公开(公告)号：US3778482A

公开(公告)日：1973-12-11

申请号：US3778482D

申请日：1971-04-19

申请人： PILOT CHEMICAL CO

发明人： MORRISROE J ,  BANIGAN T

IPC分类号： C07C29/09 ,  C07C31/22 ,  C07C33/025 ,  C07D309/10 ,  C07D309/12 ,  C07D319/06 ,  C11D1/29 ,  C11D1/72 ,  C11D3/20 ,  C07C31/18 ,  C07C43/04

CPC分类号： C07D309/10 ,  C07C29/095 ,  C07C31/22 ,  C07D319/06 ,  C10M3/00 ,  C10M2207/281 ,  C10M2207/282 ,  C10M2207/283 ,  C10M2207/286 ,  C11D1/29 ,  C11D1/72 ,  C11D3/2065 ,  C11D3/2068 ,  Y10S516/01 ,  Y10S516/03

摘要： DESCRIBED HEREIN IS A NOVEL CLASS OF COMPOUNDS OF FORMULA

R-CH(-OH)-CH(-OH)-CH2-CH2-OH

WHERE R IS A HYDROGEN OR LINEAR ALKYL GROUP FOR FROM 1 TO ABOUT 11 CARBON ATOMS. THE COMPOUNDS ARE PREPARED BY DIHYDROXYLATION OF A 3-ALKEN-1-OL, E.G., BY PEROXIDATION IN FORMIC ACID TO THE FORMATE ESTER WHICH LATTER IS HYDROLYZED TO THE 1,3,4-TRIOL OF THE INVENTION. THE MULTIFUNCTIONAL COMPOUNDS CAN BE CONVERTED TO SURFACTANTS, EMULSIFIERS AND LUBRICANTS, AND ARE USEFUL IN THE FORMATION OF URETHANES AND ALKYD-TYPE RESINS.

公开(公告)号：US3778479A

公开(公告)日：1973-12-11

申请号：US3778479D

申请日：1971-04-19

申请人： PILOT CHEMICAL CO

发明人： MORRISROE J ,  BANIGAN T

IPC分类号： C07C29/09 ,  C07C31/22 ,  C07C33/025 ,  C07D309/10 ,  C07D309/12 ,  C07D319/06 ,  C11D1/29 ,  C11D1/72 ,  C11D3/20 ,  C07C43/00 ,  C07C43/14

CPC分类号： C07D309/10 ,  C07C29/095 ,  C07C31/22 ,  C07D319/06 ,  C10M3/00 ,  C10M2207/281 ,  C10M2207/282 ,  C10M2207/283 ,  C10M2207/286 ,  C11D1/29 ,  C11D1/72 ,  C11D3/2065 ,  C11D3/2068 ,  Y10S516/01 ,  Y10S516/03

摘要： LINEAR 3-ALKEN-1-OLS OF FROM 11 TO 15 CARBON ATOMS ARE FORMED BY REACTING FORMALDEHYDE AND A LINEAR OLEFIN. COMPOUNDS EXHIBITING DESIRABLE DETERGENT PROPERTIES RESULT FROM SULFATION, ETHOXYLATION, ETHOXYLATION AND SULFATON, OR ETHOXYLATION AND DIHYDROXYLATION OF THE 3-ALKEN1-OLS.