Aliphatic-aromatic biodegradable polyester

    公开(公告)号:US11345779B2

    公开(公告)日:2022-05-31

    申请号:US16682628

    申请日:2019-11-13

    Abstract: Disclosed are aliphatic-aromatic biodegradable polyesters obtained from aliphatic dicarboxylic acids comprising azelaic acid, sebacic acid, suberic acid, brassylic acid and their esters; polyfunctional aromatic acids of renewable origin and particularly 2,5-furan dicarboxylic acid, and diols, such as 1,2-ethanediol, 1,2-propanediol, 1,3-propanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-haxanediol, 1,7-heptanediol, 1,8-octanediol, 1,9-nonanediol, 1,10-decanediol, 1,11-undecanediol, 1,12-dodecanediol, 1,13-tridecanediol, 1,4-cyclohexanedimethanol, propylene glycol, neopentyl glycol, 2-methyl-1,3-propanediol, dianhydrosorbitol, dianhydromannitol, dianhydroiditol, cyclohexanediol, cyclohexane-methanediol, aromatic diols such as phenols, and furan diol. Also disclosed are blends of the polyesters with other biodegradable polymers of either natural or synthetic origin. The polyesters have properties and viscosity values that make them suitable, after adjusting their molecular weight, for use in numerous practical applications such as films, injection molded products, extrusion coatings, fibers, foams, thermoformed products, extruded profiles and sheets, extrusion blow molding, injection blow molding, rotomolding, stretch blow molding.

    CONTINUOUS PROCESS OF OXIDATIVE CLEAVAGE OF VEGETABLE OILS

    公开(公告)号:US20160244394A1

    公开(公告)日:2016-08-25

    申请号:US15143838

    申请日:2016-05-02

    Abstract: A continuous process for the oxidative cleavage of vegetable oils containing triglycerides of unsaturated carboxylic acids, to obtain saturated carboxylic acids, comprising feeding to a first continuous reactor a vegetable oil, an oxidizing compound and catalyst capable of catalyzing the oxidation reaction of the olefinic double bond to obtain an intermediate compound containing vicinal diols: feeding to a second continuous reactor said intermediate compound, a compound containing oxygen and a catalyst capable of catalyzing the oxidation reaction of the vicinal diols to carboxylic groups, to obtain saturated monocarboxylic acids (i) and triglycerides containing saturated carboxylic acids with more than one acid function (ii); separating the saturated monocarboxylic acids (i) from the triglycerides (ii); hydrolyzing in a third reactor the triglycerides (ii) to obtain glycerol and saturated carboxylic acids with more than one acid function; and purifying said saturated carboxylic acids by fractioned crystallization by means of wash column (melt crystallization).

    PROCESS FOR THE SELECTIVE HYDROGENATION OF VEGETABLE OILS
    5.
    发明申请
    PROCESS FOR THE SELECTIVE HYDROGENATION OF VEGETABLE OILS 有权
    植物油选择性加氢方法

    公开(公告)号:US20160137580A1

    公开(公告)日:2016-05-19

    申请号:US14900762

    申请日:2014-06-25

    Applicant: NOVAMONT S.P.A

    CPC classification number: C07C51/36 B01J23/44 C11C3/126

    Abstract: This invention relates to a process for the selective hydrogenation of vegetable oils. In particular the invention relates to a process for the hydrogenation of vegetable oils which is capable of selectively converting polyunsaturated fatty acids into mono-unsaturated fatty acids and products obtained therefrom. The vegetable oils obtained from the process according to the invention have in particular a high mono-unsaturated fatty acids content and are particularly suitable for use as raw materials for the synthesis of chemical intermediates.

    Abstract translation: 本发明涉及植物油的选择性氢化方法。 特别地,本发明涉及能够选择性地将多不饱和脂肪酸转化为单不饱和脂肪酸和由其获得的产品的植物油氢化方法。 从本发明方法得到的植物油具有特别高的单不饱和脂肪酸含量,特别适用于合成化学中间体的原料。

    ALIPHATIC-AROMATIC BIODEGRADABLE POLYESTER
    7.
    发明申请

    公开(公告)号:US20200079899A1

    公开(公告)日:2020-03-12

    申请号:US16682628

    申请日:2019-11-13

    Abstract: Disclosed are aliphatic-aromatic biodegradable polyesters obtained from aliphatic dicarboxylic acids, polyfunctional aromatic acids of renewable origin and particularly 2,5-furan dicarboxylic acid, and diols. Also disclosed are blends of the polyesters with other biodegradable polymers of either natural or synthetic origin. The polyesters have properties and viscosity values that make them suitable, after adjusting their molecular weight, for use in numerous practical applications such as films, injection molded products, extrusion coatings, fibers, foams, thermoformed products, extruded profiles and sheets, extrusion blow molding, injection blow molding, rotomolding, stretch blow molding.

    Continuous process of oxidative cleavage of vegetable oils

    公开(公告)号:US10150725B2

    公开(公告)日:2018-12-11

    申请号:US15697515

    申请日:2017-09-07

    Abstract: A continuous process for the oxidative cleavage of vegetable oils containing triglycerides of unsaturated carboxylic acids, to obtain saturated carboxylic acids, comprising feeding to a first continuous reactor a vegetable oil, an oxidizing compound and catalyst capable of catalyzing the oxidation reaction of the olefinic double bond to obtain an intermediate compound containing vicinal diols: feeding to a second continuous reactor said intermediate compound, a compound containing oxygen and a catalyst capable of catalyzing the oxidation reaction of the vicinal diols to carboxylic groups, to obtain saturated monocarboxylic acids (i) and triglycerides containing saturated carboxylic acids with more than one acid function (ii); separating the saturated monocarboxylic acids (i) from the triglycerides (ii); hydrolyzing in a third reactor the triglycerides (ii) to obtain glycerol and saturated carboxylic acids with more than one acid function; and purifying said saturated carboxylic acids by fractioned crystallization by means of wash column (melt crystallization).

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