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公开(公告)号:US12076707B2
公开(公告)日:2024-09-03
申请号:US16973107
申请日:2019-07-01
CPC分类号: B01J20/3204 , B01D53/04 , B01J20/186 , B01J20/28004 , B01J20/28011 , B01J20/2808 , B01J20/3225 , B01J20/3244 , B01J20/3272 , B01D2253/108 , B01D2253/202 , B01D2253/25 , B01D2253/304 , B01D2253/308 , B01D2256/10 , B01D2256/20 , B01D2256/245 , B01D2257/102 , B01D2257/104 , B01D2257/504 , B01J2220/46
摘要: The present invention relates to a surface modified zeolite adsorbent wherein the surface of said zeolite is modified with a coating comprised of a silicone derived species, said zeolite having a mean crystal size from about 5 to about 10 μm and a skeletal density of ≥1.10 gr./cc. The invention is based on the discovery that larger crystals tend to have higher particle density, and the packing of the larger crystals in agglomeration processes leads to more idealized packing to provide a larger mean-pore diameter. The surface modified adsorbent provides rate selectivity for one gas over others is described. The superior adsorbent has the added convenience of bead forming simultaneously with pore modification as well as having the treatment result in the yielding of high crush strength products.
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公开(公告)号:US20200368724A1
公开(公告)日:2020-11-26
申请号:US16966292
申请日:2019-02-14
发明人: Neil A. Stephenson , Philip A. Barrett , Steven J. Pontonio , Nicholas R. Stuckert , Garrett R. Swindlehurst
IPC分类号: B01J20/28 , B01D53/047 , B01J20/20 , B01J20/32 , B01J20/30
摘要: The present invention relates to a superior carbon adsorbent with or without a core. In one embodiment the carbon adsorbent of the present invention employs carbon adsorbent powder and an organic binding agent which are combined together with an appropriate solvent in an agglomeration step. In another embodiment the invention contemplates a core-in-shell adsorbent comprising an outer shell composed of a carbon and a non-adsorbing inert inner core. Low temperature processing of these agglomerates substantially preserves the binding agent within the final composition and allows one to prepare adsorbent products of high sphericity. The adsorbents of the invention possess superior characteristics such as higher mass transfer rate and CO2 working capacity for use in a H2PSA process.
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公开(公告)号:US12017204B2
公开(公告)日:2024-06-25
申请号:US16966092
申请日:2019-02-14
CPC分类号: B01J20/28011 , B01D53/0476 , B01J20/18 , B01J20/20 , B01J20/28004 , B01J20/28016 , B01J20/28019 , B01J20/2803 , B01J20/3028 , B01J20/3204 , B01J20/324 , B01J20/3293 , B01D2253/102 , B01D2253/1085 , B01D2253/116 , B01D2253/25 , B01D2253/304 , B01D2253/311 , B01D2256/10 , B01D2256/16 , B01D2257/104 , B01D2257/404 , B01D2257/504 , B01D2257/702
摘要: The invention relates to a superior core-in-shell adsorbent comprising adsorbent, and an inert core, wherein said core possesses a porosity less than 10%, and has a volumetric thermal capacity greater than 1 J/K*cc. The adsorbents of the invention possess good physical strength, and allow a longer cycle time, thereby reducing the blowdown (vent) losses compared to known adsorbents.
The invention relates to an adsorber design for a vacuum/pressure swing adsorption (VSA, VPSA, PSA) process designed to obtain oxygen product from air utilizing the adsorbents of the invention.-
公开(公告)号:US09772139B2
公开(公告)日:2017-09-26
申请号:US14948959
申请日:2015-11-23
CPC分类号: F25J3/08 , C01B23/0052 , C01B23/0068 , C01B23/0078 , C01B2210/0021 , C01B2210/0034 , C01B2210/0045 , F25J3/04733 , F25J2205/60 , F25J2220/44
摘要: The invention relates to a process for removing oxygen from liquid argon using a TSA (temperature swing adsorption) cyclical process that includes cooling an adsorbent bed to sustain argon in a liquid phase; supplying the adsorbent bed with a liquid argon feed that is contaminated with oxygen and purifying the liquid argon thereby producing an argon product with less oxygen contaminant than is in the initial liquid argon feed; draining the purified residual liquid argon product and sending purified argon out of the adsorbent bed. Regeneration of specially prepared adsorbent allows the adsorbent bed to warm up to temperatures that preclude the use of requiring either vacuum or evacuation of adsorbent from the bed.
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公开(公告)号:US12059667B2
公开(公告)日:2024-08-13
申请号:US16966292
申请日:2019-02-14
发明人: Neil A. Stephenson , Philip A. Barrett , Steven J. Pontonio , Nicholas R. Stuckert , Garrett R. Swindlehurst
CPC分类号: B01J20/28011 , B01D53/0476 , B01J20/18 , B01J20/20 , B01J20/28004 , B01J20/28016 , B01J20/28019 , B01J20/2803 , B01J20/3028 , B01J20/3204 , B01J20/324 , B01J20/3293 , B01D2253/102 , B01D2253/1085 , B01D2253/116 , B01D2253/25 , B01D2253/304 , B01D2253/311 , B01D2256/10 , B01D2256/16 , B01D2257/104 , B01D2257/404 , B01D2257/504 , B01D2257/702
摘要: The present invention relates to a superior carbon adsorbent with or without a core. In one embodiment the carbon adsorbent of the present invention employs carbon adsorbent powder and an organic binding agent which are combined together with an appropriate solvent in an agglomeration step. In another embodiment the invention contemplates a core-in-shell adsorbent comprising an outer shell composed of a carbon and a non-adsorbing inert inner core. Low temperature processing of these agglomerates substantially preserves the binding agent within the final composition and allows one to prepare adsorbent products of high sphericity. The adsorbents of the invention possess superior characteristics such as higher mass transfer rate and CO2 working capacity for use in a H2PSA process.
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公开(公告)号:US20210252482A1
公开(公告)日:2021-08-19
申请号:US16973107
申请日:2019-07-01
摘要: The present invention relates to a surface modified zeolite adsorbent wherein the surface of said zeolite is modified with a coating comprised of a silicone derived species, said zeolite having a mean crystal size from about 5 to about 10 μm and a skeletal density of ≥1.10 gr./cc. The invention is based on the discovery that larger crystals tend to have higher particle density, and the packing of the larger crystals in agglomeration processes leads to more idealized packing to provide a larger mean-pore diameter. The surface modified adsorbent provides rate selectivity for one gas over others is described. The superior adsorbent has the added convenience of bead forming simultaneously with pore modification as well as having the treatment result in the yielding of high crush strength products.
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公开(公告)号:US20210031171A1
公开(公告)日:2021-02-04
申请号:US16966092
申请日:2019-02-14
IPC分类号: B01J20/32 , B01J20/28 , B01J20/18 , B01D53/047
摘要: The invention relates to a superior core-in-shell adsorbent comprising adsorbent, and an inert core, wherein said core possesses a porosity less than 10%, and has a volumetric thermal capacity greater than 1 J/K*cc. The adsorbents of the invention possess good physical strength, and allow a longer cycle time, thereby reducing the blowdown (vent) losses compared to known adsorbents.
The invention relates to an adsorber design for a vacuum/pressure swing adsorption (VSA, VPSA, PSA) process designed to obtain oxygen product from air utilizing the adsorbents of the invention.
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