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    Emulsion compositions with a polymeric emulsifier
    1.
    发明授权
    Emulsion compositions with a polymeric emulsifier 有权
    具有聚合乳化剂的乳液组合物

    公开(公告)号：US08183314B2

    公开(公告)日：2012-05-22

    申请号：US12459057

    申请日：2009-06-26

    申请人： Ramesh Varadaraj ,  Cornelius Hendrick Brons ,  David John Lohse

    发明人： Ramesh Varadaraj ,  Cornelius Hendrick Brons ,  David John Lohse

    IPC分类号： C08F2/32 ,  C08F214/16 ,  C08F236/16 ,  C08L25/16 ,  C08L9/00 ,  C08J3/215

    CPC分类号： B01F17/0035 ,  C08L23/283

    摘要： Provided are oil-in-water and water-in-oil emulsion compositions including from 0.01 to 5 wt % of a halogenated elastomer emulsifier, and optionally from to 0.5 wt % of a polyalkylene amine co-emulsifier. The emulsion compositions disclosed herein provide for increased interfacial elasticity and decreased interfacial tension at the oil-water interface to increase resistance to coalescence of dispersed water droplets of a water-in-oil emulsion or oil droplets of an oil-in-water emulsion. The emulsion compositions disclosed herein are suitable for lubricant applications due to their resistance to shear thinning.

    摘要翻译： 提供了包含0.01至5重量％的卤化弹性体乳化剂和任选地至0.5重量％的聚亚烷基胺共乳化剂的水包油和油包水乳液组合物。 本文公开的乳液组合物提供增加的界面弹性和降低油 - 水界面处的界面张力，以增加油包水乳液或油包水乳液的油滴分散水滴聚结的抗性。 本文公开的乳液组合物由于其抗剪切变稀性而适用于润滑剂应用。

    Bioremediation method of hydrocarbon contaminated soils, water, and/or sludge using urea-surfactant clathrates
    3.
    发明授权
    Bioremediation method of hydrocarbon contaminated soils, water, and/or sludge using urea-surfactant clathrates 失效
    使用尿素 - 表面活性剂包合物的碳氢化合物污染土壤，水和/或污泥的生物修复方法

    公开(公告)号：US5811290A

    公开(公告)日：1998-09-22

    申请号：US946422

    申请日：1997-10-07

    申请人： Ramesh Varadaraj ,  Cornelius Hendrick Brons

    发明人： Ramesh Varadaraj ,  Cornelius Hendrick Brons

    IPC分类号： C12N1/00 ,  B09C1/10 ,  C02F1/00 ,  C02F3/24 ,  C02F3/34 ,  C07C273/02 ,  C07C275/02 ,  C09K17/14 ,  C09K101/00 ,  C11D1/44 ,  C11D1/50 ,  C11D1/66 ,  C11D1/72 ,  C11D1/78 ,  C12N1/38 ,  A61K33/42 ,  A01N59/26 ,  B09B3/00 ,  C07C211/00

    CPC分类号： B09C1/10 ,  C02F3/34 ,  C02F3/344 ,  C07C275/02 ,  C02F2305/06

    摘要： A method and composition for enhancing the biodegradation of hydrocarbon contaminated soil, water, and/or sludge are disclosed. The composition comprises an adduct of urea with a non-ionic surfactant and a phosphorous source. The disclosed method provides for the application of a degradation effective amount of a composition which comprises a N:P ratio which ranges from 10:2 to about 10:0.5 and the urea and non-ionic surfactant are present in the adduct in a weight ratio ranging from 98:2 to 75:25. Further, the method of biodegradation is carried out by the application of the composition to provide for a C:N:P ratio of 100:10:1 to 100:1:001. The C:N:P ratio is based on the weight percent of the hydrocarbon contaminate in the soil, water and/or sludge sites to be treated. Surfactants which are useful in the disclosed composition and method have from about 2 to fifty ethylene oxide groups; and comprise such compounds as alkylethoxylates, alkyl ethoxylated phosphates, alkyl ethoxylated amines, alkylethoxylated ammonium salts, etc.

    摘要翻译： 公开了一种用于增强烃污染的土壤，水和/或污泥的生物降解的方法和组合物。 组合物包含尿素与非离子表面活性剂和磷源的加合物。 所公开的方法提供降解有效量的组合物的应用，该组合物包含10:2至约10:0.5的N:P比，并且尿素和非离子表面活性剂以重量比存在于加合物中 从98：2到75:25。 此外，生物降解的方法是通过施用组合物来提供100:10:1-100:1:001的C:N:P比。 C：N：P比是基于待处理的土壤，水和/或污泥位置中碳氢化合物污染物的重量百分比。 在所公开的组合物和方法中有用的表面活性剂具有约2-50个环氧乙烷基团; 并且包括诸如烷基乙氧基化物，烷基乙氧基化磷酸酯，烷基乙氧基化胺，烷基乙氧基化铵盐等的化合物

    Upgrading asphaltene containing oils
    4.
    发明授权
    Upgrading asphaltene containing oils 失效
    升级含沥青质的油

    公开(公告)号：US07435333B2

    公开(公告)日：2008-10-14

    申请号：US11157554

    申请日：2005-06-21

    申请人： Ramesh Varadaraj ,  Cornelius Hendrick Brons

    发明人： Ramesh Varadaraj ,  Cornelius Hendrick Brons

    IPC分类号： C01G31/00 ,  C10C3/00

    CPC分类号： C10L1/1616 ,  C10G29/20 ,  C10G31/00

    摘要： A method for reducing the viscosity and surface wetting tendency of an oil containing hydrophilic aspaltenes comprises adding to said oil an amount of hydrophobic asphaltenes in the range of 1 to 80 wt % based on weight of the hydrophilic asphaltense of said oil.

    摘要翻译： 一种降低含有亲水性海藻醇的油的粘度和表面润湿趋势的方法包括向所述油中加入一定量的疏水性沥青质，其量为所述油的亲水性沥青质的重量的1至80重量％。

    Emulsion compositions with a polymeric emulsifier
    6.
    发明申请
    Emulsion compositions with a polymeric emulsifier 有权
    具有聚合乳化剂的乳液组合物

    公开(公告)号：US20100004382A1

    公开(公告)日：2010-01-07

    申请号：US12459057

    申请日：2009-06-26

    申请人： Ramesh Varadaraj ,  Cornelius Hendrick Brons ,  David John Lohse

    发明人： Ramesh Varadaraj ,  Cornelius Hendrick Brons ,  David John Lohse

    IPC分类号： C08L23/20 ,  C08L25/06

    CPC分类号： B01F17/0035 ,  C08L23/283

    摘要： Provided are oil-in-water and water-in-oil emulsion compositions including from 0.01 to 5 wt % of a halogenated elastomer emulsifier, and optionally from to 0.5 wt % of a polyalkylene amine co-emulsifier. The emulsion compositions disclosed herein provide for increased interfacial elasticity and decreased interfacial tension at the oil-water interface to increase resistance to coalescence of dispersed water droplets of a water-in-oil emulsion or oil droplets of an oil-in-water emulsion. The emulsion compositions disclosed herein are suitable for lubricant applications due to their resistance to shear thinning.

    摘要翻译： 提供了包含0.01至5重量％的卤化弹性体乳化剂和任选地至0.5重量％的聚亚烷基胺共乳化剂的水包油和油包水乳液组合物。 本文公开的乳液组合物提供增加的界面弹性和降低油 - 水界面处的界面张力，以增加油包水乳液或油包水乳液的油滴分散水滴聚结的抗性。 本文公开的乳液组合物由于其抗剪切变稀性而适用于润滑剂应用。

    Polar solvent-asphaltene dispersant method for upgrading heavy oils
    7.
    发明授权
    Polar solvent-asphaltene dispersant method for upgrading heavy oils 失效
    极性溶剂 - 沥青质分散剂改质重油的方法

    公开(公告)号：US07579303B2

    公开(公告)日：2009-08-25

    申请号：US11173978

    申请日：2005-07-01

    申请人： Ramesh Varadaraj ,  Cornelius Hendrick Brons

    发明人： Ramesh Varadaraj ,  Cornelius Hendrick Brons

    IPC分类号： C10C1/00 ,  C10C1/18 ,  C07C303/44

    CPC分类号： C10G21/003

    摘要： A method for reducing the viscosity and toluene equivalence of an oil containing asphaltenes comprises the steps of: a) mixing with the oil, a polar solvent, and an asphaltene dispersant additive wherein the weight ratio of oil:polar solvent is in the range of 10:0.1 to 10:5, the asphaltene dispersant additive is at a treat rate in the range of 0.025 to 5 weight percent based on the weight of the oil, and then, b) removing at least 90 wt % of the polar solvent from the mixture of oil, polar solvent and the asphaltene dispersant additive to provide upgraded oil with reduced viscosity and toluene equivalence.

    摘要翻译： 降低含油沥青质的粘度和甲苯当量的方法包括以下步骤：a）与油，极性溶剂和沥青质分散剂添加剂混合，其中油：极性溶剂的重量比在10 ：0.1〜10：5，沥青质分散剂添加剂的处理速度为0.025〜5重量％，基于油的重量，然后，b）从至少90重量％的极性溶剂中除去 油，极性溶剂和沥青质分散剂添加剂的混合物，以提供具有降低的粘度和甲苯当量的改进的油。

    Aromatic sulfonic acid demulsifier for crude oils
    8.
    发明授权
    Aromatic sulfonic acid demulsifier for crude oils 失效
    用于原油的芳香族磺​​酸破乳剂

    公开(公告)号：US06599949B2

    公开(公告)日：2003-07-29

    申请号：US10261964

    申请日：2002-10-01

    申请人： Ramesh Varadaraj ,  Cornelius Hendrick Brons

    发明人： Ramesh Varadaraj ,  Cornelius Hendrick Brons

    IPC分类号： B01D1705

    CPC分类号： C10G33/04

    摘要： The invention is directed towards a chemical demulsifier formulation comprising an alkyl aromatic sulfonic acid additive with at least 16 carbon atom alkyl group and at least two 6 carbon-ring aromatic group and a co-additive selected from the group consisting of dipropylene monobutyl ether, aromatic naphtha, isoparaffinic solvent, cycloparaffinic solvent, aromatic solvent, diethylene glycol monobutyl ether, benzyl alcohol and mixtures thereof and a process for demulsification and desalting crude oil using the demulsifier formulation.

    摘要翻译： 本发明涉及一种化学破乳剂制剂，其包含具有至少16个碳原子烷基的烷基芳族磺酸添加剂和至少两个6碳环芳族基团和选自二丙烯单丁醚，芳族化合物的共添加剂 石脑油，异链烷烃溶剂，环烷烃溶剂，芳族溶剂，二甘醇单丁醚，苄醇及其混合物，以及使用破乳剂制剂使原油破乳和脱盐的方法。

    Crude oil desalting method
    9.
    发明授权
    Crude oil desalting method 失效
    原油脱盐方法

    公开(公告)号：US06228239B1

    公开(公告)日：2001-05-08

    申请号：US09258620

    申请日：1999-02-26

    申请人： Pacifico V. Manalastas ,  Ramesh Varadaraj ,  David W. Savage ,  Guido Sartori ,  Ramesh R. Hemrajani ,  Cornelius Hendrick Brons

    发明人： Pacifico V. Manalastas ,  Ramesh Varadaraj ,  David W. Savage ,  Guido Sartori ,  Ramesh R. Hemrajani ,  Cornelius Hendrick Brons

    IPC分类号： B01D1706

    CPC分类号： C10G33/00 ,  C10G31/08 ,  C10G33/02 ,  C10G33/04

    摘要： In one embodiment, the invention is related to a process for desalting crude oil that requires less wash water than conventional desalting methods. In the preferred embodiment of the invention, a chemical demulsifier formulation comprising an emulsion-breaking chemical and a solvent carrier is added to the crude oil. Wash water is then added to the crude oil until the volume of water in the oil ranges from about 0.1 to about 3 vol. %. Subsequently, the mixture of crude oil, wash water, and chemical demulsifier formulation is subjected to opposed-flow mixing. Chemical emulsion-breakers useful in the invention have a hydrophobic tail group and a hydrophilic head group. Preferably, the emulsion breaker has the formula: x ranges from 1 to 5, y ranges from 0 to 2, and R is an alkyl group having 4-9 carbon atoms, and n ranges from 3 to 9.

    摘要翻译： 在一个实施方案中，本发明涉及与常规脱盐方法相比需要较少洗涤水的原油脱盐方法。 在本发明的优选实施方案中，将包含破乳化学品和溶剂载体的化学破乳剂制剂加入到原油中。 然后将洗涤水加入到原油中，直到油中的水的体积为约0.1至约3体积％。 ％。 随后，将原油，洗涤水和化学破乳剂制剂的混合物进行相反流混合。 可用于本发明的化学乳液破乳剂具有疏水性尾基和亲水性头基。 优选地，破乳剂具有下式：x为1至5，y为0至2，R为具有4-9个碳原子的烷基，n为3至9。