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    Desulphurization process comprising a transformation step and a step for extracting sulphur-containing compounds
    1.
    发明授权
    Desulphurization process comprising a transformation step and a step for extracting sulphur-containing compounds 有权
    脱硫方法包括转化步骤和提取含硫化合物的步骤

    公开(公告)号：US07670477B2

    公开(公告)日：2010-03-02

    申请号：US11643945

    申请日：2006-12-22

    Applicant: Sylvain Louret ,  Florent Picard

    Inventor： Sylvain Louret ,  Florent Picard

    IPC: C10G45/00

    CPC classification number: B01D3/143 ,  B01D3/141 ,  C10G21/12 ,  C10G21/28 ,  C10G45/40 ,  C10G67/04 ,  C10G2400/02

    Abstract: A process and the use of a process for desulphurizing a hydrocarbon feed is described which comprises at least one of the following steps: A a step for selective hydrogenation of diolefins present in said initial hydrocarbon feed, in the presence of a catalyst comprising a metal from group VIII of the periodic table on an inert support based on metal oxides, in the presence of a quantity of hydrogen which is in excess with respect to the stoichiometric value necessary for hydrogenating all of said diolefins, the mole ratio between the hydrogen and the diolefins being in the range 1 to 5; b) Extraction, using an appropriate solvent, of said hydrogenated fraction to obtain at least two cuts including: a raffinate comprising the majority of the olefins, paraffins and naphthenes and a reduced quantity of sulphur-containing compounds contained in the initial feed; a heavy fraction containing the heavy aromatic hydrocarbons and the majority of the sulphur-containing compounds contained in the initial feed; C a step for regenerating the solvent by distillation; at least two of steps A, B and C being carried out jointly.

    Abstract translation: 描述了一种方法和使用一种用于对烃进料进行脱硫的方法，其包括以下步骤中的至少一个：在存在催化剂的情况下，存在于所述初始烃进料中的二烯烃的选择性氢化步骤，所述催化剂包含来自 在相对于氢化所有二烯烃所需的化学计量值过量的氢气存在下，基于金属氧化物的惰性载体上的元素周期表VIII族，氢和二烯烃之间的摩尔比 在1到5的范围内; b）使用合适的溶剂萃取所述氢化馏分以获得至少两个馏分，包括：包含大部分烯烃，链烷烃和环烷烃的萃余液和初始进料中所含的含硫化合物的量减少; 含有重芳香烃和包含在初始进料中的大部分含硫化合物的重馏分; C通过蒸馏再生溶剂的步骤; 步骤A，B和C中的至少两个共同执行。

    Desulphurization process comprising a transformation step and a step for extracting sulphur-containing compounds
    2.
    发明申请
    Desulphurization process comprising a transformation step and a step for extracting sulphur-containing compounds 有权
    脱硫方法包括转化步骤和提取含硫化合物的步骤

    公开(公告)号：US20070170097A1

    公开(公告)日：2007-07-26

    申请号：US11643945

    申请日：2006-12-22

    Applicant: Sylvain Louret ,  Florent Picard

    Inventor： Sylvain Louret ,  Florent Picard

    IPC: C10G45/00 ,  C10G17/00

    CPC classification number: B01D3/143 ,  B01D3/141 ,  C10G21/12 ,  C10G21/28 ,  C10G45/40 ,  C10G67/04 ,  C10G2400/02

    Abstract: A process and the use of a process for desulphurizing a hydrocarbon feed is described which comprises at least one of the following steps: A a step for selective hydrogenation of diolefins present in said initial hydrocarbon feed, in the presence of a catalyst comprising a metal from group VIII of the periodic table on an inert support based on metal oxides, in the presence of a quantity of hydrogen which is in excess with respect to the stoichiometric value necessary for hydrogenating all of said diolefins, the mole ratio between the hydrogen and the diolefins being in the range 1 to 5; b) Extraction, using an appropriate solvent, of said hydrogenated fraction to obtain at least two cuts including: a raffinate comprising the majority of the olefins, paraffins and naphthenes and a reduced quantity of sulphur-containing compounds contained in the initial feed; a heavy fraction containing the heavy aromatic hydrocarbons and the majority of the sulphur-containing compounds contained in the initial feed; C a step for regenerating the solvent by distillation; at least two of steps A, B and C being carried out jointly.

    Abstract translation: 描述了一种方法和使用一种用于对烃进料进行脱硫的方法，其包括以下步骤中的至少一个：在存在催化剂的情况下，存在于所述初始烃进料中的二烯烃的选择性氢化步骤，所述催化剂包含来自 在相对于氢化所有二烯烃所需的化学计量值过量的氢气存在下，基于金属氧化物的惰性载体上的元素周期表VIII族，氢和二烯烃之间的摩尔比 在1到5的范围内; b）使用合适的溶剂萃取所述氢化馏分以获得至少两个馏分，包括：包含大部分烯烃，链烷烃和环烷烃的萃余液和初始进料中所含的含硫化合物的量减少; 含有重芳香烃和包含在初始进料中的大部分含硫化合物的重馏分; C通过蒸馏再生溶剂的步骤; 步骤A，B和C中的至少两个共同执行。

    Process for desulphurizing gasoline by converting sulphur-containing compounds to higher boiling point compounds
    3.
    发明授权
    Process for desulphurizing gasoline by converting sulphur-containing compounds to higher boiling point compounds 有权
    通过将含硫化合物转化为高沸点化合物来脱硫汽油的方法

    公开(公告)号：US07504022B2

    公开(公告)日：2009-03-17

    申请号：US11405676

    申请日：2006-04-18

    Applicant: Florent Picard

    Inventor： Florent Picard

    IPC: C10G25/05 ,  C07C2/54

    CPC classification number: C10G17/095 ,  C10G25/05

    Abstract: A process for desulphurizing a gasoline cut containing olefins, sulphur-containing compounds and optionally molecules belonging to C3 and C4 cuts comprises at least a first step A for contacting said gasoline cut with an acidic resin having an acid capacity of more than 4.7 equivalents per kg and a specific surface area of less than 55 m2/g, and a second step B for fractionation of the mixture from the first step.

    Abstract translation: 含有烯烃，含硫化合物和任选地分别属于C3和C4馏分的汽油馏分的脱硫方法包括至少第一步骤A，用于使所述汽油馏分与酸容量大于4.7当量/ kg的酸性树脂接触 比表面积小于55m2 / g，第二步骤B从第一步骤中分离出混合物。

    Integral method for desulphurization of a hydrocarbon cracking or stream cracking effluent
    5.
    发明授权
    Integral method for desulphurization of a hydrocarbon cracking or stream cracking effluent 失效
    烃裂化或流裂解流出物脱硫的整体方法

    公开(公告)号：US07344635B2

    公开(公告)日：2008-03-18

    申请号：US10503807

    申请日：2003-01-22

    Applicant: Patrick Briot ,  Pierre Boucot ,  Alain Forestiere ,  Nathalie Marchal-George ,  Florent Picard

    Inventor： Patrick Briot ,  Pierre Boucot ,  Alain Forestiere ,  Nathalie Marchal-George ,  Florent Picard

    IPC: C10G45/02

    CPC classification number: C10G69/123 ,  C10G29/205

    Abstract: Process for desulfurization of an effluent for cracking or steam-cracking hydrocarbons, more particularly a gasoline for example for catalytic cracking that comprises the elimination of thiophenic compounds by alkylation of these compounds, followed by a distillation, a hydrocracking of said alkyl-thiophenic compounds, then a hydrodesulfurization of the effluent that is obtained from the hydrocracking zone. In a preferred embodiment, this process comprises a preliminary stage for separating the cracking or steam-cracking effluent into three fractions, and proposes sending to the alkylation stage only the intermediate fraction that is low in heavy basic nitrogen-containing compounds that are initially present in the effluents that are to be alkylated.

    Abstract translation: 用于裂化或蒸汽裂解烃的流出物的脱硫方法，更具体地，例如用于催化裂解的汽油，其包括通过这些化合物的烷基化除去噻吩化合物，然后蒸馏，所述烷基 - 噻吩化合物的加氢裂化， 然后从加氢裂化区获得的流出物的加氢脱硫。 在优选的实施方案中，该方法包括用于将裂化或蒸汽裂解流出物分离成三个馏分的初步阶段，并且建议仅向最初存在于重质碱性含氮化合物中的低碱性含氮化合物的中间馏分 待烷基化的废水。

    Selective hydrogenation process employing a catalyst having a controlled porosity
    7.
    发明申请
    Selective hydrogenation process employing a catalyst having a controlled porosity 有权
    选择性氢化方法采用具有受控孔隙率的催化剂

    公开(公告)号：US20070170098A1

    公开(公告)日：2007-07-26

    申请号：US11642976

    申请日：2006-12-21

    Applicant: Christophe Bouchy ,  Florent Picard ,  Nathalie Marchal

    Inventor： Christophe Bouchy ,  Florent Picard ,  Nathalie Marchal

    IPC: C10G29/00

    CPC classification number: B01J35/10 ,  B01J23/85 ,  B01J23/883 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/108 ,  B01J37/20 ,  C10G45/38 ,  C10G2300/104 ,  C10G2300/1044 ,  C10G2300/4018

    Abstract: A process for jointly carrying out selective hydrogenation of polyunsaturated compounds into monounsaturated compounds contained in gasolines, and for transforming light sulphur-containing compounds into heavier compounds by reaction with unsaturated compounds employing a supported catalyst, comprising at least one metal from group VIB and at least one non-noble metal from group VIII used in the sulphurized form deposited on a support and having a controlled porosity, and comprising bringing the feed into contact with the catalyst at a temperature in the range of 80° C. to 220° C. at a liquid hourly space velocity in the range of 1 h−1 to 10 h−1 and at a pressure in the range of 0.5 to 5 MPa.

    Abstract translation: 一种将多不饱和化合物选择氢化成汽油中所含的单不饱和化合物的方法，以及使用负载型催化剂与不饱和化合物反应，将轻含硫化合物转化为较重的化合物的方法，所述催化剂包含至少一种来自VIB族的金属，至少 用于硫化形式的第VIII族的一种非贵金属沉积在载体上并具有受控的孔隙率，并且包括使进料在80℃至220℃的温度范围内与催化剂接触 在1小时-1小时至10小时-1的范围内的液时空速和0.5-5MPa的压力。

    Process for hydrodesulphurizing gasoline employing a catalyst with controlled porosity
    10.
    发明授权
    Process for hydrodesulphurizing gasoline employing a catalyst with controlled porosity 有权
    使用具有受控孔隙率的催化剂加氢脱硫汽油的方法

    公开(公告)号：US08926831B2

    公开(公告)日：2015-01-06

    申请号：US13305527

    申请日：2011-11-28

    Applicant: Christophe Bouchy ,  Nathalie Marchal ,  Florent Picard

    Inventor： Christophe Bouchy ,  Nathalie Marchal ,  Florent Picard

    IPC: C10G65/04 ,  C10G45/04 ,  C10G45/08

    CPC classification number: C10G45/04 ,  C10G45/08 ,  C10G2300/1044 ,  C10G2300/202 ,  C10G2400/02

    Abstract: A novel process is described which allows selective hydrodesulphurizing gasoline cuts containing sulphur-containing compounds and olefins. The process employs a catalyst comprising a support selected, for example, from refractory oxides such as aluminas, silicas, silica-aluminas or magnesia, used alone or as a mixture, a group VI metal, preferably Mo or W which may or may not be promoted by a group VIII metal, Co or Ni. The catalyst is characterized by a mean pore diameter of more than 22 nm. The process may comprise one or more steps.

    Abstract translation: 描述了允许选择性加氢脱硫含有含硫化合物和烯烃的汽油馏分的新方法。 该方法使用包含选自例如单独使用或作为混合物使用的难熔氧化物如氧化铝，二氧化硅，二氧化硅 - 氧化铝或氧化镁的载体的载体的催化剂，VI族金属，优选Mo或W，其可以是或可以不是 由VIII族金属，Co或Ni促进。 催化剂的特征在于平均孔径大于22nm。 该过程可以包括一个或多个步骤。

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