公开(公告)号：US3927123A

公开(公告)日：1975-12-16

申请号：US21020871

申请日：1971-12-20

Applicant: RHONE POULENC SA

Inventor： BOURDIN FRANCOIS ,  CHIZAT FRANCOIS ,  COSTANTINI MICHEL ,  JOUFFRET MICHEL

IPC: C07C37/56 ,  C07C27/00 ,  C07C37/00 ,  C07C67/44

CPC classification number: C07C37/56 ,  C07C39/07 ,  C07C39/06

Abstract: Phenols nuclear substituted by 1 to 3 straight-chain or branched-chain alkyl substituents of 1 to 10 carbons are prepared by oxidizing the aldehyde group of the corresponding alkyl substituted benzaldehyde with an organic peracid, which is derived from a carboxylic acid of pKa in water less than 4. The formate ester of the phenol, which may be in the reaction product, is hydrolysed or transesterified to form the phenol.

Abstract translation: 通过用有机过酸氧化相应的烷基取代的苯甲醛的醛基来制备由1至3个具有1至10个碳原子的直链或支链烷基取代基取代的酚，该有机过酸衍生自在水中的pKa的羧酸 可以在反应产物中的酚的甲酸酯被水解或酯交换以形成苯酚。

公开(公告)号：US3875247A

公开(公告)日：1975-04-01

申请号：US29516572

申请日：1972-10-05

Applicant: RHONE POULENC SA

Inventor： BOURDIN FRANCOIS ,  CHIZAT FRANCOIS ,  COSTANTINI MICHEL ,  JOUFFRET MICHEL

IPC: C07C37/20 ,  C07C27/00 ,  C07C29/14 ,  C07C37/56 ,  C07C39/06 ,  C07C67/00 ,  C07C37/00

CPC classification number: C07C37/56 ,  C07C39/07

Abstract: O- AND/OR P-ALKYLPHENOLS WITH 1 OR 2 C1-10 alkyl groups are prepared by oxidising the corresponding alkylbenzaldehyde with hydrogen peroxide in the presence of an acid of pKa less than 3 which is an organic acid or organic sulphonic acid.

Abstract translation: 具有1个或2个C 1-10烷基的O-和/或p-烷基苯酚通过在pKa小于3的酸（其是有机酸或有机磺酸）的存在下用过氧化氢氧化相应的烷基苯甲醛来制备。

公开(公告)号：US3872156A

公开(公告)日：1975-03-18

申请号：US30753072

申请日：1972-11-17

Applicant: RHONE POULENC SA

Inventor： BOURDIN FRANCOIS ,  CHIZAT FRANCOIS ,  COSTANTINI MICHEL ,  JOUFFRET MICHEL

IPC: B01J27/00 ,  B01J31/00 ,  C07B61/00 ,  C07C27/00 ,  C07C37/56 ,  C07C39/02 ,  C07C67/00 ,  C07C37/00

CPC classification number: C07C37/56 ,  Y02P20/52 ,  C07C39/04 ,  C07C39/07

Abstract: A phenol of formula:

WHERE R1, R2 and R3 independently represent hydrogen or C1-C5 alkyl is obtained by oxidising with hydrogen peroxide a solution of the corresponding aldehyde in a polymethylene sulphone e.g. sulpholane.

Abstract translation: 下式的苯酚：

公开(公告)号：US3927122A

公开(公告)日：1975-12-16

申请号：US21020771

申请日：1971-12-20

Applicant: RHONE POULENC SA

Inventor： BOURDIN FRANCOIS ,  CHIZAT FRANCOIS ,  COSTANTINI MICHEL ,  JOUFFRET MICHEL

IPC: C07C37/56 ,  C07C51/285 ,  C07C27/00 ,  C07C37/00 ,  C07C67/44

CPC classification number: C07C37/56 ,  C07C51/285 ,  C07C63/04 ,  C07C39/07

Abstract: Phenols nuclear substituted by 1 to 3 straight chain or branched chain alkyl substituents of 1 to 10 carbons are prepared by oxidising the aldehyde group of the corresponding alkyl substituted benzaldehyde with an organic peracid, which is derived from a carboxylic acid of pKa in water of at least 4, in the presence of a carboxylic acid of pKa in water less than 4. The formate ester of the phenol, which may be in the reaction product, is hydrolysed or transesterified to form the phenol.

Abstract translation: 通过用有机过酸氧化相应的烷基取代的苯甲醛的醛基来制备由1至3个具有1至10个碳的直链或支链烷基取代基取代的酚，所述有机过酸衍生自在水中的pKa的羧酸 在低于4的水中pKa的羧酸存在下，至少4个。可能在反应产物中的酚的甲酸酯被水解或酯交换以形成苯酚。