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公开(公告)号：US5656395A
公开(公告)日：1997-08-12
申请号：US479360
申请日：1995-06-07
CPC分类号： H01M4/669 , H01M12/06 , H01M4/661 , H01M4/74 , H01M4/86 , H01M2004/8689 , Y10S428/929 , Y10T29/49108
摘要： A metal current collecting substrate for an air cathode in an electrochemical metal air cell is provided for, wherein the substrate is hardened by one of the steps of sandblasting, shotblasting, plastic deformation of the substrate below the recrystallization temperature range of the metal thereof, and heating the substrate to above the transformation temperature of the metal thereof followed by quenching the substrate below the transformation temperature of the metal thereof. Catalytically active materials, most preferably a mixture of carbon and manganese dioxide, are pressed or otherwise disposed upon the hardened substrate. The substrate is capable of being connected to electrical circuitry. Most preferably, the substrate is a metal screen that has been hardened, roughened and pitted by sandblasting before the catalytically active materials are disposed thereupon, and before the substrate is incorporated into an electrochemical metal air cell.
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2.发明授权
公开(公告)号：US5650246A
公开(公告)日：1997-07-22
申请号：US542809
申请日：1995-10-13
CPC分类号： H01M4/669 , H01M12/06 , H01M4/661 , H01M4/74 , H01M4/86 , H01M2004/8689 , Y10S428/929 , Y10T29/49108
摘要： A metal current collecting substrate for an air cathode in an electrochemical metal air cell is provided for, wherein the substrate is hardened by one of the steps of sandblasting, shotblasting, plastic deformation of the substrate below the recrystallization temperature range of the metal thereof, and heating the substrate to above the transformation temperature of the metal thereof followed by quenching the substrate below the transformation temperature of the metal thereof. Catalytically active materials, most preferably a mixture of carbon and manganese dioxide, are pressed or otherwise disposed upon the hardened substrate. The substrate is capable of being connected to electrical circuitry. Most preferably, the substrate is a metal screen that has been hardened, roughened and pitted by sandblasting before the catalytically active materials are disposed thereupon, and before the substrate is incorporated into an electrochemical metal air cell.
摘要翻译： 提供了一种用于电化学金属空气电池中的空气阴极的金属集流基板，其中通过喷砂，喷丸，低于其金属的再结晶温度范围的基板的塑性变形中的一个步骤来硬化基板，以及 将基板加热至其金属的转变温度以上，然后使基板在其金属的相变温度以下淬火。 催化活性材料，最优选碳和二氧化锰的混合物被压制或以其它方式设置在硬化的基底上。 基板能够连接到电路。 最优选地，基材是金属筛，其在将催化活性材料置于其之前以及在将基底结合到电化学金属空气电池中之前已通过喷砂而被硬化，粗糙化和凹陷。
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3.发明授权
公开(公告)号：US5587259A
公开(公告)日：1996-12-24
申请号：US208450
申请日：1994-03-09
CPC分类号： H01M4/669 , H01M12/06 , H01M4/661 , H01M4/74 , H01M4/86 , H01M2004/8689 , Y10S428/929 , Y10T29/49108
摘要： A metal current collecting substrate for an air cathode in an electrochemical metal air cell is provided for, wherein the substrate is hardened by one of the steps of sandblasting, shotblasting, plastic deformation of the substrate below the recrystallization temperature range of the metal thereof, and heating the substrate to above the transformation temperature of the metal thereof followed by quenching the substrate below the transformation temperature of the metal thereof. Catalytically active materials, most preferably a mixture of carbon and manganese dioxide, are pressed or otherwise disposed upon the hardened substrate. The substrate is capable of being connected to electrical circuitry. Most preferably, the substrate is a metal screen that has been hardened, roughened and pitted by sandblasting before the catalytically active materials are disposed thereupon, and before the substrate is incorporated into an electrochemical metal air cell.
摘要翻译： 提供了一种用于电化学金属空气电池中的空气阴极的金属集流基板，其中通过喷砂，喷丸，低于其金属的再结晶温度范围的基板的塑性变形中的一个步骤来硬化基板，以及 将基板加热至其金属的转变温度以上，然后使基板在其金属的相变温度以下淬火。 催化活性材料，最优选碳和二氧化锰的混合物被压制或以其它方式设置在硬化的基底上。 基板能够连接到电路。 最优选地，基材是金属筛，其在将催化活性材料置于其之前以及在将基底结合到电化学金属空气电池中之前已通过喷砂而被硬化，粗糙化和凹陷。
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4.发明授权Method of hardening a metal current collecting strip of an air cathode and a method of making a button type battery 失效硬化空气阴极的金属集流条的方法和制造纽扣式电池的方法
公开(公告)号：US5637117A
公开(公告)日：1997-06-10
申请号：US479361
申请日：1995-06-07
CPC分类号： H01M4/669 , H01M12/06 , H01M4/661 , H01M4/74 , H01M4/86 , H01M2004/8689 , Y10S428/929 , Y10T29/49108
摘要： A metal current collecting substrate for an air cathode in an electrochemical metal air cell is provided for, wherein the substrate is hardened by one of the steps of sandblasting, shotblasting, plastic deformation of the substrate below the recrystallization temperature range of the metal thereof, and heating the substrate to above the transformation temperature of the metal thereof followed by quenching the substrate below the transformation temperature of the metal thereof. Catalytically active materials, most preferably a mixture of carbon and manganese dioxide, are pressed or otherwise disposed upon the hardened substrate. The substrate is capable of being connected to electrical circuitry. Most preferably, the substrate is a metal screen that has been hardened, roughened and pitted by sandblasting before the catalytically active materials are disposed thereupon, and before the substrate is incorporated into an electrochemical metal air cell.
摘要翻译： 提供了一种用于电化学金属空气电池中的空气阴极的金属集流基板，其中通过喷砂，喷丸，低于其金属的再结晶温度范围的基板的塑性变形中的一个步骤来硬化基板，以及 将基板加热至其金属的转变温度以上，然后使基板在其金属的相变温度以下淬火。 催化活性材料，最优选碳和二氧化锰的混合物被压制或以其它方式设置在硬化的基底上。 基板能够连接到电路。 最优选地，基材是金属筛，其在将催化活性材料置于其之前以及在将基底结合到电化学金属空气电池中之前已通过喷砂而被硬化，粗糙化和凹陷。
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5.发明授权Metal-air cathode and cell having catalytically active manganese compounds of valence state +2 失效金属空气阴极和具有催化活性的锰化合物价态的电池+2
公开(公告)号：US5308711A
公开(公告)日：1994-05-03
申请号：US15641
申请日：1993-02-09
CPC分类号： H01M4/9016 , H01M12/06 , H01M4/96
摘要： An air cathode for a metal-air cell and methods for making it are provided. In the air cathode of the present invention, manganese compounds of valence state +2 act as catalysts for the reduction of oxygen, and are distributed substantially evenly throughout a carbon matrix. Manganese compounds of valence state +2 form between carbon particles after the carbon particles are added to an aqueous solution of potassium permanganate.
摘要翻译： 提供一种用于金属 - 空气电池的空气阴极及其制造方法。 在本发明的空气阴极中，价态为+2的锰化合物作为还原氧的催化剂，并且基本均匀地分布在整个碳基质中。 在将碳粒子加入到高锰酸钾水溶液中之后，碳粒子之间形成的价态化合物为+2的锰化合物。
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6.发明授权Method of making air cathode material having catalytically active manganese compounds of valance state +2 失效制备具有催化活性的价态锰化合物的空气阴极材料的方法+2
公开(公告)号：US5378562A
公开(公告)日：1995-01-03
申请号：US190781
申请日：1994-02-01
CPC分类号： H01M4/9016 , H01M12/06 , H01M4/96
摘要： A method of making an air cathode material for a metal-air cell is provided. In the air cathode material of the present invention, manganese compounds of valence state +2 act as catalysts for the reduction of oxygen, and are distributed substantially evenly throughout a carbon matrix. Manganese compounds of valence state +2 form between carbon particles after the carbon particles are added to an aqueous solution of potassium permanganate.
摘要翻译： 提供一种制造用于金属 - 空气池的空气阴极材料的方法。 在本发明的空气阴极材料中，价态为+2的锰化合物作为氧还原的催化剂，并且基本均匀地分布在整个碳基质中。 在将碳粒子加入到高锰酸钾水溶液中之后，碳粒子之间形成的价态化合物为+2的锰化合物。
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公开(公告)号：US4649090A
公开(公告)日：1987-03-10
申请号：US821430
申请日：1986-01-22
CPC分类号： C09J7/0296 , H01M12/02 , H01M2/08 , C09J2400/283 , Y10T428/28 , Y10T428/2848
摘要： A seal tab consisting of an acrylic adhesive applied to a biaxially-oriented three-ply synthetic paper of polypropylene is used as a sealing means for metal-air electrochemical cells, and batteries constructed thereof. The seal tabs prevent loss of rate capability and capacity due to interactions with the surrounding environment prior to the placement into service of metal air cells, yet without so isolating the cells such that the initial open circuit voltage is deemed unacceptable by the end user. Additionally, the seal tab, as provided, is easily and cleanly removed, which enhances the cell's consumer appeal.
摘要翻译： 作为用于金属 - 空气电化学电池的密封装置和由其构成的电池，使用由应用于聚丙烯的双轴取向三层合成纸的丙烯酸类粘合剂构成的密封片。 密封片防止在金属空气电池投入使用之前由于与周围环境的相互作用而造成的速率能力和容量的损失，但是没有隔离电池，使得初始开路电压被最终用户认为是不可接受的。 另外，如所提供的那样，密封片容易且干净地移除，这增强了电池的消费者吸引力。
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公开(公告)号：US4343869A
公开(公告)日：1982-08-10
申请号：US233074
申请日：1981-02-09
申请人： John E. Oltman , Robert B. Dopp
发明人： John E. Oltman , Robert B. Dopp
CPC分类号： H01M2/0222 , H01M12/06
摘要： An improved metal-oxygen button cell having a thermoplastic sealing annular ring placed between the cathode assembly and the grommet is provided. The cell basically is comprised of the following components: a conductive metal can, a cathode assembly in the can, a conductive metal cover, an anode material in the cover, a separator between the cathode assembly and anode material, a grommet and a thermoplastic sealing annular ring.
摘要翻译： 提供了一种改进的金属氧按钮电池，其具有放置在阴极组件和索环之间的热塑性密封环形环。 电池基本上由以下部件组成：导电金属罐，罐中的阴极组件，导电金属盖，盖中的阳极材料，阴极组件和阳极材料之间的隔板，索环和热塑性密封 环形环。
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公开(公告)号：US5582930A
公开(公告)日：1996-12-10
申请号：US435485
申请日：1995-05-05
申请人： John E. Oltman , Robert B. Dopp , John D. Burns
发明人： John E. Oltman , Robert B. Dopp , John D. Burns
CPC分类号： H01M4/42 , H01M12/06 , H01M2/0222 , H01M2/0257 , H01M2/027 , H01M2/0272 , H01M2/0275 , H01M4/244 , H01M4/62 , H01M2300/0085
摘要： This invention pertains to alkaline electrochemical cells, typically to metal-air cells of the button-type. Non-reactive elements of cells of the invention are thinner than corresponding non-reactive elements of prior art cells. Such elements can be made thinner because of improved structures of such elements. The anode can is made from a metal strip structure having a higher steel content. The cathode can has a modified temper, which improves relative stiffness and rigidity while retaining sufficient ductility. The seal disposed between the anode can and the cathode can is made thinner. Structure of the corner of the cathode can between the bottom and the side wall is improved. By so reducing the thicknesses of non-reactive elements of the cell, and thus the volume occupied by such non-reactive elements, the fraction of the cell devoted to holding electrochemically reactive anode material therein is increased, with corresponding increase in the milliampere hour capacity of the cell.
摘要翻译： 本发明涉及碱性电化学电池，通常用于按钮型金属 - 空气电池。 本发明的细胞的非反应性元件比现有技术细胞的相应的非反应性元件薄。 由于这些元件的结构改进，这些元件可以变得更薄。 阳极罐由具有较高钢含量的金属带结构制成。 阴极可以具有改进的回火，其改善相对刚度和刚度，同时保持足够的延展性。 设置在阳极罐和阴极罐之间的密封件变薄。 底部和侧壁之间阴极的角部结构得到改善。 通过这样减小电池的非反应性元件的厚度，并因此降低了这种非反应性元件占据的体积，致使其中保持电化学反应性阳极材料的电池部分增加，相应地增加了毫安小时容量 的细胞。
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公开(公告)号：US5567538A
公开(公告)日：1996-10-22
申请号：US435179
申请日：1995-05-05
申请人： John E. Oltman , Robert B. Dopp , John D. Burns
发明人： John E. Oltman , Robert B. Dopp , John D. Burns
CPC分类号： H01M2/0272 , H01M12/06 , H01M2/0222 , H01M2/0257 , H01M2/027 , H01M2/0275 , H01M4/244 , H01M4/42 , H01M4/62 , H01M2300/0085
摘要： This invention pertains to alkaline electrochemical cells, typically to metal-air cells of the button-type. Non-reactive elements of cells of the invention are thinner than corresponding non-reactive elements of prior art cells. Such elements can be made thinner because of improved structures of such elements. The anode can is made from a metal strip structure having a higher steel content. The cathode can has a modified temper, which improves relative stiffness and rigidity while retaining sufficient ductility. The seal disposed between the anode can and the cathode can is made thinner. Structure of the corner of the cathode can between the bottom and the side wall is improved. By so reducing the thicknesses of non-non-reactive elements of the cell, and thus the volume occupied by such non-reactive elements, the fraction of the cell devoted to holding electrochemically reactive anode material therein is increased, with corresponding increase in the milliampere hour capacity of the cell.
摘要翻译： 本发明涉及碱性电化学电池，通常用于按钮型金属 - 空气电池。 本发明的细胞的非反应性元件比现有技术细胞的相应的非反应性元件薄。 由于这些元件的结构改进，这些元件可以变得更薄。 阳极罐由具有较高钢含量的金属带结构制成。 阴极可以具有改进的回火，其改善相对刚度和刚度，同时保持足够的延展性。 设置在阳极罐和阴极罐之间的密封件制成更薄。 底部和侧壁之间阴极的角部结构得到改善。 通过这样减小电池的非非反应性元件的厚度，并因此降低这种非反应性元件占据的体积，用于保持其中的电化学反应性阳极材料的电池部分增加，相应地增加毫安 小时容量的细胞。
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