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公开(公告)号:US11345779B2
公开(公告)日:2022-05-31
申请号:US16682628
申请日:2019-11-13
Applicant: Novamont S.p.A.
Inventor: Catia Bastioli , Giampietro Borsotti , Luigi Capuzzi , Roberto Vallero
IPC: C08G63/16 , C08G63/181 , C08G63/672 , C08L67/02 , C08L1/02 , C08L3/02 , C08L67/04 , C08L93/00 , C08J5/18
Abstract: Disclosed are aliphatic-aromatic biodegradable polyesters obtained from aliphatic dicarboxylic acids comprising azelaic acid, sebacic acid, suberic acid, brassylic acid and their esters; polyfunctional aromatic acids of renewable origin and particularly 2,5-furan dicarboxylic acid, and diols, such as 1,2-ethanediol, 1,2-propanediol, 1,3-propanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-haxanediol, 1,7-heptanediol, 1,8-octanediol, 1,9-nonanediol, 1,10-decanediol, 1,11-undecanediol, 1,12-dodecanediol, 1,13-tridecanediol, 1,4-cyclohexanedimethanol, propylene glycol, neopentyl glycol, 2-methyl-1,3-propanediol, dianhydrosorbitol, dianhydromannitol, dianhydroiditol, cyclohexanediol, cyclohexane-methanediol, aromatic diols such as phenols, and furan diol. Also disclosed are blends of the polyesters with other biodegradable polymers of either natural or synthetic origin. The polyesters have properties and viscosity values that make them suitable, after adjusting their molecular weight, for use in numerous practical applications such as films, injection molded products, extrusion coatings, fibers, foams, thermoformed products, extruded profiles and sheets, extrusion blow molding, injection blow molding, rotomolding, stretch blow molding.
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公开(公告)号:US10526442B2
公开(公告)日:2020-01-07
申请号:US14881640
申请日:2015-10-13
Applicant: Novamont S.p.A.
Inventor: Catia Bastioli , Giampietro Borsotti , Luigi Capuzzi , Roberto Vallero
IPC: C08G63/16 , C08G63/181 , C08G63/672 , C08L67/02 , C08L67/04 , C08L93/00 , C08J5/18 , C08L1/02 , C08L3/02
Abstract: Disclosed are aliphatic-aromatic biodegradable polyesters obtained from aliphatic dicarboxylic acids, polyfunctional aromatic acids of renewable origin and particularly 2,5-furan dicarboxylic acid, and diols. Also disclosed are blends of the polyesters with other biodegradable polymers of either natural or synthetic origin. The polyesters have properties and viscosity values that make them suitable, after adjusting their molecular weight, for use in numerous practical applications such as films, injection molded products, extrusion coatings, fibers, foams, thermoformed products, extruded profiles and sheets, extrusion blow molding, injection blow molding, rotomolding, stretch blow molding.
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公开(公告)号:US09868688B2
公开(公告)日:2018-01-16
申请号:US15049400
申请日:2016-02-22
Applicant: Novamont S.p.A.
Inventor: Arno Bieser , Giampietro Borsotti , Francesca Digioia , Adriano Ferrari , Alessandro Pirocco
IPC: C07C33/00 , C07C51/09 , C07C51/245 , C07C51/353 , C07C51/44 , B01D15/36 , C07C67/31 , C07C67/42
CPC classification number: C07C51/09 , B01D15/361 , C07C51/245 , C07C51/353 , C07C51/44 , C07C67/31 , C07C67/42 , C07C53/126 , C07C55/02
Abstract: Provided is a continuous process for the oxidative cleavage of derivatives of unsaturated carboxylic acids for the production of saturated carboxylic acids and their derivatives which comprises the steps of: a) feeding to a first reactor at least a derivative of an unsaturated carboxylic acid, an oxidizing compound and a catalyst capable of catalyzing the oxidation reaction of the olefinic double bond to obtain an intermediate compound containing vicinal diols, and of b) feeding to a second reactor said intermediate compound, a compound containing oxygen and a catalyst capable of catalyzing the oxidation reaction of the vicinal diols to carboxylic groups, to obtain saturated monocarboxylic acids (i) and derivatives of saturated carboxylic acids with more than one acid function (ii); c) separating the saturated monocarboxylic acids (i) from the derivatives of carboxylic acids having more than one acid function (ii).
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公开(公告)号:US20160244394A1
公开(公告)日:2016-08-25
申请号:US15143838
申请日:2016-05-02
Applicant: Novamont S.p.A.
Inventor: Arno Bieser , Giampietro Borsotti , Francesca Digioia , Adriano Ferrari , Alessandro Pirocco
IPC: C07C51/285 , C07C51/347
CPC classification number: C07C51/285 , C07C51/09 , C07C51/16 , C07C51/245 , C07C51/347 , C07C51/353 , C11C1/04 , C07C55/02 , C07C55/18 , C07C53/126
Abstract: A continuous process for the oxidative cleavage of vegetable oils containing triglycerides of unsaturated carboxylic acids, to obtain saturated carboxylic acids, comprising feeding to a first continuous reactor a vegetable oil, an oxidizing compound and catalyst capable of catalyzing the oxidation reaction of the olefinic double bond to obtain an intermediate compound containing vicinal diols: feeding to a second continuous reactor said intermediate compound, a compound containing oxygen and a catalyst capable of catalyzing the oxidation reaction of the vicinal diols to carboxylic groups, to obtain saturated monocarboxylic acids (i) and triglycerides containing saturated carboxylic acids with more than one acid function (ii); separating the saturated monocarboxylic acids (i) from the triglycerides (ii); hydrolyzing in a third reactor the triglycerides (ii) to obtain glycerol and saturated carboxylic acids with more than one acid function; and purifying said saturated carboxylic acids by fractioned crystallization by means of wash column (melt crystallization).
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公开(公告)号:US20160137580A1
公开(公告)日:2016-05-19
申请号:US14900762
申请日:2014-06-25
Applicant: NOVAMONT S.P.A
Inventor: Giampietro Borsotti , Luigi Capuzzi , Francesca Digioia
Abstract: This invention relates to a process for the selective hydrogenation of vegetable oils. In particular the invention relates to a process for the hydrogenation of vegetable oils which is capable of selectively converting polyunsaturated fatty acids into mono-unsaturated fatty acids and products obtained therefrom. The vegetable oils obtained from the process according to the invention have in particular a high mono-unsaturated fatty acids content and are particularly suitable for use as raw materials for the synthesis of chemical intermediates.
Abstract translation: 本发明涉及植物油的选择性氢化方法。 特别地,本发明涉及能够选择性地将多不饱和脂肪酸转化为单不饱和脂肪酸和由其获得的产品的植物油氢化方法。 从本发明方法得到的植物油具有特别高的单不饱和脂肪酸含量,特别适用于合成化学中间体的原料。
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6.
公开(公告)号:US20150152354A1
公开(公告)日:2015-06-04
申请号:US14408972
申请日:2013-06-18
Applicant: Novamont S.p.A.
Inventor: Giampietro Borsotti , Francesca Digioia
IPC: C11C3/10
Abstract: The invention relates to a process for the preparation of complex oligomeric structures obtained from vegetable oils. These structures comprise esters containing acid groups which are in turn esterified.
Abstract translation: 本发明涉及制备由植物油获得的复合低聚结构的方法。 这些结构包含酯酸酯,它们又被酯化。
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公开(公告)号:US20200079899A1
公开(公告)日:2020-03-12
申请号:US16682628
申请日:2019-11-13
Applicant: Novamont S.p.A.
Inventor: Catia Bastioli , Giampietro Borsotti , Luigi Capuzzi , Roberto Vallero
IPC: C08G63/16 , C08L67/02 , C08G63/672 , C08G63/181 , C08J5/18
Abstract: Disclosed are aliphatic-aromatic biodegradable polyesters obtained from aliphatic dicarboxylic acids, polyfunctional aromatic acids of renewable origin and particularly 2,5-furan dicarboxylic acid, and diols. Also disclosed are blends of the polyesters with other biodegradable polymers of either natural or synthetic origin. The polyesters have properties and viscosity values that make them suitable, after adjusting their molecular weight, for use in numerous practical applications such as films, injection molded products, extrusion coatings, fibers, foams, thermoformed products, extruded profiles and sheets, extrusion blow molding, injection blow molding, rotomolding, stretch blow molding.
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8.
公开(公告)号:US10450631B2
公开(公告)日:2019-10-22
申请号:US15542852
申请日:2016-01-20
Applicant: Novamont S.p.A.
Inventor: Giampietro Borsotti , Francesca Digioia
IPC: C22B3/42 , C22B34/36 , B01J39/04 , B01J47/02 , B01J39/05 , B01J39/20 , C02F1/42 , C22B3/00 , C02F1/26 , C02F101/20 , C02F103/32 , C02F101/32
Abstract: This invention relates to a process for the recovery of cobalt ions and tungstic acid and/or its derivatives from aqueous solutions, such as in particular the spent catalytic waters deriving from processes for the oxidative cleavage of vegetable oils. In particular this invention relates to a process for the recovery of cobalt ions and tungstic acid and/or its derivatives which provides for the use of cation-exchange resins.
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公开(公告)号:US10208271B2
公开(公告)日:2019-02-19
申请号:US15538352
申请日:2015-12-21
Applicant: Novamont S.p.A.
Inventor: Giampietro Borsotti , Luigi Capuzzi , Francesca DiGioia
IPC: C11C3/12 , C07C67/303 , C07C69/587
Abstract: Process for the catalytic hydrogenation of vegetable oils wherein the oil is placed in contact with molecular hydrogen in the presence of a metal catalyst, and the process is performed in the absence of water or in the presence of a quantity of water equal to or less than 5:1 with respect to the weight of the metal catalyst and at a temperature equal to or less than 50° C.
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公开(公告)号:US10150725B2
公开(公告)日:2018-12-11
申请号:US15697515
申请日:2017-09-07
Applicant: Novamont S.p.A.
Inventor: Arno Bieser , Giampietro Borsotti , Francesca Digioia , Adriano Ferrari , Alessandro Pirocco
IPC: C07C51/285 , C07C51/16 , C07C51/09 , C07C51/245 , C07C51/353 , C07C51/347 , C11C1/04
Abstract: A continuous process for the oxidative cleavage of vegetable oils containing triglycerides of unsaturated carboxylic acids, to obtain saturated carboxylic acids, comprising feeding to a first continuous reactor a vegetable oil, an oxidizing compound and catalyst capable of catalyzing the oxidation reaction of the olefinic double bond to obtain an intermediate compound containing vicinal diols: feeding to a second continuous reactor said intermediate compound, a compound containing oxygen and a catalyst capable of catalyzing the oxidation reaction of the vicinal diols to carboxylic groups, to obtain saturated monocarboxylic acids (i) and triglycerides containing saturated carboxylic acids with more than one acid function (ii); separating the saturated monocarboxylic acids (i) from the triglycerides (ii); hydrolyzing in a third reactor the triglycerides (ii) to obtain glycerol and saturated carboxylic acids with more than one acid function; and purifying said saturated carboxylic acids by fractioned crystallization by means of wash column (melt crystallization).
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