-
公开(公告)号:US06391463B1
公开(公告)日:2002-05-21
申请号:US08772980
申请日:1996-12-23
申请人: Mingxin Fan , Gary W. Ceska , James Horgan , Thomas Hazell
发明人: Mingxin Fan , Gary W. Ceska , James Horgan , Thomas Hazell
IPC分类号: C08F3008
CPC分类号: C08F30/08 , C07F7/081 , C07F7/12 , C07F7/1804 , C09D4/00 , Y10T428/31663 , C08F230/08
摘要: Compounds of the formula wherein R1=H, CH3 R2=H, CH3, CH2CH3, or CH2CH2CH3 n=1-10 X=halogen, (C1-C6) alkyl, (C1-C6) alkoxy, or aromatic radical are shown to be useful as coupling agents or adhesion promotors in free radically curable compositions such as UV curable and peroxide curable (meth)acrylate based coating compositions. The associated methods, curable compositions, coatings, adhesives and coated articles are also disclosed.
摘要翻译: 化合物R1 = H,CH3R2 = H,CH3,CH2CH3或CH2CH2CH3n = 1-10X =卤素,(C1-C6)烷基,(C1-C6)烷氧基或芳族基团可用作偶联剂或 可自由基固化组合物中的粘合促进剂,例如UV可固化和可过氧化物固化的(甲基)丙烯酸酯基涂料组合物。 还公开了相关方法,可固化组合物,涂料,粘合剂和涂覆制品。
-
2.
公开(公告)号:US06124483A
公开(公告)日:2000-09-26
申请号:US773524
申请日:1996-12-23
申请人: Mingxin Fan , Gary W. Ceska , James Horgan
发明人: Mingxin Fan , Gary W. Ceska , James Horgan
IPC分类号: B01J31/24 , B01J31/34 , C07D301/12 , C07D303/16 , C07D303/24 , C07D303/40 , C08F20/32 , C08G59/24
CPC分类号: C07D303/40 , C07D301/12 , C07D303/16 , C07D303/24 , C08G59/24
摘要: Process of making compounds of the formula ##STR1## wherein R.sub.1 =(C.sub.1 -C.sub.6) alkyl;X=O, S, NH;R.sub.2 =divalent saturated organic group;Y=O, S, NH, ester;R.sub.3 =cyclic moiety containing oxirane group;comprising reacting a compound of the formula ##STR2## wherein R.sub.4 is a cyclic moiety containing C.dbd.C group with hydrogen peroxide in the presence of (a) tungstic acid, (b) phosphoric acid or its metal salts, and (c) at least one phase transfer catalyst;polymers of compounds of formula I; andcompounds of formula I except for compounds wherein R.sub.4 is a dicyclopentenyl epoxide, Y is O, R.sub.2 is --CH.sub.2 CH.sub.2 --, X is O, and R.sub.1 is H or methyl.
摘要翻译: 制备下式化合物的方法其中R1 =(C1-C6)烷基; X = O,S,NH; R2 =二价饱和有机基团; Y = O,S,NH,酯; R3 =含环氧乙烷基团的环状部分; 包括在(a)钨酸,(b)磷酸或其金属盐存在下使下式化合物其中R 4是含有C = C基团的环状部分与过氧化氢反应,和(c)至少一种相转移 催化剂; 式I化合物的聚合物; 和式I化合物,除了其中R 4是二环戊烯基环氧化物,Y是O,R 2是-CH 2 CH 2 - ,X是O,R 1是H或甲基的化合物。
-
3.
公开(公告)号:US06242506B1
公开(公告)日:2001-06-05
申请号:US09120508
申请日:1998-07-22
申请人: Mingxin Fan , Gary W. Ceska , James Horgan
发明人: Mingxin Fan , Gary W. Ceska , James Horgan
IPC分类号: C08G1867
CPC分类号: C08G18/672 , C08G18/42 , C08G18/48
摘要: Radiation curable acrylic compositions are improved with regard to flame resistance by incorporating a reactive compound which is the reaction product of tetrabromophthalic anhydride or acid and a (meth)acrylic compound.
摘要翻译: 通过加入作为四溴邻苯二甲酸酐或酸与(甲基)丙烯酸类化合物的反应产物的反应性化合物,可辐射固化丙烯酸组合物在阻燃性方面得到改善。
-
公开(公告)号:US5900472A
公开(公告)日:1999-05-04
申请号:US772432
申请日:1996-12-23
申请人: Mingxin Fan , Gary W. Ceska , James Horgan
发明人: Mingxin Fan , Gary W. Ceska , James Horgan
IPC分类号: C07C67/08 , C07C69/76 , C07C69/94 , C07C323/62 , C08F2/50 , C08F22/10 , C08F220/30 , C08G6/00 , C08G10/00 , C08G14/00
CPC分类号: C08F22/105 , C07C69/76 , Y10T428/31627 , Y10T428/31649
摘要: Copolymerizable benzophenone photoinitiators of the formula I ##STR1## wherein 1, k=0, 1, 2.R.sub.1 =divalent organic group having 1 to 25 carbon atoms;R.sub.2 =H or methyl; andR.sub.3, R.sub.4 =organic group having 1 to 25 carbon atoms.X, Y=hydrogen, halogen or (C.sub.1 -C.sub.25) groups containing N, S, and/or O;and method of making the photoinitiators.The photoinitiators overcome the leaching problem with prior photoinitiators in radiation curable polymer applications. Radiation curable polymers, cured polymers, and coated articles are also disclosed.
摘要翻译: 式I的可共聚二苯甲酮光引发剂,其中1,k = 0,1,2。R1 =具有1至25个碳原子的二价有机基团; R2 = H或甲基; R3,R4 =碳原子数为1〜25的有机基团。 X,Y =氢,卤素或含有N,S和/或O的(C1-C25)基团; 以及制备光引发剂的方法。 光引发剂克服了可辐射固化聚合物应用中先前光引发剂的浸出问题。 还公开了可辐射固化聚合物,固化聚合物和涂覆制品。
-
公开(公告)号:US5789512A
公开(公告)日:1998-08-04
申请号:US772313
申请日:1996-12-23
申请人: Mingxin Fan , Gary W. Ceska , James Horgan
发明人: Mingxin Fan , Gary W. Ceska , James Horgan
CPC分类号: C08C19/06
摘要: A process for epoxidizing unsaturated polymers comprising reacting an unsaturated polymer with hydrogen peroxide in the presence of (a) tungstic acid or its metal salts, (b) phosphoric acid or its metal salts, and (c) at least one phase transfer catalyst.
摘要翻译: 环氧化不饱和聚合物的方法,包括在(a)钨酸或其金属盐,(b)磷酸或其金属盐存在下使不饱和聚合物与过氧化氢反应,和(c)至少一种相转移催化剂。
-
6.
公开(公告)号:US07569641B2
公开(公告)日:2009-08-04
申请号:US11035357
申请日:2005-01-12
申请人: Mingxin Fan , Jeffrey Allan Klang , Gary W. Ceska , James Horgan
发明人: Mingxin Fan , Jeffrey Allan Klang , Gary W. Ceska , James Horgan
CPC分类号: C08C19/38 , B33Y70/00 , C08G18/69 , C08L15/00 , C08L19/006
摘要: A composition comprising a polymer according to Structure 1 wherein R is H, Me, Et or C6H5; R′ is H or Me; n is a number from 1 to 100; and Z is a number from 1 to 3; f is a number from 1 to 5, with f=1 if B is nothing; A is residue of a hydrogenated polybutadiene backbone; and B nothing or it is a difunctional organic linking group is disclosed. The composition can be cured and used in a wide range of articles such as a photopolymer printing plate, sealant, caulk, encapsulent, road marking paint, photoresist, binder, impact modifier, polymer modifier, oxygen or water vapor barrier coating, conformal coating, solder mask, pigment dispersion, stereolithograph, laminating resin, grafted co-polymer, composite, optical fiber coating, paper coating, metal coating, glass coating, plastic coating, wood coating, waterproofing material, electrical insulating material, automotive belt or hose, tire, engine mount, gasket, golf ball core, and rubber roll.
摘要翻译: 一种组合物,其包含根据结构1的聚合物,其中R是H,Me,Et或C 6 H 5; R'是H或Me; n是1至100的数字; Z为1〜3的数; f是从1到5的数字,如果B没有,f = 1; A是氢化聚丁二烯骨架的残基; 和B无关,或者是双官能的有机连接基。 该组合物可以固化并用于宽范围的制品中,例如光聚合物印刷版,密封剂,填缝料,密封剂,道路标线漆,光致抗蚀剂,粘合剂,抗冲改性剂,聚合物改性剂,氧气或水蒸气阻隔涂料,保形涂层, 焊料掩模,颜料分散体,立体光刻胶,层压树脂,接枝共聚物,复合材料,光纤涂层,纸张涂层,金属涂层,玻璃涂层,塑料涂层,木器涂料,防水材料,电绝缘材料,汽车皮带或软管,轮胎 发动机支架,垫片,高尔夫球芯和橡胶辊。
-
公开(公告)号:US5767150A
公开(公告)日:1998-06-16
申请号:US831677
申请日:1997-04-10
申请人: Mingxin Fan , Gary W. Ceska , James Horgan , Henri Strub
发明人: Mingxin Fan , Gary W. Ceska , James Horgan , Henri Strub
IPC分类号: C07D301/12 , C07D303/16 , C07D303/40 , C08G59/24 , C08G59/32 , A61K31/335 , C07D303/00
CPC分类号: C08G59/24 , C07D301/12 , C07D303/16 , C07D303/40 , C08G59/3218
摘要: Compounds having the formula ##STR1## wherein X is selected from O, (CH.sub.2).sub.m O, S, (CH.sub.2).sub.m S, NH, (CH.sub.2).sub.m NH, COO.sup.-, (CH.sub.2).sub.m COO.sup.-, .sup.- OOC and .sup.- OOC (CH.sub.2).sub.m ; m is 1 to 6; n is 1 to 100; R.sub.1 is (C.sub.1 -C.sub.20) ester; and A is a saturated organic linking group selected from residues of polyol, polythiol, polyamine, and polyacid, are prepared by reacting compounds according to formula II ##STR2## with hydrogen peroxide in the presence of (a) tungstic acid or its metal salts, (b) phosphoric acid or its metal salts, and (c) at least one phase transfer catalyst.
摘要翻译: 具有式(I)的化合物其中X选自O,(CH 2)m O,S,(CH 2)m S,NH,(CH 2)m NH,COO-,(CH 2)m COO-, - OOC和 -OOC(CH 2)m; m为1〜6; n为1〜100; R1是(C1-C20)酯; 并且A是选自多元醇,多硫醇,多胺和多元酸的残基的饱和有机连接基团,其通过使式II(II)的化合物与(a)钨酸或其 金属盐,(b)磷酸或其金属盐,和(c)至少一种相转移催化剂。
-
公开(公告)号:US06559260B1
公开(公告)日:2003-05-06
申请号:US09535176
申请日:2000-03-27
申请人: Mingxin Fan , Gary W. Ceska , James Horgan
发明人: Mingxin Fan , Gary W. Ceska , James Horgan
IPC分类号: C08L7516
CPC分类号: C09D175/16 , C08G18/6715
摘要: The present invention is for a new class of allyl urethane resin which can be cured with peroxide at high temperature alone or in combination with some accelerators. These allyl urethane resins can be sued alone or in combination with other free radically polymerizable materials such as allyl monomers and ligomers or (meth)acrylate monomers and oligomers. These new allyl urethane resins contain at least two allyl functional groups.
摘要翻译: 本发明是一种新的烯丙基聚氨酯树脂,其可以单独或与一些加速剂组合使用,可以在高温下用过氧化物固化。 这些烯丙基聚氨酯树脂可以单独或与其它可自由基聚合的材料如烯丙基单体和连接体或(甲基)丙烯酸酯单体和低聚物组合起来。 这些新的烯丙基聚氨酯树脂含有至少两个烯丙基官能团。
-
公开(公告)号:US6084111A
公开(公告)日:2000-07-04
申请号:US62593
申请日:1998-04-17
申请人: Mingxin Fan , Gary W. Ceska , James Horgan , Henri Strub
发明人: Mingxin Fan , Gary W. Ceska , James Horgan , Henri Strub
IPC分类号: C07D301/12 , C07D303/16 , C07D303/40 , C08G59/24 , C08G59/32 , C07D303/00
CPC分类号: C08G59/24 , C07D301/12 , C07D303/16 , C07D303/40 , C08G59/3218
摘要: Compounds having the formula ##STR1## wherein X is selected from O, (CH.sub.2).sub.m O, S, (CH.sub.2).sub.m S, NH, (CH.sub.2).sub.m NH, COO.sup.-, (CH.sub.2).sub.m COO.sup.-, .sup.- OOC and .sup.- OOC (CH.sub.2).sub.m ;m is 1 to 6;n is 1 to 100;R.sub.1 is selected from H, (C.sub.1 -C.sub.20) alkyl, (C.sub.1 -C.sub.20) alkoxy and (C.sub.1 -C.sub.20) ester; andA is a saturated organic linking group selected from residues of polyol, polythiol, polyamine, and polyacid, are prepared by reacting compounds according to formula II ##STR2## with hydrogen peroxide in the presence of (a) tungstic acid or its metal salts, (b) phosphoric acid or its metal salts, and (c) at least one phase transfer catalyst.
摘要翻译: 具有下式的化合物其中X选自O,(CH 2)m O,S,(CH 2)m S,NH,(CH 2)m NH,COO-,(CH 2)m COO-, - OOC和-OOC(CH 2)m; m为1〜6; n为1〜100; R1选自H,(C1-C20)烷基,(C1-C20)烷氧基和(C1-C20)酯; (a)钨酸或其金属盐的存在下,通过使根据式II的化合物与过氧化氢反应制备A是选自多元醇,多硫醇,多胺和多元酸的残基的饱和有机连接基团,(b) 磷酸或其金属盐,以及(c)至少一种相转移催化剂。
-
公开(公告)号:US5763629A
公开(公告)日:1998-06-09
申请号:US772979
申请日:1996-12-23
申请人: Mingxin Fan , Gary W. Ceska , James Horgan , Thomas W. Hazell
发明人: Mingxin Fan , Gary W. Ceska , James Horgan , Thomas W. Hazell
IPC分类号: C07D303/16 , C08F20/32 , C08G65/14 , C08L71/02 , C07D301/12
CPC分类号: C08G65/14 , C07D303/16 , C08F20/32 , C08L71/02
摘要: Compounds of the formula ##STR1## wherein R.sub.1 32 H, CH.sub.3 ; R.sub.2 =H, (C.sub.1 -C.sub.6)alkyl; and x=1-20; and process for preparing such compounds by reacting a compound of the formula ##STR2## with hydrogen peroxide in the presence of (a) tungstic acid or its metal salts, (b) phosphoric acid or its metal salts, and (c) at least one phase transfer catalyst.
摘要翻译: 式(I)的化合物其中R 13 2 H,CH 3; R2 = H,(C1-C6)烷基; 和x = 1-20; 和(a)钨酸或其金属盐,(b)磷酸或其金属盐的存在下,使式(II)化合物与过氧化氢反应制备此类化合物的方法,和(c) 至少一种相转移催化剂。
-
-
-
-
-
-
-
-
-