公开(公告)号：US09663612B2

公开(公告)日：2017-05-30

申请号：US14722699

申请日：2015-05-27

Applicant: PHILLIPS 66 COMPANY ,  SOLARMER ENERGY, INC.

Inventor： Kathy Woody ,  Hui Huang ,  Ting He ,  Wei Wang ,  Chenjun Shi ,  Yue Wu

IPC: C08G75/00 ,  C08G61/12 ,  H01L51/00 ,  H01L51/42

CPC classification number: C08G61/126 ,  C08G2261/12 ,  C08G2261/1426 ,  C08G2261/1428 ,  C08G2261/146 ,  C08G2261/149 ,  C08G2261/18 ,  C08G2261/3223 ,  C08G2261/3243 ,  C08G2261/414 ,  C08G2261/91 ,  H01L51/0036 ,  H01L51/0043 ,  H01L51/4253 ,  Y02E10/549

Abstract: A process of polymerizing wherein the stoichiometric ratio of (f+g)≈(h+i) and f, g, h and i are not equal to 0. Additionally, R1, R2, R3 and R4 can be independently selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof and where the combination of R1, R2, R3 and R4 are not all identical. In addition, x and y can be different from each other and independently selected from the group consisting of: alkyl group, alkoxy group, aryl groups, where y=1-3, where y=0-12, where R5 is selected from the group consisting of H, alkyl group, alkoxy group, aryl groups, where R6 is selected from the group consisting of H, alkyl group, alkoxy group, aryl groups, where R7 and R8 are independently selected from the group consisting of H, alkyl group, alkoxy group, aryl groups, —NR9R10 where R9 and R10 are independently selected from the group consisting of H, alkyl group, alkoxy group, aryl groups.

公开(公告)号：US20150349259A1

公开(公告)日：2015-12-03

申请号：US14722433

申请日：2015-05-27

Applicant: PHILLIPS 66 COMPANY

Inventor： Kathy Woody ,  Hui Huang ,  Ting He

IPC: H01L51/00 ,  C08G75/06

CPC classification number: H01L51/0036 ,  H01L51/0043 ,  H01L51/0047 ,  H01L51/4253 ,  Y02E10/549

Abstract: A process of polymerizing f with wherein the stoichiometric ratio of f≈(g+h) and f, g and h are not equal to 0. This process can also have R1 selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof. Additionally, x and y can be different from each other and can be independently selected from the group consisting of: alkyl group, alkoxy group, aryl groups, where y=1-3, where y=0-12, where R2 is selected from the group consisting of H, alkyl group, alkoxy group, aryl groups, where R3 is selected from the group consisting of H, alkyl group, alkoxy group, aryl groups, where R4 and R5 are independently selected from the group consisting of H, alkyl group, alkoxy group, aryl groups, —NR6R7 where R6 and R7 are independently selected from the group consisting of H, alkyl group, alkoxy group, aryl groups.

Abstract translation: 聚合f的方法，其中f≈（g + h）和f，g和h的化学计量比不等于0.该方法还可以具有选自烷基，烷氧基，芳基 及其组合。 另外，x和y可以彼此不同，并且可以独立地选自：烷基，烷氧基，芳基，其中y = 1-3，其中y = 0-12，其中R 2选自 由H，烷基，烷氧基，芳基组成的组，其中R 3选自H，烷基，烷氧基，芳基，其中R 4和R 5独立地选自H，烷基 基团，烷氧基，芳基，-NR 6 R 7，其中R 6和R 7独立地选自H，烷基，烷氧基，芳基。

公开(公告)号：US20140058111A1

公开(公告)日：2014-02-27

申请号：US13954229

申请日：2013-07-30

Applicant: PHILLIPS 66 COMPANY

Inventor： Hui Huang

IPC: C07D513/04

CPC classification number: C07D513/04 ,  C07D277/68

Abstract: A process comprising the step of synthesizing 2,6-dibromo-4,8-dihexylbenzo[1, 2-d:4,5-d′]bis(thiazole) from 2,5-dihyxylbenzene-1,4-diamine.

Abstract translation: 一种包括从2,5-二羟基苯-1,4-二胺合成2,6-二溴-4,8-​​二己基苯并[1,2-d：4,5-d']双（噻唑）的步骤的方法。

公开(公告)号：US09673398B2

公开(公告)日：2017-06-06

申请号：US14722774

申请日：2015-05-27

Applicant: PHILLIPS 66 COMPANY ,  SOLARMER ENERGY, INC.

Inventor： Wei Wang ,  Jun Yang ,  Chenjun Shi ,  Christopher Daeffler ,  Janice Hawkins ,  Yue Wu ,  Ting He ,  Hui Huang ,  Amit Palkar ,  Kathy Woody ,  Joe Bullock

IPC: C08G75/00 ,  H01L51/00 ,  H01L51/42

CPC classification number: H01L51/0036 ,  H01L51/4253 ,  Y02E10/549

Abstract: A polymer having a monomer repeat unit comprising wherein Ar is an aryl group.

公开(公告)号：US09527963B2

公开(公告)日：2016-12-27

申请号：US14722650

申请日：2015-05-27

Applicant: PHILLIPS 66 COMPANY ,  SOLARMER ENERGY, INC.

Inventor： Wei Wang ,  Jun Yang ,  Chenjun Shi ,  Christopher Daeffler ,  Janice Hawkins ,  Yue Wu ,  Ting He ,  Hui Huang ,  Amit Palkar ,  Kathy Woody ,  Joe Bullock

IPC: C08G75/06 ,  C07D495/04 ,  C08G61/12 ,  A61K31/4162 ,  C07B59/00

CPC classification number: C08G75/06 ,  A61K31/4162 ,  C07B59/002 ,  C07D495/04 ,  C08G61/123

Abstract: A process of dissolving 3-fluoro-4,6-dihydrothieno[3,4-b]thiophene in a solvent to create a solution. An initiator is then added to the solution to produce an initiated solution followed by adding a fluorinated chemical to the initiated solution to produce 2,3-difluoro-4,6-dihydrothieno[3,4-b]thiophene. 2,3-difluoro-4,6-dihydrothieno[3,4-b]thiophene is then oxidized with an oxidant to produce 2,3-difluorothieno[3,4-b]thiophene. A brominating step then occurs to the 2,3-difluorothieno[3,4-b]thiophene to produce 4,6-dibromo-2,3-difluorothieno[2,3-c]thiophene 4,6-dibromo-2,3-difluorothieno[2,3-c]thiophene is then debrominated and polymerized to The stoichiometric ratio of (f+g)≈h and f, g and h are not equal to 0. Additionally, in this embodiment R1, R2, R3 and R4 are independently selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof and where the combination of R1, R2, R3 and R4 are not all identical.

Abstract translation: 将3-氟-4,6-二氢噻吩并[3,4-b]噻吩溶解在溶剂中以产生溶液的方法。 然后将引发剂加入到溶液中以产生引发的溶液，然后向引发的溶液中加入氟化物，得到2,3-二氟-4,6-二氢噻吩并[3,4-b]噻吩。 然后用氧化剂氧化2,3-二氟-4,6-二氢噻吩并[3,4-b]噻吩，得到2,3-二氟噻吩并[3,4-b]噻吩。 然后在2,3-二氟噻吩并[3,4-b]噻吩中发生溴化步骤，生成4,6-二溴-2,3-二氟噻吩并[2,3-c]噻吩。 然后将4,6-二溴-2,3-二氟噻吩并[2,3-c]噻吩脱溴并聚合成（f + g）≈h的化学计量比，f，g和h不等于0.另外， 在该实施方案中，R 1，R 2，R 3和R 4独立地选自烷基，烷氧基，芳基及其组合，并且其中R 1，R 2，R 3和R 4的组合不完全相同。

公开(公告)号：US20150349258A1

公开(公告)日：2015-12-03

申请号：US14722409

申请日：2015-05-27

Applicant: PHILLIPS 66 COMPANY

Inventor： Kathy Woody ,  Hui Huang ,  Ting He

IPC: H01L51/00 ,  C08G75/06

CPC classification number: H01L51/0036 ,  H01L51/0043 ,  H01L51/4253 ,  Y02E10/549

Abstract: A polymer having two different sets of repeat units consisting essentially of: Additionally, in the polymer R1 can be selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof. In the polymer, n and m can be greater than 1.In the polymer, x and y can be different from each other and independently selected from the group consisting of: an alkoxy group, a substituted alkoxy group, an aryl group, an alkyl group, a substituted alkyl group, where y=1-3, where y=0-12, where R2 is selected from the group consisting of H, alkyl groups, and aryl groups, where R3 is selected from the group consisting of H, alkyl groups, and aryl groups, where R4 and R5 are independently selected from the group consisting of H, alkyl groups, and aryl groups, —NR6R7 where R6 and R7 are independently selected from the group consisting of H, alkyl groups, and aryl groups.

Abstract translation: 具有两个不同组的重复单元的聚合物，其基本上由以下组成：另外，在聚合物R1中可以选自烷基，烷氧基，芳基及其组合。 在聚合物中，n和m可以大于1.在聚合物中，x和y可以彼此不同并且独立地选自：烷氧基，取代的烷氧基，芳基，烷基 基团，取代的烷基，其中y = 1-3，其中y = 0-12，其中R 2选自H，烷基和芳基，其中R 3选自H， 烷基和芳基，其中R 4和R 5独立地选自H，烷基和芳基，-NR 6 R 7，其中R 6和R 7独立地选自H，烷基和芳基 。

公开(公告)号：US20150344608A1

公开(公告)日：2015-12-03

申请号：US14722864

申请日：2015-05-27

Applicant: PHILLIPS 66 COMPANY ,  SOLARMER ENERGY, INC.

Inventor： Wei Wang ,  Jun Yang ,  Chenjun Shi ,  Christopher Daeffler ,  Janice Hawkins ,  Yue Wu ,  Ting He ,  Hui Huang ,  Amit Palkar ,  Kathy Woody ,  Joe Bullock

IPC: C08F228/06 ,  H01L51/00

CPC classification number: C08F228/06 ,  H01L51/0036 ,  H01L51/0043 ,  Y02E10/549

Abstract: A polymer having two different sets of repeat units consisting essentially of: In this polymer, R1, R2, R3 and R4 can be independently selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof. Also the combination of R1, R2, R3 and R4 are not all identical and n and o are greater than 1.

Abstract translation: 具有两个不同组的重复单元的聚合物基本上由以下组成：在该聚合物中，R 1，R 2，R 3和R 4可以独立地选自烷基，烷氧基，芳基及其组合。 R1，R2，R3和R4的组合也不完全相同，n和o大于1。

公开(公告)号：US20140151657A1

公开(公告)日：2014-06-05

申请号：US14084358

申请日：2013-11-19

Applicant: Solarmer Energy, Inc. ,  Phillips 66 Company

Inventor： Wei Wang ,  Chenjun Shi ,  Ruby Chen ,  Jun Yang ,  Yue Wu ,  Hui Huang ,  Kathy Woody ,  Joe Bullock ,  Amit Palkar ,  Ting He

IPC: H01L51/42

CPC classification number: H01L51/0043 ,  H01L51/0036 ,  H01L51/0047 ,  H01L51/4253 ,  Y02E10/549

Abstract: Compositions, synthesis and applications for furan, thiophene and selenophene derivatized benzo[1,2-b:3,4-b′]dithiophene(BDT)-thienothiophene (BDT-TT) based polymers, namely, poly[(4,8-bis(5-(2-ethyhexyl)selenophen-2-yl)-benzo[1,2-b;4,5-b′]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexanoyl)-3-fluorothieno[3,4-b]thiophene)-2-6-diyl (CS-15), poly[(4,8-bis(5-(2-ethyhexyl)selenophen-2-yl)-benzo[1,2-b;4,5-b′]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene)-2-carboxylate-2-6-diyl (CS-16), poly[(4,8-bis(5-(2-ethyhexyl)furan-2-yl)-benzo[1,2-b;4,5-b′]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexyl)-3-fluorothieno[3,4-b]thiophene)-2-carboxylate-2-6-diyl (CS-18) and poly[(4,8-bis(5-hexylfuran-2-yl)-benzo[1,2-b;4,5-b′]dithiophene)-2,6-diyl-alt-(4-(2-ethylhexanoyl)-3-fluorothieno[3,4-b]thiophene)-2-6-diyl (CS-24) are disclosed. Further, an organic solar cell constructed of a derivatized benzo[1,2-b:3,4-b′]dithiophene(BDT)-thienothiophene (BDT-TT) based polymer is discussed.

Abstract translation: 呋喃，噻吩和硒吩衍生的苯并[1,2-b：3,4-b']二噻吩（BDT） - 噻吩并噻吩（BDT-TT）基聚合物的组合物，合成和应用，即聚[（4,8- （5-（2-乙基己基）硒吩-2-基） - 苯并[1,2-b; 4,5-b']二噻吩）-2,6-二基-alt-（4-（2-乙基己酰基） -3-氟噻吩并[3,4-b]噻吩）-2-6-二基（CS-15），聚[（4,8-双（5-（2-乙基己基）硒吩-2-基） 1,2-b; 4,5-b']二噻吩）-2,6-二基-alt-（4-（2-乙基己基）-3-氟噻吩并[3,4-b]噻吩） （CS-16），聚[（4,8-双（5-（2-乙基己基）呋喃-2-基） - 苯并[1,2-b; 4,5-b']二噻吩 ）-2,6-二基-2-（4-（2-乙基己基）-3-氟噻吩并[3,4-b]噻吩）-2-羧酸酯-2,6-二基（CS-18）和聚[ 4,5-双（5-己基呋喃-2-基） - 苯并[1,2-b; 4,5-b']二噻吩）-2,6-二基-alt-（4-（2-乙基己酰基） 公开了3-氟噻吩并[3,4-b]噻吩）-2-6-二基（CS-24）。 此外，讨论了由衍生化的苯并[1,2-b：3,4-b']二噻吩（BDT） - 噻吩并噻吩（BDT-TT）基聚合物构成的有机太阳能电池。

公开(公告)号：US20140058110A1

公开(公告)日：2014-02-27

申请号：US13950720

申请日：2013-07-25

Applicant: PHILLIPS 66 COMPANY

Inventor： Hui Huang

IPC: C07D513/14

CPC classification number: C07D513/14 ,  C07D513/04 ,  H01L51/0035 ,  H01L51/0036 ,  H01L51/42

Abstract: A composition having the structure comprising: wherein Z is a halogen; wherein X is selected from the group consisting of N, O, P, S, and Se; wherein Y is selected from the group consisting of N, O, P, S and Se; and wherein R is an n-alkane chain.

Abstract translation: 一种具有以下结构的组合物：其中Z为卤素; 其中X选自N，O，P，S和Se; 其中Y选自N，O，P，S和Se; 并且其中R是正烷烃链。

公开(公告)号：US09537099B2

公开(公告)日：2017-01-03

申请号：US14722409

申请日：2015-05-27

Applicant: PHILLIPS 66 COMPANY

Inventor： Kathy Woody ,  Hui Huang ,  Ting He

IPC: C08G75/00 ,  H01L51/00 ,  H01L51/42

CPC classification number: H01L51/0036 ,  H01L51/0043 ,  H01L51/4253 ,  Y02E10/549

Abstract: A polymer having two different sets of repeat units consisting essentially of: Additionally, in the polymer R1 can be selected from the group consisting of alkyl group, alkoxy group, aryl groups and combinations thereof. In the polymer, n and m can be greater than 1.In the polymer, x and y can be different from each other and independently selected from the group consisting of: an alkoxy group, a substituted alkoxy group, an aryl group, an alkyl group, a substituted alkyl group, where y=1-3, where y=0-12, where R2 is selected from the group consisting of H, alkyl groups, and aryl groups, where R3 is selected from the group consisting of H, alkyl groups, and aryl groups, where R4 and R5 are independently selected from the group consisting of H, alkyl groups, and aryl groups, —NR6R7 where R6 and R7 are independently selected from the group consisting of H, alkyl groups, and aryl groups.

Abstract translation: 具有两个不同组的重复单元的聚合物，其基本上由以下组成：另外，在聚合物R1中可以选自烷基，烷氧基，芳基及其组合。 在聚合物中，n和m可以大于1.在聚合物中，x和y可以彼此不同并且独立地选自：烷氧基，取代的烷氧基，芳基，烷基 基团，取代的烷基，其中y = 1-3，其中y = 0-12，其中R 2选自H，烷基和芳基，其中R 3选自H， 烷基和芳基，其中R 4和R 5独立地选自H，烷基和芳基，-NR 6 R 7，其中R 6和R 7独立地选自H，烷基和芳基 。