NEGATIVE ELECTRODE COMPOSITE MATERIAL, PREPARATION METHOD THEREOF, NEGATIVE ELECTRODE AND LITHIUM-ION SECONDARY BATTERY

    公开(公告)号:US20240347706A1

    公开(公告)日:2024-10-17

    申请号:US18612418

    申请日:2024-03-21

    Abstract: The present invention provides a negative electrode composite material, a preparation method thereof, a negative electrode and a lithium ion secondary battery. The negative electrode composite material comprises negative electrode active material particulates and Li2CO3 and LiOH at the surface of the negative electrode active material particulates, the negative electrode active material particulates comprise: particles containing silicon oxide and at least one lithium silicate selected from Li2SiO3 and Li2Si2O5; and a carbon coating layer coating at least a part of surface of the particles, based on the weight of the negative electrode active material particulates, the content of Li2CO3 is greater than about 0 wt % and less than about 0.01 wt %, and the content of LiOH is greater than about 0 wt % and less than about 0.01 wt %. By the negative electrode composite material, the preparation method thereof, the negative electrode and the lithium-ion secondary battery of the present invention, the residual lithium amount can be reduced to a great extent, the processing performance of the slurry can be significantly improved, and the initial Coulombic efficiency and cycle performance of the lithium-ion secondary battery can be improved.

    POSITIVE ELECTRODE ACTIVE MATERIAL FOR LITHIUM ION SECONDARY BATTERY

    公开(公告)号:US20200006748A1

    公开(公告)日:2020-01-02

    申请号:US16446033

    申请日:2019-06-19

    Inventor: Yuli LI Jixian LV

    Abstract: The present disclosure provides a positive electrode active material for a lithium ion secondary battery. The positive electrode active material includes a material represented by LiCo(1−α−β)A(α)B(β)O2, wherein the material is configured to have good cycling performance and thermal stability at high charging voltages, and to inhibit expansion of the secondary battery. The present disclosure further provides a positive electrode and a secondary battery using the same positive electrode active material.

    Negative Electrode Composite Material, Preparation Method Thereof, Negative Electrode and Lithium-Ion Secondary Battery

    公开(公告)号:US20240332501A1

    公开(公告)日:2024-10-03

    申请号:US18612265

    申请日:2024-03-21

    Abstract: The present invention provides a negative electrode composite material, a preparation method thereof, a negative electrode and a lithium ion secondary battery. The negative electrode composite material comprises: negative electrode active material particulates and Li2CO3 and LiOH at the surface of the negative electrode active material particulates, the negative electrode active material particulates comprise: particles containing silicon oxide, Li2SiO3 and Li2Si2O5; and a carbon coating layer coating at least a part of surface of the particles, based on the weight of the negative electrode active material particulates, the content of Li2CO3 is greater than about 0.01 wt % and less than about 1 wt %, the content of LiOH is greater than about 0.001 wt % and less than about 0.1 wt %, and the weight ratio of Li2Si2O5 to Li2SiO3, i.e. Li2Si2O5/Li2SiO3 is in the range of about 1.00 to about 10.00. By the negative electrode composite material, the preparation method thereof, the negative electrode and the lithium-ion secondary battery of the present invention, the residual lithium amount can be effectively reduced, the processing performance of the slurry can be improved, and the initial Coulombic efficiency and cycle performance of the lithium-ion secondary battery can be improved.

    COMPOSITE CATHODE ACTIVE MATERIAL, PREPARATION METHOD THEREOF, CATHODE SHEET AND LITHIUM ION SECONDARY BATTERY

    公开(公告)号:US20220336796A1

    公开(公告)日:2022-10-20

    申请号:US17706942

    申请日:2022-03-29

    Abstract: The present invention provides a composite cathode active material, which comprises a core layer comprising a cathode active material; a hydrogen fluoride barrier layer coating the core layer, the hydrogen fluoride barrier layer comprising a substance consisting of any one of Nb, Ba, Zr, Mn, Mg, Al and Ca or any combination thereof and any one of O, F, B and P or any combination thereof; and a physical barrier layer coating the hydrogen fluoride barrier layer. By using the composite cathode active material, preparation method thereof, cathode sheet and lithium ion secondary battery of the present invention, the contacting and reacting of the hydrogen fluoride with cathode active material are effectively prevented, the dissolution of the metal in the cathode active material is inhibited, the stability of the crystal structure in the bulk phase of the cathode active material is ensured, and the increase of the cycle retention rate and the decrease of the impedance growth rate are realized.

    POSITIVE ELECTRODE MATERIAL FOR LITHIUM ION SECONDARY BATTERY AND PREPARATION METHOD THEREFOR

    公开(公告)号:US20250002370A1

    公开(公告)日:2025-01-02

    申请号:US18676091

    申请日:2024-05-28

    Abstract: The present application provides a positive electrode material for a lithium ion secondary battery and a preparation method therefor. The positive electrode material for a lithium ion secondary battery comprises polycrystalline particles of a ternary positive electrode material and a modifying material. The polycrystalline particles comprise a plurality of primary particles. The modifying materials are located on the surface of the polycrystalline particles and/or at the grain boundary interfaces between the primary particles, wherein the modifying material comprises an oxide of a positive pentavalent or positive hexavalent transition metal. By using the positive electrode material for a lithium ion secondary battery and the preparation method therefor of the present application, the problem of cracking of secondary particles of the material during the circulation process is avoided. Thus, the mechanical strength and structural stability of the ternary positive electrode material are effectively improved, and at the same time, the high-temperature cycle stability of the ternary positive electrode material is significantly improved, and the impedance increase during the cycle of the lithium ion secondary battery prepared thereby is effectively reduced.

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