Negative electrode material for non-aqueous electrolyte secondary battery, process for producing the same, negative electrode, and non-aqueous electrolyte secondary battery
    4.
    发明授权
    Negative electrode material for non-aqueous electrolyte secondary battery, process for producing the same, negative electrode, and non-aqueous electrolyte secondary battery 有权
    用于非水电解质二次电池的负极材料,其制造方法,负极和非水电解质二次电池

    公开(公告)号:US07858239B2

    公开(公告)日:2010-12-28

    申请号:US11991628

    申请日:2006-09-05

    IPC分类号: H01M4/58 C01B31/02

    摘要: A negative electrode material for non-aqueous electrolyte secondary batteries, which is best suited for large current I/O non-aqueous electrolyte secondary batteries represented by those for hybrid electric vehicles (HEVs), which are unlikely to be influenced by the deterioration of battery characteristics due to water, and a production process thereof are provided.The negative electrode material having at least one exothermic peak in the range of not lower than 650° C. and lower than 700° C., and at least one exothermic peak in the range of not lower than 700° C. and lower than 760° C., in differential thermal analysis measured under an air flow. The production process of the negative electrode material for non-aqueous electrolyte secondary batteries is characterized by carbonizing a negative electrode material precursor having an oxygen content of not less than 5% by weight and less than 10% by weight, under an inert gas flow at a rate of not more than 120 ml/g·h, under a pressure of normal pressure to 10 kPa, at a temperature higher than 1100° C. and lower than 1500° C.

    摘要翻译: 用于非水电解质二次电池的负极材料,其最适合用于混合电动车辆(HEV)的那些代表的大电流I / O非水电解质二次电池,其不太可能受电池劣化的影响 提供了水的特性及其制造方法。 所述负极材料具有不低于650℃且低于700℃的至少一个放热峰,并且至少一个放热峰在不低于700℃且低于760的范围内 °C,在气流下测量的差热分析。 非水电解质二次电池用负极材料的制造方法的特征在于,在惰性气体流动下,将含氧量不小于5重量%且小于10重量%的负极材料前体碳化 在高于1100℃和低于1500℃的温度下,在常压至10kPa的压力下,速度不超过120ml / g·h。

    POLYMER ELECTROLYTE AND NONAQUEOUS BATTERY CONTAINING THE SAME
    6.
    发明申请
    POLYMER ELECTROLYTE AND NONAQUEOUS BATTERY CONTAINING THE SAME 有权
    聚合物电解液和含有该电池的非电解电池

    公开(公告)号:US20120009482A1

    公开(公告)日:2012-01-12

    申请号:US13238250

    申请日:2011-09-21

    IPC分类号: H01M10/056

    摘要: A nonaqueous battery, such as a lithium ion battery, is formed from a polymer electrolyte comprising: a vinylidene fluoride copolymer comprises 90 to 97 wt. % of vinylidene fluoride monomer units and 3 to 10 wt. % of units of at least one monomer copolymerizable with the vinylidene fluoride monomer and has an inherent viscosity of 1.5 to 10 dl/g. The polymer electrolyte stably retains the nonaqueous electrolytic solution in a large amount and has excellent strength in this state.

    摘要翻译: 诸如锂离子电池的非水电池由聚合物电解质形成,包括:偏二氟乙烯共聚物,其包含90至97重量% %偏二氟乙烯单体单元和3至10wt。 至少一种可与偏二氟乙烯单体共聚的单体的单位百分比,其特性粘度为1.5-10dl / g。 高分子电解质在该状态下稳定地保持非水电解液,并具有优异的强度。

    Cathode material for lithium rechargeable batteries
    7.
    发明授权
    Cathode material for lithium rechargeable batteries 有权
    锂可充电电池的阴极材料

    公开(公告)号:US06855461B2

    公开(公告)日:2005-02-15

    申请号:US10073678

    申请日:2002-02-11

    摘要: A crystal which can be employed as the active material of a lithium-based battery has an empirical formula of Lix1A2Ni1-y-zCoyBzOa, wherein “x1” is greater than about 0.1 and equal to or less than about 1.3, “x2,” “y” and “z” each is greater than about 0.0 and equal to or less than about 0.2, “a” is greater than about 1.5 and less than about 2.1, “A” is at least one element selected from the group consisting of barium, magnesium, calcium and strontium and “B” is at least one element selected from the group consisting of boron, aluminum, gallium, manganese, titanium, vanadium and zirconium. A method includes combining lithium, nickel, cobalt and at least one element “A” selected from the group consisting of barium, magnesium, calcium and strontium, has at least one element “B” selected from the group consisting of boron, aluminum, gallium, manganese, titanium, vanadium and zirconium, in the presence of oxygen, wherein the combined components have the relative ratio of Lix1:Ax2:Ni1-y-z:Coy:Bz, wherein “x1,” “x2,” “y” and “z” have the values given for the empirical formula shown above.

    摘要翻译: 可以用作锂基电池的活性材料的晶体具有Lix1A2Ni1-y-zCoyBzOa的经验式,其中“x1”大于约0.1且等于或小于约1.3,“x2”,“ y“和”z“各自大于约0.0且等于或小于约0.2,”a“大于约1.5且小于约2.1,”A“是选自由以下组成的组中的至少一种元素:钡 ,镁,钙和锶,“B”是选自硼,铝,镓,锰,钛,钒和锆中的至少一种元素。 一种方法包括组合锂,镍,钴和至少一种选自钡,镁,钙和锶的元素“A”,具有至少一种选自硼,铝,镓的元素“B” ,锰,钛,钒和锆,其中组合成分具有Lix1:Ax2:Ni1-yz:Coy:Bz的相对比例,其中“x1”,“x2”,“y”和“ z“具有上述经验公式给出的值。

    Vinylidene fluoride polymer and process for production thereof
    8.
    发明授权
    Vinylidene fluoride polymer and process for production thereof 有权
    偏二氟乙烯聚合物及其生产方法

    公开(公告)号:US06686427B2

    公开(公告)日:2004-02-03

    申请号:US10054795

    申请日:2002-01-25

    IPC分类号: C08F1422

    摘要: A vinylidene fluoride polymer having good high-temperature coloring resistance is produced through suspension polymerization at 10-100° C. in a mixture solvent of 100 wt. parts of an aqueous medium and 10-50 wt. parts of a halogenated hydrocarbon solvent showing a good dissolving power to both a vinylidene fluoride monomer and a polymerization initiator and represented by a formula of: CX3CX2CHX2, wherein X is a fluorine or chlorine atom, and 7 X's include 4-6 fluorine atoms and 1-3 chlorine atoms. The vinylidene fluoride polymer is characterized by an elutable total organic carbon content in pure water at 95° C. of at most 1.1 &mgr;g/cm2.

    摘要翻译: 通过在100-100℃的混合溶剂中在10-100℃下悬浮聚合制备具有良好耐高温着色性的偏二氟乙烯聚合物。 水性介质的一部分和10-50wt。 部分卤代烃溶剂对偏二氟乙烯单体和聚合引发剂具有良好的溶解力,并由下式表示:其中X是氟或氯原子,7 X包括4-6个氟原子和1-3个 氯原子。 偏二氟乙烯聚合物的特征在于在95℃的纯水中可洗脱的总有机碳含量最多为1.1mug / cm 2。

    Pyroelectric infrared sensor with different sized effective light
receiving electrode areas and a method of manufacturing a dual
pyroelectric element used therein
    9.
    发明授权
    Pyroelectric infrared sensor with different sized effective light receiving electrode areas and a method of manufacturing a dual pyroelectric element used therein 失效
    具有不同尺寸的有效光接收电极区域的电子红外传感器和制造其使用的双电极元件的方法

    公开(公告)号:US5105084A

    公开(公告)日:1992-04-14

    申请号:US581255

    申请日:1990-09-11

    CPC分类号: G01J5/34 H01L37/02

    摘要: A pyroelectric infrared sensor includes a package having a light-receiving window, and at least two dual pyroelectric elements arranged in the package, each of the dual pyroelectric elements having first and second unit pyroelectric elements, the first and second unit pyroelectric elements being connected in series or parallel with each other so as to have opposite polarities, wherein the first and second light-receiving electrodes and the first and second back electrodes are formed such that an effective light-receiving electrode area of the first unit pyroelectric element opposing a central portion of the light-receiving window is smaller than an effective light-receiving electrode area of the second unit pyroelectric element opposing a peripheral portion of the light-receiving window. A difference between secondary infrared rays incident on the first and second unit pyroelectric elements which is caused by a difference between angles of visibility of these elements with respect to the light-receiving window can be compensated. This invention also relates to a method of manufacturing the dual pyroelectric element.

    Vinylidene fluoride copolymer-based polymer electrolyte for nonaqueous battery retaining large proportion of electrolytic solution
    10.
    发明授权
    Vinylidene fluoride copolymer-based polymer electrolyte for nonaqueous battery retaining large proportion of electrolytic solution 有权
    用于非水电池的偏二氟乙烯共聚物聚合物电解质保留了大量的电解液

    公开(公告)号:US08574770B2

    公开(公告)日:2013-11-05

    申请号:US13238250

    申请日:2011-09-21

    IPC分类号: H01M6/14

    摘要: A non-aqueous battery comprising a positive electrode material capable of being doped with and liberating lithium, a negative electrode material capable of being doped with and liberating lithium, and a polymer electrolyte disposed between the positive and negative electrode materials. The polymer electrolyte is formed by mixing a vinylidene fluoride copolymer and a nonaqueous electrolytic solution with a solvent, followed by evaporation of the solvent, so as to retain a high proportion of the nonaqueous electrolytic solution, leading to high electroconductivity and excellent strength in this state. The vinylidene fluoride copolymer comprises 80 to 97 wt. % of vinylidene fluoride monomer units and 3 to 20 wt. % of units of at least one monomer copolymerizable with vinylidene fluoride monomer, and has an inherent viscosity of 1.7 to 7 dl/g, as measured at 30° C. in a solution at a concentration of 4 g of polymer in 1 liter of N,N-dimethylformamide.

    摘要翻译: 包括能够掺杂并释放锂的正极材料的非水电池,能够掺杂和释放锂的负极材料,以及设置在正极和负极材料之间的聚合物电解质。 通过将偏二氟乙烯共聚物和非水电解液与溶剂混合,然后蒸发溶剂,以保持高比例的非水电解液形成聚合物电解质,导致高导电性和优异的强度 。 偏二氟乙烯共聚物包含80至97wt。 %偏二氟乙烯单体单元和3至20wt。 至少一种可与偏二氟乙烯单体共聚的单体的单位百分数,并且在30℃下在浓度为4g聚合物1升N的溶液中测定的特性粘度为1.7至7dl / g ,N-二甲基甲酰胺。