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公开(公告)号：US4595650A
公开(公告)日：1986-06-17
申请号：US632738
申请日：1984-07-20
IPC分类号： C07D231/52 , C07D233/88 , G03C7/26 , G03C7/38 , G03C7/384 , G03C7/16
摘要： A silver halide color photographic light-sensitive material is described, comprising a support having coated thereon at least one silver halide emulsion layer, the color photographic light-sensitive material having a photographic layer containing at least one kind of magenta coupler of 5-pyrazolone type having an arylthio group at the coupling position thereof, the arylthio group having an alkoxy group or an aryloxy group at the ortho position to the sulfur atom thereof and the alkoxy group and the aryloxy group being substituted with a cyano group, a halogen atom, a sulfonyl group, a sulfinyl group, a phosphonyl group, or an ##STR1## group, wherein A represents a chemical bond, an alkylene group, an arylene group, an oxygen atom, a sulfur atom, or an imino group; and B represents a hydroxy group, an alkoxy group, an aryloxy group, a hydrogen atom, an alkyl group, an aryl group, a heterocyclic group, an acyclic amino group, or a hydrazino group.The silver halide color photographic light-sensitive material containing the 2-equivalent magenta coupler has an excellent color forming property even when it is processed in a color developing solution containing a salt of alkaline earth metal, exhibits photographic properties which are not influenced by variations in the pH of the color developing solution, and provides a magenta color image having a good light fastness. A method of forming a color image using the silver halide color photographic light-sensitive material is also described.
摘要翻译： 描述了一种卤化银彩色摄影感光材料，其包括在其上涂覆有至少一个卤化银乳剂层的载体，该彩色摄影感光材料具有含有至少一种5-吡唑啉酮型品红成色剂的照相层 在其偶联位置具有芳硫基，在其与硫原子的邻位具有烷氧基或芳氧基的芳硫基，并且所述烷氧基和所述芳氧基被氰基，卤素原子， 磺酰基，亚磺酰基，膦酰基或
基，其中A表示化学键，亚烷基，亚芳基，氧原子，硫原子或亚氨基; B表示羟基，烷氧基，芳氧基，氢原子，烷基，芳基，杂环基，无环氨基或肼基。 含有2-当量品红成色剂的卤化银彩色摄影感光材料即使在含有碱土金属盐的显色溶液中加工也具有优异的成色性，具有不受 显色液的pH值，提供耐光性好的品红色图像。 还描述了使用卤化银彩色照相感光材料形成彩色图像的方法。 -
2.发明授权Silver halide color photographic material comprising specified couplers and anti-fading agents 失效卤化银彩色照相材料包含特定的成色剂和抗褪色剂
公开(公告)号：US4906555A
公开(公告)日：1990-03-06
申请号：US267620
申请日：1988-11-03
CPC分类号： G03C7/3225 , Y10S430/132
摘要： A multilayer silver halide color photographic material comprising a reflective support and a blue-, green- and red-sensitive emulsion layer containing at least one yellow coupler (represented by the general formula (I)), magenta coupler (represented by the general formula (II)), and cyan coupler (represented by the general formula (III)), respectively, and the blue-sensitive emulsion layer also contains at least one compound represented by the general formulae (A) or (B), all compounds are as disclosed in the specification.
摘要翻译： 包含反射性支持体和含有至少一种黄色成色剂（由通式（I）表示））的红，蓝，红和红敏感的乳剂层的多层卤化银彩色照相材料，品红色成色剂（由通式 II））和青色成色剂（由通式（III）表示），蓝敏感性乳剂层还含有至少一种由通式（A）或（B）表示的化合物，所有化合物均为 在说明书中公开。
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3.发明授权
公开(公告)号：US4865963A
公开(公告)日：1989-09-12
申请号：US913792
申请日：1986-09-30
申请人： Nobuo Furutachi , Tadahisa Sato , Seiki Sakanoue , Akio Mitsui , Minoru Sakai , Masakazu Morigaki , Hidetoshi Kobayashi , Nobuo Sakai , Kiyoshi Nakazyo , Takeshi Hirose , Toshio Kawagishi
发明人： Nobuo Furutachi , Tadahisa Sato , Seiki Sakanoue , Akio Mitsui , Minoru Sakai , Masakazu Morigaki , Hidetoshi Kobayashi , Nobuo Sakai , Kiyoshi Nakazyo , Takeshi Hirose , Toshio Kawagishi
IPC分类号： C07D487/04 , G03C7/30 , G03C7/305 , G03C7/38
CPC分类号： C07D487/04 , G03C7/301 , G03C7/30529 , G03C7/3835
摘要： A silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer, said silver halide emulsion layer containing a pyrazoloazole series magenta coupler represented by general formula [I] ##STR1## wherein, R.sup.1 and R.sup.2 each represents a hydrogen atom or a substituent; and X represents a hydrogen atom or a releasing group which is released at the reaction with the oxidation product of an aromatic primary amine developing agent; at least one of said R.sup.1 and R.sup.2 is an alkyl group having a secondary or tertiary carbon atom directly bonded to the skeleton, at least one of said R.sub.1 and R.sub.2 is a sulfonamidoalkyl group or a sulfamoylalkyl group; and the magenta coupler may form a dimer or more polymer at the position of said R.sup.1, R.sup.2 or X.By the combined use of high boiling point organic solvent and ultraviolet absorbent, light fastness and coloring property are markedly improved.
摘要翻译： 一种卤化银彩色照相材料，包括其上具有至少一个卤化银乳剂层的载体，所述卤化银乳剂层含有由通式[I]表示的吡唑并苯系列品红成色剂，其中R1和R2各自表示 氢原子或取代基; X表示在与芳族伯胺显影剂的氧化产物反应时释放的氢原子或释放基团; 所述R 1和R 2中的至少一个是具有与所述骨架直接键合的仲或叔碳原子的烷基，所述R 1和R 2中的至少一个是亚磺酰氨基烷基或氨磺酰基烷基; 并且品红色成色剂可以在所述R1，R2或X的位置形成二聚体或更多聚合物。通过组合使用高沸点有机溶剂和紫外线吸收剂，耐光性和着色性显着提高。
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公开(公告)号：USH706H
公开(公告)日：1989-11-07
申请号：US237205
申请日：1988-08-29
CPC分类号： G03C7/39236
摘要： A silver halide color photosensitive material is disclosed, characterized in that a lipophilic fine grain dispersed in at least one hydrophilic colloidal layer formed on a support contains at least one compound of formula (I) and at least one compound of formula (II):R.sub.1 --SO.sub.2.M.sub.1 (I)R.sub.2 --SO.sub.3.M.sub.2 (II)wherein each of R.sub.1 and R.sub.2 represents an aliphatic group having 8 or more carbon atoms, an aromatic group having 8 or more carbon atoms or a heterocyclic group having 8 or more carbon atoms; each of M.sub.1 and M.sub.2 represents a hydrogen atom or an inorganic or organic salt-forming atom or atomic group; also M.sub.1 represents a protective group to be hydrolyzed with alkali; and sodium dodecylbenzenesulfonate is excluded from the compounds of formula (II). The combined use of the compounds of formulae (I) and (II) can effectively control the formation of stains on the processed white ground after the lapse of time without substantially lowering the maximum color density.
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公开(公告)号：US4983507A
公开(公告)日：1991-01-08
申请号：US262603
申请日：1988-10-26
CPC分类号： G03C7/3805 , G03C7/39252
摘要： The present invention provides silver halide color photographic materials having a layer which contains at least one magenta color image-forming oleophilic coupler of the following formulae (I) and/or (II) and at least one of the following formula (III): ##STR1## in which Ar represents a phenyl group which is substituted by at least one substituent selected from the group consisting of a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group and a cyano group; Y represents an acylamino group or an anilino group; and Z.sub.1 represents a group capable of being removed by coupling, ##STR2## in which X represents a hydrogen atom or a substituent; Z.sub.2 represents a hydrogen atom or a group capable of being removed by coupling;W represents a hydrogen atom, an acyl group or an aliphatic or aromatic sulfonyl group;Za and Zb each represent a methine group, a substituted methine group or --N.dbd.; andX, Z.sub.2 or the substituted methine of Za or Zb may form a dimer or higher polymer, ##STR3## in which A represents an alkyl group, an aryl group, a heterocyclic group, an acyl group, an alkoxy group, an aryloxy group, a heterocyclic oxy group, an alkylthio group, an arylthio group or an amino group, which may be substituted or unsubstituted; R.sub.1 and R.sub.2 each independently represents a hydrogen atom or a substituted or unsubstituted alkyl group; R.sub.3a and R.sub.3b each represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group or an arylthio group; R.sub.4 represents an alkyl group, an aryl group or a heterocyclic group; and D represents an oxygen atom or a sulfur atom.The use of the combination of the magenta coupler(s) of the formulae (I) and/or (II) and the stain-inhibitory additive(s) of the formula (II) provides photographic light-sensitive materials that are almost free from stains when such materials are preserved for a long period of time after having been exposed, developed and then photographically processed.
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6.发明授权
公开(公告)号：US4559297A
公开(公告)日：1985-12-17
申请号：US699091
申请日：1985-02-07
CPC分类号： G03C7/39288 , C07F7/0812 , C07F7/0818
摘要： A silver halide photographic light-sensitive material is described, the material comprising a support having thereon at least one photographic layer containing at least one compound represented by formula (I): ##STR1## wherein R represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted heterocyclic group, ##STR2## a substituted or unsubstituted silyl group, a substituted or unsubstituted phosphoric acid group, or a divalent group derived from the above-described groups which forms a ring together with the oxygen atom linking to --R and the carbon atom which is in the ortho-position to --O--R and to which ##STR3## is not bonded; R.sub.1, R.sub.2 and R.sub.3 which may be the same or different each represents a hydrogen atom, an alkyl group, an alkenyl group, a cycloalkyl group, an aralkyl group, an aryl group or a substituent thereof; Q represents an atomic group necessary to form a substituted or unsubstituted aromatic ring; R.sub.4 represents a hydrogen atom, an alkyl group, a cycloalkyl group, an alkenyl group, an aryl group, an alkoxy group, an aryloxy group, an amino group, a cycloamino group, an alkylthio group, an arylthio group, an acyl group, an alkoxycarbonyl group or a substituent thereof; and R.sub.5 represents an H atom, an alkyl group, a cycloalkyl group, an alkenyl group, an aryl group or a substituent thereof.
摘要翻译： 描述了一种卤化银照相感光材料，该材料包括其上具有至少一个含有至少一种由式（I）表示的化合物的照相层的载体：其中R表示氢原子，取代的 或未取代的烷基，取代或未取代的烯基，取代或未取代的环烷基，取代或未取代的芳基，取代或未取代的杂环基，取代或未取代的甲硅烷基，取代或未取代的磷酸基 或衍生自上述基团的二价基团，其与连接到-R的氧原子和与-OR邻位并且未键合的碳原子一起形成环; 可以相同或不同的R 1，R 2和R 3表示氢原子，烷基，烯基，环烷基，芳烷基，芳基或其取代基; Q表示形成取代或未取代的芳环所必需的原子团; R4表示氢原子，烷基，环烷基，烯基，芳基，烷氧基，芳氧基，氨基，环氨基，烷硫基，芳硫基，酰基， 烷氧基羰基或其取代基; R5代表H原子，烷基，环烷基，烯基，芳基或取代基。
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公开(公告)号：US4351897A
公开(公告)日：1982-09-28
申请号：US291886
申请日：1981-08-11
申请人： Kozo Aoki , Nobuo Seto , Yoshiharu Yabuki , Masakazu Morigaki , Nobuo Furutachi , Kotaro Nakamura
发明人： Kozo Aoki , Nobuo Seto , Yoshiharu Yabuki , Masakazu Morigaki , Nobuo Furutachi , Kotaro Nakamura
IPC分类号： G03C7/38 , C07D231/52 , C09B26/02 , G03C7/384 , G03C1/40
CPC分类号： C07D231/52 , G03C7/384
摘要： A silver halide color photographic light-sensitive material is described comprising a support having thereon a photographic layer containing at least one coupler represented by formula (I) or (II) ##STR1## wherein Ar represents a phenyl group substituted with at least one substituent selected from a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group and a cyano group; X represents a halogen atom or an alkoxy group; R.sub.1 represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, an acylamino group, a sulfonamido group, a sulfamoyl group, a carbamoyl group, a diacylamino group, an alkoxycarbonyl group, an alkoxysulfonyl group, an aryloxysulfonyl group, an alkanesulfonyl group, an arylsulfonyl group, an alkylthio group, an arylthio group, an alkyloxycarbonylamino group, an alkylureido group, an acyl group, a nitro group, a carboxy group, or a trifluoromethyl group; R.sub.2 represents a halogen atom, a hydroxy group, an alkyl group, an alkoxy group or an aryl group; R.sub.3 represents a hydrogen atom, a halogen atom, a hydroxy group, an alkyl group, an alkoxy group or an aryl group; at least one of R.sub.2 and R.sub.3 represents an alkoxy group; m.sub.1 and m.sub.2 each represents an integer from 1 to 4; R.sub.4 represents an alkyl group or an aryl group; R.sub.5 represents a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group or an aryl group; n represents an integer from 1 to 6; and when m.sub.1, m.sub.2 and n each is 2 or more, each R.sub.1, R.sub.3 and R.sub.5 may be the same or different.The color photographic light-sensitive material containing a 2-equivalent magenta color image-forming coupler as described above has various advantages, for example, in that the dye formation efficiency in the color development step is high, the photographic properties are not influenced by variations in the pH of the color development bath, and the color images formed are fast to heat or light.
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8.发明授权Color photographs, a process for preparing them and color photographic material employed therefor 失效彩色摄影，其制作方法及其使用的彩色摄影材料
公开(公告)号：US5098805A
公开(公告)日：1992-03-24
申请号：US501400
申请日：1990-03-19
IPC分类号： C07D207/46 , C07D213/68 , C07D215/32 , C07D231/08 , C07D231/12 , C07D231/20 , C07D231/22 , C07D231/24 , C07D231/32 , C07D233/66 , C07D237/32 , C07D251/26 , C07D261/12 , C07D263/40 , C07D267/10 , C07D271/06 , C07D277/82 , C07D295/02 , C07D309/40 , C07D311/04 , C07D311/58 , C07D311/72 , C07D417/04 , C07D417/06 , C07D473/08 , C07D487/04 , C07D493/10 , C07D521/00 , G03C7/26 , G03C7/392
CPC分类号： G03C7/39296 , G03C7/39236
摘要： There is provided a color photograph improved in preservability that has been obtained by making chemically inactive the aromatic amine type color developing agents and their oxidized product that remains in the silver halide photographic materials after color development processing. The color photograph exhibits excellent performance in that its white background can be prevented from discoloring even during long-term storage or display, and deterioration of a dye image caused by the remaining color developing agent being taken into the photographic material after the color development, bleaching, and fixing processes, or due to its oxidized product, can be prevented.
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公开(公告)号：US5041365A
公开(公告)日：1991-08-20
申请号：US555676
申请日：1990-07-19
CPC分类号： G03C7/3805 , G03C7/39252
摘要： The present invention provides silver halide color photographic materials having a layer which contains at least one magenta color image-forming oleophilic coupler of the following formulae (I) and/or (II) and at least one of the following formula (III): ##STR1## in which Ar represents a phenyl group which is substituted by at least one substituent selected from the group consisting of a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group and a cyano group; Y represents an acylamino group or an anilino group; and Z.sub.1 represents a group capable of being removed by coupling, ##STR2## in which X represents a hydrogen atom or a substituent; Z.sub.2 represents a hydrogen atom or a group capable of being removed by coupling;W represents a hydrogen atom, an acyl group or an aliphatic or aromatic sulfonyl group;Za and Zb each represent a methine group, a substituted methine group or --N.dbd.; andX, Z.sub.2 or the substituted methine of Za or Zb may form a dimer or higher polymer, ##STR3## in which A represents an alkyl group, an aryl group, a heterocyclic group, an acyl group, an alkoxy group, an aryloxy group, a heterocyclic oxy group, an alkylthio group, an arylthio group or an amino group, which may be substituted or unsubstituted; R.sub.1 and R.sub.2 each independently represents a hydrogen atom or a substituted or unsubstituted alkyl group; R.sub.3a and R.sub.3b each represents a hydrogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group or an arylthio group; R.sub.4 represents an alkyl group, an aryl group or a heterocyclic group; and D represents an oxygen atom or a sulfur atom.The use of the combination of the magenta couplers(s) of the formulae (I) and/or (II) and the stain-inhibitory additive(s) of the formula (III) provides photographic light-sensitive materials that are almost free from stains when such materials are preserved for a long period of time after having been exposed, developed and then photographically processed.
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公开(公告)号：US4266020A
公开(公告)日：1981-05-05
申请号：US81986
申请日：1979-10-04
CPC分类号： G03C7/39268
摘要： A color photographic color coupler-containing light-sensitive material containing, in a photographic layer, at least one compound represented by the following general formula (I): ##STR1## wherein R.sub.1 represents a hydrogen atom, an alkyl group, a heterocyclic group, a dialkylsilyl group, a trialkylsilyl group, an alkanesulfonyl group, an arylsulfonyl group, an aralknesulfonyl group or an -X-Y group in which X represents a carbonyl group, and Y represents an alkyl group, an aryl group, an aralkyl group, an alkoxy group, an aryloxy group, an aralkoxy group, an alkylamino group, a dialkylamino group, an arylamino or diarylamino group, an alkoxycarbonyl group, an aryloxycarbonyl group, an aralkoxycarbonyl group or an acyl group; R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents a hydrogen atom, an alkyl group, an alkoxy group, an aryl group, an aryloxy group, an aralkyl group, an aralkoxy group, an alkenyl group, an alkenoxy group, an acylamino group, a halogen atom, an alkylthio group, an arylthio group, a diacylamino group, an acyl group, a sulfonamido group, an alkylamino group, an alkoxycarbonyl group or an acyloxy group; and R.sub.5 and R.sub.6, which may be the same or different, each represents a hydrogen atom, an alkyl group, an aryl group or an aralkyl group, or R.sub.5 and R.sub.6 are bonded each other to form a 5-membered, 6-membered or 7-membered ring.
摘要翻译： 一种含彩色照相彩色成色剂的感光材料，其在照相层中含有至少一种由以下通式（I）表示的化合物：其中R 1表示氢原子，烷基， 杂环基，二烷基甲硅烷基，三烷基甲硅烷基，链烷磺酰基，芳基磺酰基，芳烷基磺酰基或-XY基，X表示羰基，Y表示烷基，芳基，芳烷基， 烷氧基，芳氧基，芳烷氧基，烷基氨基，二烷基氨基，芳基氨基或二芳基氨基，烷氧基羰基，芳氧基羰基，芳烷氧基羰基或酰基; R2，R3和R4可以相同或不同，分别表示氢原子，烷基，烷氧基，芳基，芳氧基，芳烷基，芳烷氧基，烯基，烯氧基 基团，酰氨基，卤素原子，烷硫基，芳硫基，二酰基氨基，酰基，亚磺酰氨基，烷基氨基，烷氧基羰基或酰氧基; R 5和R 6可以相同或不同，各自表示氢原子，烷基，芳基或芳烷基，或者R 5和R 6相互键合形成5元，6元或 7元环。
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