摘要:
A positive electrode material that can form a positive electrode mixture containing composition with reduced changes over time and high productivity, a manufacturing method thereof, a non-aqueous rechargeable battery less likely to swell and having a high storage characteristic during storage at high temperatures, and a positive electrode that can form the battery are provided. The object is solved by providing a positive electrode material having a coating layer of an organic silane compound on a surface of a positive electrode active material made of a lithium nickel composite oxide represented by the general compositional formula (1): Li1+xMO2 where −0.5≦x≦0.5, M represents a group of at least two elements including at least one of Mn and Co and Ni, and 20≦a
摘要翻译:能够形成含有时间变化小且生产率高的组合物的正极合剂的正极材料,其制造方法,在高温下储存时不太可能膨胀且具有高储存特性的非水可再充电电池,以及 提供可形成电池的正电极。 本发明的目的是通过在由通式(1)表示的锂镍复合氧化物的正极活性物质的表面上设置具有有机硅烷化合物的被覆层的正极材料:Li1 + xMO2,其中, 0.5和nlE; x和nlE; 0.5,M表示包含Mn和Co和Ni中的至少一种的至少两种元素的基团,以及20和nlE; a <100和50和nlE; a + b + c&nlE; 100当比率(mol% 在形成M的元素中的Ni,Mn和Co分别为a,b和c。
摘要:
A positive electrode material that can form a positive electrode mixture containing composition with reduced changes over time and high productivity, a manufacturing method thereof, a non-aqueous rechargeable battery less likely to swell and having a high storage characteristic during storage at high temperatures, and a positive electrode that can form the battery are provided. The object is solved by providing a positive electrode material having a coating layer of an organic silane compound on a surface of a positive electrode active material made of a lithium nickel composite oxide represented by the general compositional formula (1): Li1+xMO2 where −0.5≦x≦0.5, M represents a group of at least two elements including at least one of Mn and Co and Ni, and 20≦a≦100 and 50≦a+b+c≦100 when the ratios (mol %) of Ni, Mn, and Co in the elements forming M are a, b, and c, respectively.
摘要翻译:能够形成含有时间变化小且生产率高的组合物的正极合剂的正极材料,其制造方法,在高温下储存时不太可能膨胀且具有高储存特性的非水可再充电电池,以及 提供可形成电池的正电极。 本发明的目的是通过在由通式(1)表示的锂镍复合氧化物的正极活性物质的表面上设置具有有机硅烷化合物的被覆层的正极材料:Li1 + xMO2,其中, 0.5和nlE; x&nlE; 0.5,当比例(摩尔%)为0.5时,M表示至少包含Mn和Co和Ni中的至少一种的元素,以及20和nlE; a&nlE; 100和50和nlE; a + b + c& 在形成M的元素中的Ni,Mn和Co分别为a,b和c。
摘要:
An electrode for an electrochemical device of the present invention includes an electrode mixture layer that includes a lithium-containing composite oxide expressed by the general composition formula (1): Li1+xMO2 as an active material, where x satisfies −0.3≦x≦0.3 and M represents an element group including Ni, Mn, and Mg. The relationships 70≦a≦97, 0.5
摘要:
There is provided a positive electrode material used for a positive electrode of a non-aqueous secondary battery. The positive electrode material includes: a positive electrode active material; and at least one selected from the group consisting of (i) a compound having two or more epoxy groups, (ii) a ring-cleavage form of the compound in which at least one of the epoxy groups is opened, and (iii) a polymer of the compound.
摘要:
A non-aqueous secondary battery of the present invention includes a positive electrode, a negative electrode, a separator and a non-aqueous electrolyte. The positive electrode includes a lithium-containing composite oxide as a positive electrode active material, expressed by a general compositional formula (1): Li1+yMO2 where −0.5≦y≦0.5. M denotes an element group including Ni and at least one element selected from the group consisting of Co, Mn, Fe and Ti. And the non-aqueous electrolyte includes a cycloalkane derivative A having at least one alkyl ether group containing an unsaturated bond, and at least one compound selected from the group consisting of an azacrown ether compound B having a functional group where at least one of nitrogen atoms contains an unsaturated bond and a nitrogen-containing heterocyclic compound C.
摘要:
An electrode active material includes particles of a lithium-containing composite oxide represented by the general compositional formula: Li1+xMO2, where −0.15≦x≦0.15, and M represents an element group of three or more elements including at least Ni, Co and Mn, wherein the ratios of Ni, Co and Mn to the total elements constituting M satisfy 45≦a≦90, 5≦b≦30, 5≦c≦30 and 10≦b+c≦55, where the ratios of Ni, Co and Mn are represented by a, b and c, respectively, in units of mol %, the average valence A of Ni in the whole particles is 2.2 to 3.2, the valence B of Ni on the surface of the particles has the relationship: B
摘要:
An electrode active material includes particles of a lithium-containing composite oxide represented by the general compositional formula: Li1+xMO2, where −0.15≦x≦0.15, and M represents an element group of three or more elements including at least Ni, Co and Mn, wherein the ratios of Ni, Co and Mn to the total elements constituting M satisfy 45≦a≦90, 5≦b≦30, 5≦c≦30 and 10≦b+c≦55, where the ratios of Ni, Co and Mn are represented by a, b and c, respectively, in units of mol %, the average valence A of Ni in the whole particles is 2.2 to 3.2, the valence B of Ni on the surface of the particles has the relationship: B
摘要:
The non-aqueous secondary battery of the present invention includes a positive electrode, a negative electrode, a non-aqueous electrolyte and a separator. The positive electrode includes a positive electrode mixture layer containing a positive electrode active material, a conductive polymer, an organic silane compound, a conductive assistant and a binder, the conductive polymer is polythiophene or a derivative thereof, and the content of the conductive polymer is 0.05 to 0.5 mass % with respect to the total mass of the positive electrode mixture layer.
摘要:
The electrode for a lithium ion secondary battery of the present invention has an electrode mixture layer containing carbon nanotubes as a conductive auxiliary agent and deoxyribonucleic acid as a dispersant for the carbon nanotubes, and the content of the carbon nanotubes in the electrode mixture layer is 0.001 to 5 parts by mass with respect to 100 parts by mass of active material particles. The lithium ion secondary battery of the present invention has the electrode of the invention as its positive electrode and/or negative electrode. The electrode of the invention can be produced by a producing method of the invention of forming the electrode mixture layer from an electrode mixture-containing composition prepared using a dispersion including carbon nanotubes and deoxyribonucleic acid.
摘要:
A non-aqueous electrolyte secondary battery including a positive electrode, a negative electrode, a non-aqueous electrolyte, and a separator, wherein the positive electrode includes a positive electrode current collector and a positive electrode material mixture layer formed on one or both sides of the positive electrode current collector, the positive electrode material mixture layer has a thickness greater than 80 μm per side of the positive electrode current collector, the positive electrode material mixture layer includes a positive electrode active material, the positive electrode active material is composed of secondary particles formed by aggregation of primary particles, the secondary particles have an average particle size of 6 μm or less, and, when diffraction-line integrated intensities of the (003) plane and the (104) plane in an X-ray diffraction chart of the positive electrode material mixture layer are I003 and I104, respectively, the ratio I003/I104 of the integrated intensities is 1.1 or more.