公开(公告)号：US20150349261A1

公开(公告)日：2015-12-03

申请号：US14722774

申请日：2015-05-27

Applicant: PHILLIPS 66 COMPANY ,  SOLARMER ENERGY, INC.

Inventor： Wei Wang ,  Jun Yang ,  Chenjun Shi ,  Christopher Daeffler ,  Janice Hawkins ,  Yue Wu ,  Ting He ,  Hui Huang ,  Amit Palkar ,  Kathy Woody ,  Joe Bullock

IPC: H01L51/00 ,  C08G75/10

CPC classification number: H01L51/0036 ,  H01L51/4253 ,  Y02E10/549

Abstract: A polymer having a monomer repeat unit comprising wherein Ar is an aryl group.

Abstract translation: 具有单体重复单元的聚合物，其中Ar是芳基。

公开(公告)号：US20150344495A1

公开(公告)日：2015-12-03

申请号：US14722919

申请日：2015-05-27

Applicant: PHILLIPS 66 COMPANY ,  SOLARMER ENERGY, INC.

Inventor： Wei Wang ,  Jun Yang ,  Chenjun Shi ,  Christopher Daeffler ,  Janice Hawkins ,  Yue Wu ,  Ting He ,  Hui Huang ,  Amit Palkar ,  Kathy Woody ,  Joe Bullock

IPC: C07D495/04

CPC classification number: C07D495/04

Abstract: A method of producing a monomer wherein the method begins by dissolving 3-fluoro-4,6 dihydrothieno[3,4-b]thiophene in a solvent to create a solution. An initiator is then added to the solution to produce an initiated solution. This is followed by adding a fluorinated chemical to the initiated solution to produce 2,3-difluoro-4,6-dihydrothieno[3,4-b]thiophene. 2,3-difluoro-4,6-dihydrothieno[3,4-b]thiophene is then oxidized with an oxidant to produce 2,3-difluorothieno[3,4-b]thiophene. 2,3-difluorothieno[3,4-b]thiophene is then bromoated to produce 4,6-dibromo-2,3-difluorothieno[2,3-c]thiophene. The final step involves debrominating 4,6-dibromo-2,3-difluorothieno[2,3-c]thiophene and adding an aryl group to produce the monomer

Abstract translation: 制备单体的方法，其中该方法开始于将3-氟-4,6-二氢噻吩并[3,4-b]噻吩溶于溶剂中以产生溶液。 然后将引发剂加入到溶液中以产生引发的溶液。 然后在引发的溶液中加入氟化物，生成2,3-二氟-4,6-二氢噻吩并[3,4-b]噻吩。 然后用氧化剂氧化2,3-二氟-4,6-二氢噻吩并[3,4-b]噻吩，得到2,3-二氟噻吩并[3,4-b]噻吩。 然后将2,3-二氟噻吩并[3,4-b]噻吩溴化，得到4,6-二溴-2,3-二氟噻吩并[2,3-c]噻吩。 最后一步涉及脱溴4,6-二溴-2,3-二氟噻吩并[2,3-c]噻吩并加入芳基来制备单体

公开(公告)号：US20150136224A1

公开(公告)日：2015-05-21

申请号：US14532229

申请日：2014-11-04

Applicant: Phillips 66 Company ,  Solarmer Energy, Inc.

Inventor： Chenjun Shi ,  Ruby Chen ,  Jun Yang ,  Christopher S. Daeffler ,  Janice Hawkins ,  Yue Wu ,  Wei Wang ,  Kathy Woody ,  Joe Bullock ,  Hui Huang ,  Amit Palkar ,  Ting He

IPC: H01L51/00 ,  H01L51/44 ,  H01L51/42 ,  C08G61/12

CPC classification number: H01L51/0036 ,  C08G61/126 ,  C08G2261/12 ,  C08G2261/18 ,  C08G2261/3243 ,  C08G2261/91 ,  C09K11/06 ,  C09K2211/1458 ,  H01L51/0043 ,  H01L51/0074 ,  H01L51/4253 ,  H01L2251/308 ,  Y02E10/549

Abstract: Compositions, synthesis and applications for benzene, furan, thiophene, selenophene, pyrole, pyran, pyridine, oxazole, thiazole and imidazole derivatized anthra[2,3-b:6,7-b′]dithiophene (ADT) based polymers, namely, poly{5,11-bis(5-(2-ethylhexyl)thiophen-2-yl)anthra[2,3-b:6,7-b′]dithiophene-2,8-diyl-alt-2-ethyl-1-(thieno[3,4-b]thiophen-2-yl)hexan-1-one-4,6-diyl}, poly{5,11-bis(5-(2-ethylhexyl)furan-2-yl)anthra[2,3-b:6,7-b′]dithiophene-2,8-diyl-alt-2-ethyl-1-(thieno[3,4-b]thiophen-2-yl)hexan-1-one-4,6-diyl and poly{5,11-bis(5-(2-ethylhexyl)selenophen-2-yl)anthra[2,3-b:6,7-b′]dithiophene-2,8-diyl-alt-2-ethyl-1-(thieno[3,4-b]thiophen-2-yl)hexan-1-one-4,6-diyl} are disclosed. Further, an organic solar cell constructed of a derivatized anthra[2,3-b:6,7-b′]dithiophene (ADT) based polymer is discussed.

Abstract translation: 苯，呋喃，噻吩，硒吩，吡咯，吡喃，吡啶，恶唑，噻唑和咪唑衍生化的蒽[2,3-b：6,7-b']二噻吩（ADT）基聚合物的组合物，合成和应用， 聚[5,11-双（5-（2-乙基己基）噻吩-2-基）蒽[2,3-b：6,7-b']二噻吩-2,8-二基-2-乙基-2-乙基 - 1-（噻吩并[3,4-b]噻吩-2-基）己-1-酮-4,6-二基}，聚{5,11-双（5-（2-乙基己基）呋喃-2-基 ）噻吩[2,3-b：6,7-b']二噻吩-2,8-二基-2-乙基-1-（噻吩并[3,4-b]噻吩-2-基）己烷-1 - 酮-4,6-二基和聚{5,11-双（5-（2-乙基己基）硒吩-2-基）蒽[2,3-b：6,7-b']二噻吩-2,8 - 二基-2-乙基-1-（噻吩并[3,4-b]噻吩-2-基）己-1-酮-4,6-二基}。 此外，讨论了由衍生的蒽[2,3-b：6,7-b']二噻吩（ADT）基聚合物构成的有机太阳能电池。

公开(公告)号：US09673398B2

公开(公告)日：2017-06-06

申请号：US14722774

申请日：2015-05-27

Applicant: PHILLIPS 66 COMPANY ,  SOLARMER ENERGY, INC.

Inventor： Wei Wang ,  Jun Yang ,  Chenjun Shi ,  Christopher Daeffler ,  Janice Hawkins ,  Yue Wu ,  Ting He ,  Hui Huang ,  Amit Palkar ,  Kathy Woody ,  Joe Bullock

IPC: C08G75/00 ,  H01L51/00 ,  H01L51/42

CPC classification number: H01L51/0036 ,  H01L51/4253 ,  Y02E10/549

Abstract: A polymer having a monomer repeat unit comprising wherein Ar is an aryl group.

公开(公告)号：US09527963B2

公开(公告)日：2016-12-27

申请号：US14722650

申请日：2015-05-27

Applicant: PHILLIPS 66 COMPANY ,  SOLARMER ENERGY, INC.

Inventor： Wei Wang ,  Jun Yang ,  Chenjun Shi ,  Christopher Daeffler ,  Janice Hawkins ,  Yue Wu ,  Ting He ,  Hui Huang ,  Amit Palkar ,  Kathy Woody ,  Joe Bullock

IPC: C08G75/06 ,  C07D495/04 ,  C08G61/12 ,  A61K31/4162 ,  C07B59/00

CPC classification number: C08G75/06 ,  A61K31/4162 ,  C07B59/002 ,  C07D495/04 ,  C08G61/123

Abstract: A process of dissolving 3-fluoro-4,6-dihydrothieno[3,4-b]thiophene in a solvent to create a solution. An initiator is then added to the solution to produce an initiated solution followed by adding a fluorinated chemical to the initiated solution to produce 2,3-difluoro-4,6-dihydrothieno[3,4-b]thiophene. 2,3-difluoro-4,6-dihydrothieno[3,4-b]thiophene is then oxidized with an oxidant to produce 2,3-difluorothieno[3,4-b]thiophene. A brominating step then occurs to the 2,3-difluorothieno[3,4-b]thiophene to produce 4,6-dibromo-2,3-difluorothieno[2,3-c]thiophene 4,6-dibromo-2,3-difluorothieno[2,3-c]thiophene is then debrominated and polymerized to The stoichiometric ratio of (f+g)≈h and f, g and h are not equal to 0. Additionally, in this embodiment R1, R2, R3 and R4 are independently selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof and where the combination of R1, R2, R3 and R4 are not all identical.

Abstract translation: 将3-氟-4,6-二氢噻吩并[3,4-b]噻吩溶解在溶剂中以产生溶液的方法。 然后将引发剂加入到溶液中以产生引发的溶液，然后向引发的溶液中加入氟化物，得到2,3-二氟-4,6-二氢噻吩并[3,4-b]噻吩。 然后用氧化剂氧化2,3-二氟-4,6-二氢噻吩并[3,4-b]噻吩，得到2,3-二氟噻吩并[3,4-b]噻吩。 然后在2,3-二氟噻吩并[3,4-b]噻吩中发生溴化步骤，生成4,6-二溴-2,3-二氟噻吩并[2,3-c]噻吩。 然后将4,6-二溴-2,3-二氟噻吩并[2,3-c]噻吩脱溴并聚合成（f + g）≈h的化学计量比，f，g和h不等于0.另外， 在该实施方案中，R 1，R 2，R 3和R 4独立地选自烷基，烷氧基，芳基及其组合，并且其中R 1，R 2，R 3和R 4的组合不完全相同。

公开(公告)号：US20150344608A1

公开(公告)日：2015-12-03

申请号：US14722864

申请日：2015-05-27

Applicant: PHILLIPS 66 COMPANY ,  SOLARMER ENERGY, INC.

Inventor： Wei Wang ,  Jun Yang ,  Chenjun Shi ,  Christopher Daeffler ,  Janice Hawkins ,  Yue Wu ,  Ting He ,  Hui Huang ,  Amit Palkar ,  Kathy Woody ,  Joe Bullock

IPC: C08F228/06 ,  H01L51/00

CPC classification number: C08F228/06 ,  H01L51/0036 ,  H01L51/0043 ,  Y02E10/549

Abstract: A polymer having two different sets of repeat units consisting essentially of: In this polymer, R1, R2, R3 and R4 can be independently selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof. Also the combination of R1, R2, R3 and R4 are not all identical and n and o are greater than 1.

Abstract translation: 具有两个不同组的重复单元的聚合物基本上由以下组成：在该聚合物中，R 1，R 2，R 3和R 4可以独立地选自烷基，烷氧基，芳基及其组合。 R1，R2，R3和R4的组合也不完全相同，n和o大于1。

公开(公告)号：US20140151657A1

公开(公告)日：2014-06-05

申请号：US14084358

申请日：2013-11-19

Applicant: Solarmer Energy, Inc. ,  Phillips 66 Company

Inventor： Wei Wang ,  Chenjun Shi ,  Ruby Chen ,  Jun Yang ,  Yue Wu ,  Hui Huang ,  Kathy Woody ,  Joe Bullock ,  Amit Palkar ,  Ting He

IPC: H01L51/42

CPC classification number: H01L51/0043 ,  H01L51/0036 ,  H01L51/0047 ,  H01L51/4253 ,  Y02E10/549

Abstract: Compositions, synthesis and applications for furan, thiophene and selenophene derivatized benzo[1,2-b:3,4-b′]dithiophene(BDT)-thienothiophene (BDT-TT) based polymers, namely, poly[(4,8-bis(5-(2-ethyhexyl)selenophen-2-yl)-benzo[1,2-b;4,5-b′]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexanoyl)-3-fluorothieno[3,4-b]thiophene)-2-6-diyl (CS-15), poly[(4,8-bis(5-(2-ethyhexyl)selenophen-2-yl)-benzo[1,2-b;4,5-b′]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene)-2-carboxylate-2-6-diyl (CS-16), poly[(4,8-bis(5-(2-ethyhexyl)furan-2-yl)-benzo[1,2-b;4,5-b′]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene)-2-carboxylate-2-6-diyl (CS-18) and poly[(4,8-bis(5-hexylfuran-2-yl)-benzo[1,2-b;4,5-b′]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexanoyl)-3-fluorothieno[3,4-b]thiophene)-2-6-diyl (CS-24) are disclosed. Further, an organic solar cell constructed of a derivatized benzo[1,2-b:3,4-b′]dithiophene(BDT)-thienothiophene (BDT-TT) based polymer is discussed.

Abstract translation: 呋喃，噻吩和硒吩衍生的苯并[1,2-b：3,4-b']二噻吩（BDT） - 噻吩并噻吩（BDT-TT）基聚合物的组合物，合成和应用，即聚[（4,8- （5-（2-乙基己基）硒吩-2-基） - 苯并[1,2-b; 4,5-b']二噻吩）-2,6-二基-alt-（4-（2-乙基己酰基） -3-氟噻吩并[3,4-b]噻吩）-2-6-二基（CS-15），聚[（4,8-双（5-（2-乙基己基）硒吩-2-基） 1,2-b; 4,5-b']二噻吩）-2,6-二基-alt-（4-（2-乙基己基）-3-氟噻吩并[3,4-b]噻吩） （CS-16），聚[（4,8-双（5-（2-乙基己基）呋喃-2-基） - 苯并[1,2-b; 4,5-b']二噻吩 ）-2,6-二基-2-（4-（2-乙基己基）-3-氟噻吩并[3,4-b]噻吩）-2-羧酸酯-2,6-二基（CS-18）和聚[ 4,5-双（5-己基呋喃-2-基） - 苯并[1,2-b; 4,5-b']二噻吩）-2,6-二基-alt-（4-（2-乙基己酰基） 公开了3-氟噻吩并[3,4-b]噻吩）-2-6-二基（CS-24）。 此外，讨论了由衍生化的苯并[1,2-b：3,4-b']二噻吩（BDT） - 噻吩并噻吩（BDT-TT）基聚合物构成的有机太阳能电池。

公开(公告)号：US09691986B2

公开(公告)日：2017-06-27

申请号：US14084358

申请日：2013-11-19

Applicant: Phillips 66 Company ,  Solarmer Energy, Inc.

Inventor： Wei Wang ,  Chenjun Shi ,  Ruby Chen ,  Jun Yang ,  Yue Wu ,  Hui Huang ,  Kathy Woody ,  Joe Bullock ,  Amit Palkar ,  Ting He

IPC: C08G75/00 ,  H01L51/00 ,  H01L51/42

CPC classification number: H01L51/0043 ,  H01L51/0036 ,  H01L51/0047 ,  H01L51/4253 ,  Y02E10/549

Abstract: Compositions, synthesis and applications for furan, thiophene and selenophene derivatized benzo[1,2-b:3,4-b′]dithiophene(BDT)-thienothiophene (BDT-TT) based polymers, namely, poly[(4,8-bis(5-(2-ethyhexyl)selenophen-2-yl)-benzo[1,2-b;4,5-b′]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexanoyl)-3-fluorothieno[3,4-b]thiophene)-2-6-diyl (CS-15), poly[(4,8-bis(5-(2-ethyhexyl)selenophen-2-yl)-benzo[1,2-b;4,5-b′]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene)-2-carboxylate-2-6-diyl (CS-16), poly[(4,8-bis(5-(2-ethyhexyl)furan-2-yl)-benzo[1,2-b;4,5-b′]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene)-2-carboxylate-2-6-diyl (CS-18) and poly[(4,8-bis(5-hexylfuran-2-yl)-benzo[1,2-b;4,5-b′]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexanoyl)-3-fluorothieno[3,4-b]thiophene)-2-6-diyl (CS-24) are disclosed. Further, an organic solar cell constructed of a derivatized benzo[1,2-b:3,4-b′]dithiophene(BDT)-thienothiophene (BDT-TT) based polymer is discussed.

公开(公告)号：US09663604B2

公开(公告)日：2017-05-30

申请号：US14722864

申请日：2015-05-27

Applicant: PHILLIPS 66 COMPANY ,  SOLARMER ENERGY, INC.

Inventor： Wei Wang ,  Jun Yang ,  Chenjun Shi ,  Christopher Daeffler ,  Janice Hawkins ,  Yue Wu ,  Ting He ,  Hui Huang ,  Amit Palkar ,  Kathy Woody ,  Joe Bullock

IPC: C08G75/00 ,  C08F228/06 ,  H01L51/00

CPC classification number: C08F228/06 ,  H01L51/0036 ,  H01L51/0043 ,  Y02E10/549

Abstract: A polymer having two different sets of repeat units consisting essentially of: In this polymer, R1, R2, R3 and R4 can be independently selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof. Also the combination of R1, R2, R3 and R4 are not all identical and n and o are greater than 1.

公开(公告)号：US09278980B2

公开(公告)日：2016-03-08

申请号：US14722919

申请日：2015-05-27

Applicant: PHILLIPS 66 COMPANY ,  SOLARMER ENERGY, INC.

Inventor： Wei Wang ,  Jun Yang ,  Chenjun Shi ,  Christopher Daeffler ,  Janice Hawkins ,  Yue Wu ,  Ting He ,  Hui Huang ,  Amit Palkar ,  Kathy Woody ,  Joe Bullock

IPC: C07D495/04

CPC classification number: C07D495/04

Abstract: A method of producing a monomer wherein the method begins by dissolving 3-fluoro-4,6 dihydrothieno[3,4-b]thiophene in a solvent to create a solution. An initiator is then added to the solution to produce an initiated solution. This is followed by adding a fluorinated chemical to the initiated solution to produce 2,3-difluoro-4,6-dihydrothieno[3,4-b]thiophene. 2,3-difluoro-4,6-dihydrothieno[3,4-b]thiophene is then oxidized with an oxidant to produce 2,3-difluorothieno[3,4-b]thiophene. 2,3-difluorothieno[3,4-b]thiophene is then bromoated to produce 4,6-dibromo-2,3-difluorothieno[2,3-c]thiophene. The final step involves debrominating 4,6-dibromo-2,3-difluorothieno[2,3-c]thiophene and adding an aryl group to produce the monomer

Abstract translation: 制备单体的方法，其中该方法开始于将3-氟-4,6-二氢噻吩并[3,4-b]噻吩溶于溶剂中以产生溶液。 然后将引发剂加入到溶液中以产生引发的溶液。 然后在引发的溶液中加入氟化物，生成2,3-二氟-4,6-二氢噻吩并[3,4-b]噻吩。 然后用氧化剂氧化2,3-二氟-4,6-二氢噻吩并[3,4-b]噻吩，得到2,3-二氟噻吩并[3,4-b]噻吩。 然后将2,3-二氟噻吩并[3,4-b]噻吩溴化，得到4,6-二溴-2,3-二氟噻吩并[2,3-c]噻吩。 最后一步涉及脱溴4,6-二溴-2,3-二氟噻吩并[2,3-c]噻吩并加入芳基来制备单体