公开(公告)号：US4904575A

公开(公告)日：1990-02-27

申请号：US216573

申请日：1988-07-08

申请人： Michio Ono ,  Minoru Sakai ,  Kozo Aoki

发明人： Michio Ono ,  Minoru Sakai ,  Kozo Aoki

IPC分类号： C07D209/34 ,  C07D263/56 ,  C07D263/57 ,  C07D498/04 ,  G03C7/34

CPC分类号： C07D263/56 ,  C07D209/34 ,  C07D263/57 ,  G03C7/342

摘要： A silver halide color photographic material comprising a support having coated thereon at least one silver halide emulsion layer, the silver halide color photographic material containing a photographic cyan dye forming coupler represented by the following general formula (I): ##STR1## wherein R.sub.1 represents an aliphatic group, an aromatic group, heterocyclic group or a substituted amino group; R.sub.2 and R.sub.3, which may be the same or different, each represents an aliphatic group, an aromatic group or a heterocyclic group, or R.sub.2 and R.sub.3 may combine with each other to form a ring; and X represents a group capable of beiing released upon an oxidative coupling with a developing agent (including a hydrogen atom).The photographic cyan dye forming coupler has a high color forming rate and provides a high maximum color density even when a color developing solution which does not contain benzyl alcohol is used, and exhibits substantially no reduction in color density in the case of processing in a bleaching solution having a weak oxidation power or an exhausted bleaching solution.The silver halide color photographic material containing the photographic cyan dye forming coupler can provide color images having excellent fastness and color reproducibility and less stain in white background area.

摘要翻译： 一种卤化银彩色照相材料，其包含在其上涂覆有至少一个卤化银乳剂层的载体，所述卤化银彩色照相材料含有由以下通式（I）表示的照相青色染料形成成色剂：其中 R1表示脂族基，芳基，杂环基或取代氨基; R 2和R 3可以相同或不同，各自表示脂族基团，芳族基团或杂环基团，或者R 2和R 3可以彼此结合形成环; X表示与显影剂（包括氢原子）氧化偶合时能够释放的基团。 感光青色染料成色剂具有高的成色速率，并且即使使用不含苄醇的显色溶液也能提供高的最大色密度，并且在漂白处理的情况下基本上不会降低色浓度 溶液具有弱氧化能力或耗尽的漂白溶液。 含有照相青色染料形成成色剂的卤化银彩色照相材料可以提供在白色背景区域中具有优异的牢度和颜色再现性以及较少污渍的彩色图像。

公开(公告)号：US4564586A

公开(公告)日：1986-01-14

申请号：US696610

申请日：1985-01-30

申请人： Kozo Aoki ,  Michio Ono ,  Kiyoshi Nakazyo

发明人： Kozo Aoki ,  Michio Ono ,  Kiyoshi Nakazyo

IPC分类号： C07D215/22 ,  C07D215/227 ,  C07D215/38 ,  C09B53/00 ,  G03C7/34 ,  G03C7/26

CPC分类号： C07D215/227 ,  C07D215/38 ,  G03C7/34

摘要： A silver halide color photographic light-sensitive material comprising a support having coated thereon at least one silver halide emulsion layer, wherein the silver halide color photographic light-sensitive material contains a cyan dye forming coupler represented by the following general formula (I): ##STR1## wherein R.sub.1 represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic group; R.sub.2, R.sub.3, R.sub.4 and R.sub.5, which may be the same or different, each represents a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted aryloxy group, a substituted or unsubstituted alkylthio group, a substituted or unsubstituted arylthio group, a substituted or unsubstituted acylamino group, a substituted or unsubstituted sulfonamido group, a substituted or unsubstituted alkoxycarbonyl group, a substituted or unsubstituted arylcarbonyl group, a substituted or unsubstituted carbonyl group or a nitrile group, or R.sub.2 and R.sub.3 or R.sub.4 and R.sub.5 may together represent an alkylidene group, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 may combine each other to form a ring, three or more of R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are not hydrogen atom at the same time and when two of R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are hydrogen atoms at the same time, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 combine each other to form a ring or R.sub.2 and R.sub.3 or R.sub.4 and R.sub.5 are hydrogen atoms; X represents a hydrogen atom or a group capable of being released upon an oxidative coupling with a developing agent; and n represents 0 or 1.The cyan dye forming coupler can provide a cyan color image having excellent fastness to light and heat and have good solubility in an organic solvent having a high boiling point.

摘要翻译： 一种卤化银彩色照相感光材料，其包含涂覆有至少一个卤化银乳剂层的载体，其中所述卤化银彩色照相感光材料含有由以下通式（I）表示的形成青色染料的成色剂： （I）其中R1表示取代或未取代的烷基，取代或未取代的芳基或取代或未取代的杂环基; R 2，R 3，R 4和R 5可以相同或不同，各自表示氢原子，卤素原子，取代或未取代的烷基，取代或未取代的烯基，取代或未取代的芳基，取代或未取代的芳基， 未取代的烷氧基，取代或未取代的芳氧基，取代或未取代的烷硫基，取代或未取代的芳硫基，取代或未取代的酰氨基，取代或未取代的亚磺酰氨基，取代或未取代的烷氧基羰基，取代或未取代的 芳基羰基，取代或未取代的羰基或腈水泥浆，或R 2和R 3或R 4和R 5可以一起代表亚烷基，R 2，R 3，R 4和R 5可以相互结合形成环，R 3 R 3，R 4和R 5同时不是氢原子，当R2，R3，R4和R5中的两个同时为氢原子时，R2，R3，R4和R5相互结合 形成环或R 2，R 3或R 4和R 5为氢原子; X表示氢原子或与显影剂氧化偶联时能够释放的基团; 并且n表示0或1.青色染料形成成色剂可以提供具有优异的耐光性和耐热性的青色图像，并且在具有高沸点的有机溶剂中具有良好的溶解性。

公开(公告)号：US4892810A

公开(公告)日：1990-01-09

申请号：US136518

申请日：1987-12-22

申请人： Kozo Aoki ,  Michio Ono ,  Naoki Saito

发明人： Kozo Aoki ,  Michio Ono ,  Naoki Saito

IPC分类号： G03C7/34

CPC分类号： G03C7/346

摘要： A silver halide color photographic light-sensitive material is described, the light-sensitive material containing a cyan dye forming coupler represented by the following general formula (I): ##STR1## wherein R.sub.1 represents an alkyl group having 2 to 15 carbon atoms, R.sub.2 and R.sub.3 represent each a hydrogen atom or an alkyl group, R.sub.4 represents a substituted aryl group which is substituted by a group other than an aryl group or an aralkyl group, X represents a hydrogen atom, a halogen atom, an alkyl group or an alkoxy group, Z represents a hydrogen atom or a group capable of release by an oxidation coupling reaction with the developing agent, n represents an integer of 1 to 4, and the total number of carbon atoms in the alkyl groups contained in R.sub.1, R.sub.2, R.sub.3, R.sub.4, X and Z is 8 or more, and the total number of carbon atoms in the alkyl groups substituted in R.sub.1 and R.sub.4, in the case that n is 1, is 11 or less.

摘要翻译： 描述了一种卤化银彩色照相感光材料，该感光材料包含由以下通式（I）表示的形成青色染料的成色剂：其中R 1表示具有2至15个碳原子的烷基 原子，R 2和R 3各自表示氢原子或烷基，R 4表示被芳基或芳烷基以外的基团取代的取代芳基，X表示氢原子，卤素原子，烷基 或烷氧基，Z表示氢原子或能够通过与显影剂的氧化偶联反应释放的基团，n表示1〜4的整数，R1中所含的烷基中的碳原子总数， R2，R3，R4，X和Z为8以上，在n为1的情况下，在R1和R4中取代的烷基中的碳原子总数为11以下。

公开(公告)号：US4746602A

公开(公告)日：1988-05-24

申请号：US44270

申请日：1987-04-30

申请人： Michio Ono ,  Kozo Aoki

发明人： Michio Ono ,  Kozo Aoki

IPC分类号： C07D223/16 ,  C07D243/12 ,  G03C7/34

CPC分类号： C07D223/16 ,  C07D243/12 ,  G03C7/34

摘要： A silver halide color photographic material is disclosed, comprising a support having provided thereon at least one silver halide emulsion layer containing a cyan-dye-forming coupler represented by formula (I) ##STR1## wherein Y represents an atomic group forming an at least 7-membered nitrogen-containing heterocyclic ring containing at least one--NHCO-- group; Z represents a hydrogen atom or a group releasable upon coupling with an oxidation product of a color developing agent; R represents an aliphatic group, an aromatic group, a heterocyclic group, or a substituted amino group, or any of R, Z and Y form a dimer or higher polymer.The material forms a dye image excellent in fastness and color reproducibility, and free from white background stains.

摘要翻译： 公开了一种卤化银彩色照相材料，其包括其上提供有至少一个含有由式（I）表示的形成青色染料的成色剂的卤化银乳剂层的载体，其中Y表示形成 至少含有至少一个NHCO-的7元含氮杂环; Z表示氢原子或与彩色显影剂的氧化产物偶联时可释放的基团; R表示脂肪族基团，芳香族基团，杂环基团或取代氨基，或者R，Z和Y中的任一种形成二聚体或更高级的聚合物。 该材料形成了色牢度和色彩再现性优异的染色图像，并且没有白色背景污渍。

公开(公告)号：US4686177A

公开(公告)日：1987-08-11

申请号：US760852

申请日：1985-07-31

申请人： Kozo Aoki ,  Michio Ono ,  Naoki Saito ,  Makoto Umemoto

发明人： Kozo Aoki ,  Michio Ono ,  Naoki Saito ,  Makoto Umemoto

IPC分类号： G03C7/34 ,  G03C1/40

CPC分类号： G03C7/346

摘要： A silver halide color photographic material having excellent color fastness against light, heat and heat with humidity, particularly against light irradiation, containing a cyan coupler of the general formula (I): ##STR1## wherein R represents an unsubstituted linear or branched aliphatic group or a linear or branched aliphatic group substituted with one or more substituents selected from a chlorine atom, an alkoxy group, an alkylthio group, an arylthio group, an alkylsulfonyl group, an arylsulfonyl group, a sulfonamido group, an acylamino group, an alkyloxycarbonyl group, an aryloxycarbonyl group, a carbamoyl group, an alkylcarbonyloxy group, an arylcarbonyloxy group, a carboxyl group and a hydroxyl group; R.sub.1 represents an unsubstituted or substituted linear or branched alkyl group having 2 to 15 carbon atoms; X is a hydrogen atom, a halogen atom, an alkyl group, an an alkoxy group or an acylamino group; Z is a hydrogen atom or a residue which may be removed in an oxidation coupling reaction with a developing agent; and said R may optionally form a dimeric or higher polymeric structure.

摘要翻译： 一种卤化银彩色照相材料，其特征在于，含有具有通式（I）的青色成色剂的光，​​热和热，特别是耐光照的耐光色牢度：其中R表示未取代的直链或支链 脂族基团或被一个或多个选自氯原子，烷氧基，烷硫基，芳硫基，烷基磺酰基，芳基磺酰基，亚磺酰氨基，酰氨基， 烷氧基羰基，芳氧基羰基，氨基甲酰基，烷基羰基氧基，芳基羰基氧基，羧基和羟基; R1表示未取代或取代的具有2至15个碳原子的直链或支链烷基; X是氢原子，卤素原子，烷基，烷氧基或酰氨基; Z是氢原子或可在与显影剂的氧化偶合反应中除去的残基; 并且所述R可任选地形成二聚或更高级聚合物结构。

公开(公告)号：US5260177A

公开(公告)日：1993-11-09

申请号：US884897

申请日：1992-05-18

申请人： Kozo Aoki ,  Michio Ono ,  Katsuyoshi Yamakawa ,  Shigeru Yamazaki ,  Kei Sakanoue ,  Hidetoshi Kobayashi

发明人： Kozo Aoki ,  Michio Ono ,  Katsuyoshi Yamakawa ,  Shigeru Yamazaki ,  Kei Sakanoue ,  Hidetoshi Kobayashi

IPC分类号： C07D213/75 ,  C07D213/76 ,  C07D471/04 ,  G03C7/38 ,  G03C7/388

CPC分类号： C07D213/75 ,  C07D213/76 ,  C07D471/04 ,  G03C7/3815

摘要： A silver halide color photographic light-sensitive material comprises a novel cyan dye-forming coupler or a combination of a specific cyan dye-forming coupler with an .alpha.-pivaloylacetoanilide type yellow dye-forming coupler or a pyrazoloazole type magenta dye-forming coupler, the specific cyan dye-forming coupler being contained in the silver halide emulsion layer in the form of an emulsion of lipophilic fine particles obtained by mixing the coupler with at least one water-insoluble and organic solvent-soluble homo- or co-polymer to form a dispersion. The silver halide color photographic light-sensitive material is excellent in the reproduction of yellow, magenta and cyan colors and has low fog of cyan. Thus, the light-sensitive material can provide color images excellent in the fastness of the cyan color images.The cyan dye-forming coupler is represented by general formula (II): ##STR1## wherein R.sub.1 represents an aliphatic group, an aromatic group or a heterocyclic group; R.sub.2 represents a group or atom which can be bonded with the heterocyclic ring; X represents a hydrogen atom or a group which can be eliminated; Y represents a divalent bonding group having at least one amido bond and/or ester bond; Z represents a dissociative group; A, B, C, D and E each represents a nitrogen atom or a carbon atom a which hydrogen atom is bonded, provided that one or two of them represent a nitrogen atom; and n represents 0, 1 or 2.

摘要翻译： 卤化银彩色照相感光材料包括新型的青色染料形成成色剂或特定的形成青色染料的成色剂与α-对甲酰基乙酰苯胺型黄色染料形成成色剂或吡唑并唑型品红色染料形成成色剂的组合， 通过将成色剂与至少一种水不溶性和有机溶剂可溶性均聚物或共聚物混合而形成的亲脂性细颗粒乳液形式的卤化银乳剂层中所含有特定的青色成色剂， 分散。 卤化银彩色摄影感光材料在黄色，品红色和青色的再现方面是优异的，并且具有低的青色雾。 因此，感光材料可以提供在青色图像的牢度方面优异的彩色图像。 青色染料成色剂由通式（II）表示：其中R 1表示脂族基团，芳族基团或杂环基团; R2表示可以与杂环结合的基团或原子; X表示氢原子或可被除去的基团; Y表示具有至少一个酰胺键和/或酯键的二价键合基​​团; Z表示离解基团; A，B，C，D和E各自表示氮原子或氢原子键合的碳原子a，条件是它们中的一个或两个表示氮原子; n表示0,1或2。

公开(公告)号：US4430423A

公开(公告)日：1984-02-07

申请号：US451229

申请日：1982-12-20

申请人： Kozo Aoki ,  Michio Ono

发明人： Kozo Aoki ,  Michio Ono

IPC分类号： C07D209/34 ,  C07D235/26 ,  C07D239/80 ,  C07D241/44 ,  C07D265/18 ,  C07D265/36 ,  C09B53/00 ,  G03C7/34 ,  G03C7/16 ,  G03C7/26

CPC分类号： C07D265/36 ,  C07D235/26 ,  C07D239/80 ,  G03C7/34

摘要： A color photographic light-sensitive material comprising a cupport having coated thereon at least one silver halide emulsion layer. The color photographic light-sensitive material contains a cyan dye forming coupler represented by the following general formula (I): ##STR1## wherein Z represents ##STR2## R represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted heterocyclic group; X represents a hydrogen atom or a group capable of being released upon an oxidative coupling reaction with a developing agent; Y represents ##STR3## --O-- or --S--; R.sup.1 and R.sup.2, which may be the same or different, each represents a halogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, a substituted or unsubstituted alkoxycarbonyl group, a substituted or unsubstituted alkylcarbonyl group, a substituted or unsubstituted arylcarbonyl group, a substituted or unsubstituted carbonyl group, a substituted or unsubstituted acylamino group or a nitryl group or R.sup.1 and R.sup.2 together represents an oxo group; and R.sup.3 represents a hydrogen atom, a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group.The color photographic light-sensitive material provides a cyan color image having preferred spectral absorption characteristics for color reproduction and excellent fastness to light and heat. Furthermore, a decrease in optical density of the cyan color image is not substantially observed even when the color photographic light-sensitive material is processed with a bleaching solution which has a weak oxidation power or a bleaching solution which is exhausted.

摘要翻译： 一种彩色摄影感光材料，其包括在其上涂覆有至少一个卤化银乳剂层的杯口。 彩色摄影感光材料包含由以下通式（I）表示的青色染料形成成色剂：其中Z表示R表示取代或未取代的烷基，取代或未取代的芳基 或取代或未取代的杂环基; X表示氢原子或与显影剂进行氧化偶联反应时能够释放的基团; Y表示-O-或-S-; R 1和R 2可以相同或不同，各自表示卤素原子，取代或未取代的烷基，取代或未取代的芳基，取代或未取代的烷氧基，取代或未取代的烷氧基羰基，取代或未取代的 取代或未取代的芳基羰基，取代或未取代的羰基，取代或未取代的酰氨基或硝基，或者R 1和R 2一起表示氧代基; 并且R 3表示氢原子，取代或未取代的烷基或取代或未取代的芳基。 彩色照相感光材料提供具有优异的色彩再现特性和对光和热的优异耐光性的青色图像。 此外，即使当用具有弱氧化功能的漂白溶液或耗尽的漂白溶液处理彩色照相感光材料时，也基本上不观察到青色图像的光密度的降低。

公开(公告)号：US4587210A

公开(公告)日：1986-05-06

申请号：US595195

申请日：1984-03-30

申请人： Michio Ono ,  Masakazu Morigaki ,  Takayoshi Kamio ,  Kozo Aoki ,  Kazuhiko Furuya

发明人： Michio Ono ,  Masakazu Morigaki ,  Takayoshi Kamio ,  Kozo Aoki ,  Kazuhiko Furuya

IPC分类号： G03C7/26 ,  G03C7/392 ,  G03C1/08 ,  G03C7/32

CPC分类号： G03C7/39216

摘要： A color photographic silver halide light-sensitive material is described, characterized by containing at least one of the compounds represented by the general formula (I) and their precursors. ##STR1## wherein R represents ##STR2## (wherein R.sub.1 and R.sub.2 are each a hydrogen atom or an alkyl group and may combine with R.sub.3 to form a ring having 5 to 10 carbon atoms, provided that R.sub.1 and R.sub.2 are not hydrogen atoms at the same time, R.sub.3 is a substituted or unsubstituted aryl group, and n is an integer of 1 to 4), and R' has 1 to 20 carbon atoms and represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, or a substituent defined by R as defined above). This light-sensitive material provides color images which are stabilized, i.e., freed of fading and the discoloration of the white ground.

摘要翻译： 描述了彩色照相卤化银感光材料，其特征在于含有至少一种由通式（I）表示的化合物及其前体。 式（I）其中R表示（其中R 1和R 2各自为氢原子或烷基，并且可以与R 3结合形成具有5至10个碳原子的环，条件是R 1和R 2不为 氢原子，R3为取代或未取代的芳基，n为1〜4的整数），R'为碳原子数1〜20，表示取代或未取代的烷基，取代或未取代的环烷基 基团，取代或未取代的芳基或由如上定义的R定义的取代基）。 该感光材料提供稳定的彩色图像，即，消除白色地面的褪色和变色。

公开(公告)号：US06811728B2

公开(公告)日：2004-11-02

申请号：US10374906

申请日：2003-02-24

申请人： Shougo Yagi ,  Tadayuki Imai ,  Michio Ono ,  Hiroki Yamazaki ,  Haruki Kozawaguchi

发明人： Shougo Yagi ,  Tadayuki Imai ,  Michio Ono ,  Hiroki Yamazaki ,  Haruki Kozawaguchi

IPC分类号： B29D1100

CPC分类号： G11B7/0065 ,  G03H2001/2226 ,  G03H2001/2615 ,  G11B7/24

摘要： An inexpensive multi-layered holographic read-only memory having a large capacity is provided. In the memory in which single-mode slab waveguides are multi-layered, a periodic scattering center whose period approximately agrees with the period of the guided mode is provided in at least one of a core layer and a clad layer in each waveguide so that a guided wave in the waveguide is diffracted by the periodic scattering center to the outside of the waveguide and a holographic image is generated.

摘要翻译： 提供了一种具有大容量的便宜的多层全息只读存储器。 在单模平板波导为多层的存储器中，在每个波导管中的芯层和覆层中的至少一个中提供周期大约与引导周期大致相同的周期性散射中心，使得 波导中的导波被周期性散射中心衍射到波导的外部，并且产生全息图像。

公开(公告)号：US6121182A

公开(公告)日：2000-09-19

申请号：US981545

申请日：1997-12-11

申请人： Yoshikuni Okumura ,  Tsutomu Sakuragi ,  Michio Ono ,  Shintaro Inazawa

发明人： Yoshikuni Okumura ,  Tsutomu Sakuragi ,  Michio Ono ,  Shintaro Inazawa

IPC分类号： C08F4/64 ,  C08F4/642 ,  C08F4/659 ,  C08F4/6592 ,  C08F10/00 ,  C08F110/06 ,  B01J31/16

CPC分类号： C08F10/00 ,  C08F110/06 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65927 ,  Y10S526/943

摘要： A catalyst component for polyolefin production catalysts comprising a metallocene compound represented by general formula (1) (symbols have the meanings as described in the specification), polyolefin production catalyst containing the component, and method for producing polyolefin with the catalyst are provided. Use of a catalyst containing the novel metallocene compound as a catalyst component of the invention in polymerization of .alpha.-olefin, particularly propylene, enables one to prepare high rigid, high melting point isotactic polypropylene useful as an industrial material for automobiles and the like, more specifically isotactic polypropylene having highly controlled stereoregulartity and regioregularity, particularly the one having a high regioregularity that has been difficult to achieve with conventional metallocene catalysts. ##STR1##

摘要翻译： PCT No.PCT / JP97 / 01387 Sec。 371 1997年12月11日第 102（e）日期1997年12月11日PCT 1997年4月22日提交PCT公布。 公开号WO97 / 40075 PCT 日期：1997年10月30日一种用于聚烯烃生产催化剂的催化剂组分，其包含由通式（1）表示的茂金属化合物（符号具有说明书中所述的含义），含有该组分的聚烯烃生产催化剂，以及使用催化剂制备聚烯烃的方法 被提供。 使用含有新型茂金属化合物的催化剂作为本发明的催化剂组分在α-烯烃，特别是丙烯的聚合中，使得能够制备用作汽车等的工业材料的高刚性，高熔点全同立构聚丙烯，更多 特别是具有高度控制的立体结构和区域均匀性的全同立构聚丙烯，特别是具有高常规金属茂催化剂难以达到的高定向度的聚丙烯。