in storage stability than conventional ones.

摘要翻译： 一种水性乳液，其包含作为树脂组分的自乳化共聚物，其中至少一种烯键式不饱和单体和至少一种具有至少一个巯基和至少一个亲水性极性基团的氨基甲酸酯预聚物通过自由基聚合键合，或其中 至少一种烯键式不饱和单体，至少一种有机多异氰酸酯，至少一种具有至少一个巯基和至少一个含活性氢基团的化合物和至少一种具有至少一个亲水性极性基团和至少一种活性基团的化合物 含氢基团通过氨基甲酸酯化反应和自由基聚合键合。 水乳液的储存稳定性优于常规乳液。

公开(公告)号：US5998539A

公开(公告)日：1999-12-07

申请号：US946216

申请日：1997-10-07

申请人： Takeshi Morishima ,  Shogo Itoh ,  Shin Konishi

发明人： Takeshi Morishima ,  Shogo Itoh ,  Shin Konishi

IPC分类号： C08G18/70 ,  C08G18/80 ,  C08J3/00 ,  C08K3/20 ,  C08L75/00

CPC分类号： C08G18/706 ,  C08G18/8016 ,  C08G18/8051 ,  C08G18/807 ,  C08G2105/02 ,  C08G2170/80

摘要： A water-dispersible blocked isocyanate composition, including an isocyanate group-terminated precursor and a blocking agent for blocking a free isocyanate group of the precursor, wherein the precursor includes at least an organic diisocyanate, a low-molecular glycol, and a hydrophilic surfactant having at least one active hydrogen group. The precursor also has an isocyanurate ring structure; an average functional group number (f) satisfying 2.0.ltoreq.f.ltoreq.4.2; a low-molecular glycol content (X) satisfying 0.5 wt. %.ltoreq.X .ltoreq.15 wt. %; and a hydrophilic surfactant content(Y) satisfying 0.1 wt. % .ltoreq.Y.ltoreq.50 wt. %.

摘要翻译： 一种水分散性封端异氰酸酯组合物，其包括异氰酸酯基封端的前体和用于封闭前体的游离异氰酸酯基的封闭剂，其中前体包括至少一种有机二异氰酸酯，低分子量二醇和亲水性表面活性剂，其具有 至少一个活性氢基团。 前体还具有异氰脲酸酯环结构; 平均官能团数（f）满足2.0

公开(公告)号：US20050255830A1

公开(公告)日：2005-11-17

申请号：US10845558

申请日：2004-05-13

申请人： Dean Thorson ,  Michael Kinnavy ,  Takeshi Morishima

发明人： Dean Thorson ,  Michael Kinnavy ,  Takeshi Morishima

IPC分类号： H04M1/68 ,  H04W12/12

CPC分类号： H04W12/12

摘要： A method (400) and corresponding data processing system (209) of detecting cloned or duplicated communication units based on received signals is described. The method comprise receiving a signal (403) comprising a sequence of data symbols; and determining (405) whether the signal originated from a plurality of communication units based on a parameter, such as power or quality level of a group of the data symbols.

摘要翻译： 描述了基于接收到的信号检测克隆或复制的通信单元的方法（400）和相应的数据处理系统（209）。 该方法包括接收包括数据符号序列的信号（403）; 以及基于诸如数据符号组的功率或质量水平的参数来确定（405）来自多个通信单元的信号。

公开(公告)号：US11679379B2

公开(公告)日：2023-06-20

申请号：US17734702

申请日：2022-05-02

申请人： Koji Sugiura ,  Takeshi Hirabayashi ,  Akemi Satou ,  Keisuke Murawaki ,  Takaya Ota ,  Masatoshi Ikebe ,  Kohei Takasaki ,  Takeshi Morishima

发明人： Koji Sugiura ,  Takeshi Hirabayashi ,  Akemi Satou ,  Keisuke Murawaki ,  Takaya Ota ,  Masatoshi Ikebe ,  Kohei Takasaki ,  Takeshi Morishima

IPC分类号： B01J35/00 ,  B01J35/04 ,  F01N3/28 ,  B01D53/94

CPC分类号： B01J35/0006 ,  B01D53/94 ,  B01J35/04 ,  F01N3/2828 ,  B01D2255/1021 ,  B01D2255/1025 ,  B01D2255/407 ,  B01D2255/9022 ,  B01D2255/9205 ,  F01N2330/06 ,  F01N2330/48 ,  F01N2370/02 ,  F01N2510/06

摘要： The exhaust gas purification device includes a substrate, a first catalyst layer, and a second catalyst layer. The substrate includes an upstream end, a downstream end, and a porous partition wall defining a plurality of cells extending between the upstream end and the downstream end. The plurality of cells include an inlet cell opening at the upstream end and sealed at the downstream end, and an outlet cell adjacent to the inlet cell sealed at the upstream end and opening at the downstream end. The first catalyst layer is disposed on a surface of the partition wall in an upstream region. In a downstream region, the second catalyst layer is disposed inside the partition wall, and a second catalyst-containing wall including the partition wall and the second catalyst layer has a porosity of 35% or more.

公开(公告)号：US07405258B2

公开(公告)日：2008-07-29

申请号：US10591422

申请日：2005-02-01

申请人： Naotaka Izumi ,  Takeshi Morishima ,  Iku Ohki ,  Mitsushige Ikemoto

发明人： Naotaka Izumi ,  Takeshi Morishima ,  Iku Ohki ,  Mitsushige Ikemoto

IPC分类号： C08J3/00 ,  C08K3/20 ,  C08L75/00

CPC分类号： C08G18/283 ,  C08G18/0823 ,  C08G18/092 ,  C08G18/12 ,  C08G18/44 ,  C08G18/6659 ,  C08G18/706 ,  C09D5/022 ,  C09D175/04 ,  C08G18/302 ,  C08G18/3234

摘要： [PROBLEMS] The invention is to provide an aqueous one-component coating agent that is environmentally friendly and safe, and is excellent in productivity and storage stability, and also in alkali resistance and solvent resistance of a coated film.[MEANS FOR SOLVING PROBLEMS] The problems are solved by providing a method for producing polyurethane emulsion for an aqueous one-component coating agent, comprising: reacting an organic diisocyanate (a1), a high molecular weight polyol (a2) and a low molecular weight glycol containing a carboxyl group (a3) to produce an isocyanate-terminated urethane prepolymer having a carboxyl group (A); mixing the urethane prepolymer (A) with a polyisocyanate containing a nonionic polar group (B); neutralizing the carboxyl group in the system with a neutralizing agent (C); and subjecting the mixture to emulsification in water and chain extension with water or an amine.

摘要翻译： 本发明提供一种环保且安全的水性单组分涂布剂，其生产率和储存稳定性优异，并且还具有涂膜的耐碱性和耐溶剂性。 解决问题的手段通过提供一种单组分涂料的水溶性聚氨酯乳液的制造方法，能够解决上述问题，该方法包括：使有机二异氰酸酯（a1），高分子量多元醇（a2）与低分子量 含有羧基（a3）的二醇以制备具有羧基（A）的异氰酸酯封端的氨基甲酸酯预聚物; 将氨基甲酸酯预聚物（A）与含有非极性基团（B）的多异氰酸酯混合; 用中和剂（C）中和体系中的羧基; 并将混合物在水中乳化并用水或胺延伸链。

公开(公告)号：US4308288A

公开(公告)日：1981-12-29

申请号：US128508

申请日：1980-03-10

申请人： Jun Hara ,  Masao Takeuchi ,  Takeshi Morishima

发明人： Jun Hara ,  Masao Takeuchi ,  Takeshi Morishima

IPC分类号： A23G1/30 ,  A23G1/00 ,  A23G1/04

CPC分类号： A23G1/047

摘要： Improved granular cocoa which is sufficiently dense and stiff but nevertheless is readily soluble in water, even in cold water, can be produced without using any binder by subjecting a cocoa powder of which fat content is 12-29% to compression, feeding the compressed powder to a roller press thereby forming small plate-like agglomerates which are 0.5-3 mm thick, and crushing and sifting the agglomerates to obtain 10-30 mesh granules of cocoa. The physical properties of the cocoa granules are further improved by ageing the granules at temperatures below about 27.degree. C., most preferably at 15-25.degree. C., for a few hours to several days. the starting cocoa powder may have been added with powdered sugar and/or milk.

摘要翻译： 通过使脂肪含量为12-29％的可可粉进行压缩，即使在冷水中也可容易地溶解于水中，即使在冷水中也可以制备改进的颗粒状可可，而不使用任何粘合剂，将压缩粉末 到辊压机上，从而形成0.5-3mm厚的小板状团聚体，并且对附聚物进行粉碎和筛分以获得10-30目可可的颗粒。 通过在低于约27℃，最优选15-25℃的温度下使颗粒老化数小时至数天，可以进一步提高可可颗粒的物理性能。 起始的可可粉可以加入糖粉和/或牛奶。

公开(公告)号：US12036510B2

公开(公告)日：2024-07-16

申请号：US17717690

申请日：2022-04-11

申请人： Akemi Sato ,  Takeshi Hirabayashi ,  Koji Sugiura ,  Keisuke Murawaki ,  Takaya Ota ,  Masatoshi Ikebe ,  Kohei Takasaki ,  Takeshi Morishima

发明人： Akemi Sato ,  Takeshi Hirabayashi ,  Koji Sugiura ,  Keisuke Murawaki ,  Takaya Ota ,  Masatoshi Ikebe ,  Kohei Takasaki ,  Takeshi Morishima

IPC分类号： B01D53/94

CPC分类号： B01D53/94 ,  B01D2255/1021 ,  B01D2255/1025 ,  B01D2255/2042 ,  B01D2255/2065 ,  B01D2255/20715 ,  B01D2255/407 ,  B01D2255/9155 ,  F01N2330/60 ,  F01N2510/0682

摘要： An exhaust gas purification device suppresses a pressure loss increase and includes a honeycomb substrate and inflow cell side catalyst layer. The substrate includes a porous partition wall defining several cells extending from an inflow side end surface to an outflow side end surface. The cells include an inflow and outflow cell adjacent across the wall. The inflow cell has an open inflow side end and sealed outflow side end. The outflow cell has a sealed inflow side end and open outflow side end. The catalyst layer is on an inflow cell side surface in an region extending from the inflow side end positioned 10% or more of the partition wall length. At this position, a filled portion of the inflow cell side catalyst layer pores are 40% or less. The pores are present to a depth of 50% of a thickness of the partition wall.

公开(公告)号：US20070155894A1

公开(公告)日：2007-07-05

申请号：US10591422

申请日：2005-02-01

申请人： Naotaka Izumi ,  Takeshi Morishima ,  Iku Ohki ,  Mitsushige Ikemoto

发明人： Naotaka Izumi ,  Takeshi Morishima ,  Iku Ohki ,  Mitsushige Ikemoto

IPC分类号： C08G18/08

CPC分类号： C08G18/283 ,  C08G18/0823 ,  C08G18/092 ,  C08G18/12 ,  C08G18/44 ,  C08G18/6659 ,  C08G18/706 ,  C09D5/022 ,  C09D175/04 ,  C08G18/302 ,  C08G18/3234

摘要： [PROBLEMS] The invention is to provide an aqueous one-component coating agent that is environmentally friendly and safe, and is excellent in productivity and storage stability, and also in alkali resistance and solvent resistance of a coated film. [MEANS FOR SOLVING PROBLEMS] The problems are solved by providing a method for producing polyurethane emulsion for an aqueous one-component coating agent, comprising: reacting an organic diisocyanate (a1), a high molecular weight polyol (a2) and a low molecular weight glycol containing a carboxyl group (a3) to produce an isocyanate-terminated urethane prepolymer having a carboxyl group (A); mixing the urethane prepolymer (A) with a polyisocyanate containing a nonionic polar group (B); neutralizing the carboxyl group in the system with a neutralizing agent (C); and subjecting the mixture to emulsification in water and chain extension with water or an amine.

摘要翻译： 本发明提供一种环保且安全的水性单组分涂布剂，其生产率和储存稳定性优异，并且还具有涂膜的耐碱性和耐溶剂性。 解决问题的手段通过提供一种单组分涂料的水溶性聚氨酯乳液的制造方法，能够解决上述问题，该方法包括：使有机二异氰酸酯（a1），高分子量多元醇（a2）与低分子量 含有羧基（a3）的二醇以制备具有羧基（A）的异氰酸酯封端的氨基甲酸酯预聚物; 将氨基甲酸酯预聚物（A）与含有非极性基团（B）的多异氰酸酯混合; 用中和剂（C）中和体系中的羧基; 并将混合物在水中乳化并用水或胺延伸链。