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    SURFACE SUPPORTED CATALYSTS WITH PORE SIZE CONTROL
    2.
    发明申请
    SURFACE SUPPORTED CATALYSTS WITH PORE SIZE CONTROL 有权

    公开(公告)号：US20230095433A1

    公开(公告)日：2023-03-30

    申请号：US17405616

    申请日：2021-08-18

    申请人： Saudi Arabian Oil Company

    发明人： Sibo Lin ,  Brian Hanna

    IPC分类号： B01J31/16 ,  B01J21/08 ,  B01J21/18

    摘要： Supported catalysts include a solid support, a metal-ligand complex tethered to a surface of the solid support through at least two surface reactive moieties of the metal-ligand complex, and a conformationally stable molecular pore defined between the metal-ligand complex and the surface of the solid support. The metal-ligand complex includes a catalytic metal center, such as a transition metal, coordinated with multiple monodentate ligands, a multidentate ligand, or a combination thereof. The ligands include a tethering portion that is terminated by a surface reactive moiety tethered to the surface of the solid support by a surface interaction. By tailoring the tethering portion, a volume of the molecular pore may be provided that is selective and suitable for a chosen reactant or a chosen reaction type.

    Surface supported catalysts with pore size control
    3.
    发明授权
    Surface supported catalysts with pore size control 有权

    公开(公告)号：US11607678B1

    公开(公告)日：2023-03-21

    申请号：US17405616

    申请日：2021-08-18

    申请人： Saudi Arabian Oil Company

    发明人： Sibo Lin ,  Brian Hanna

    IPC分类号： B01J31/16 ,  B01J21/18 ,  B01J21/08

    摘要： Supported catalysts include a solid support, a metal-ligand complex tethered to a surface of the solid support through at least two surface reactive moieties of the metal-ligand complex, and a conformationally stable molecular pore defined between the metal-ligand complex and the surface of the solid support. The metal-ligand complex includes a catalytic metal center, such as a transition metal, coordinated with multiple monodentate ligands, a multidentate ligand, or a combination thereof. The ligands include a tethering portion that is terminated by a surface reactive moiety tethered to the surface of the solid support by a surface interaction. By tailoring the tethering portion, a volume of the molecular pore may be provided that is selective and suitable for a chosen reactant or a chosen reaction type.