摘要:
A method of main reformer startup is disclosed. The method comprises introducing a first supply of fuel and a first supply of air into a micro-reformer. The first supply of fuel is increased to produce a heated reformate in the micro-reformer. The heated reformate is directed through a main reformer in order to heat the main reformer. At least a portion of the heated reformate is burned in the main reformer. A second supply of fuel and a second supply of air is introduced into the main reformer to produce a main supply of reformate. A method for maintaining a vehicle device in standby condition is also disclosed.
摘要:
A method of operating a fuel cell includes the step of selectively connecting and disconnecting the fuel cell to at least one electrical load dependent at least in part upon at least one of a fuel cell voltage, a fuel cell current and a fuel cell temperature.
摘要:
A current carrier for a solid oxide fuel cell system comprising a current-carrying core formed of a high-conductivity metallic material such as copper, brass, bronze, silver, silver-copper alloys, molybdenum, tungsten, or the like, and a protective jacket surrounding the core material. Preferably, the jacket is metallurgically bonded to the core. The jacket is formed of a high temperature alloy such as stainless steel, nickel, or a nickel alloy. The jacket is structurally competent to maintain the form of the electrical carrier at elevated temperatures at which the core material may be structurally incompetent. The current carrier may be sized comparable to conventional copper cables. The carrier is attached to a fuel cell current collector by a clamp assembly having a large surface contact area. Preferably, a contact paste consisting of fine silver particles forms a diffusion bond between the clamp and the carrier jacket, resulting in a low-loss connection.
摘要:
A textured surface is formed on at least one of a fuel cell mounting plate or fuel cell subassembly to define a joint spacing between these two components. In a preferred embodiment, the textured surface comprises a plurality of dimples coined or otherwise formed in the metal mounting plate. The joint spacing improves the manufacturing and assembly process of the fuel cell cassettes through precise application and control of the brazing process which improves the braze joint strength while reducing material cost.
摘要:
An SOFC stack module including an integral individual stack manifold containing all of the gas pathways necessary for supply and exhaust of fuel gas and cathode air to and from the stack chimneys. The stack is mounted and hermetically joined directly to the manifold without an intermediate base plate. Flanges at the inlet and outlet ports couple to system distributary manifolds via high temperature sealing joints. The manifold preferably is fabricated of a ferritic stainless steel, and may be formed in a one-piece casting, a combination of multiple castings and stamped plates metallurgically joined (brazed or welded together), or stamped from sheet metal stock. Preferably, the manifold includes fin structures extending into adjacent fuel gas and cathode air chambers to enhance balancing of temperatures by heat exchange therebetween. Heat exchange may be further improved by configuring the manifold to have a plurality of interleaved anode and cathode gas supply chambers.
摘要:
In a fuel cell assembly, nickel-based anodes are readily oxidized when exposed to oxygen as may happen through atmospheric invasion of the assembly during cool-down following shutdown of the assembly. Repeated anode oxidation and reduction can be destructive of the anodes, leading to cracking and failure. To prevent such oxygen migration, oxygen getter devices containing oxygen-gettering material such as metallic nickel are provided in the fuel passageways leading to and from the anodes. Oxidation of the oxygen-gettering material is readily reversed through reduction by fuel when the assembly is restarted.
摘要:
In a modular fuel cell cassette for forming a fuel cell stack, anode openings in the mounting plate and separator plate are separated and connected by modular spacer rings such that the cassette is incompressible at operating temperatures and compressive loads within the stack. The spacer rings are formed in modules wherein all of the rings required for all of the anode supply chimneys or all of the anode exhaust chimneys of any given cassette are ganged together and include a perimeter rail to which the rings are connected which automatically orients and positions the rings within the cassette during assembly thereof. The present invention eliminates the prior art need for individually positioning and spot welding each prior art ring in place prior to assembly of a prior art cassette. Two different structural embodiments for a spacer ring module are disclosed.
摘要:
A solid-oxide fuel cell system wherein a reformate combustor is disposed in the reformate flow path between a hydrocarbon reformer and a fuel cell stack. At system start-up, reformate is partially burned within the combustor by admitting combustion air, and the partially-burned reformate is passed through the anode chambers of the stack to warm the anodes. In addition, reformate is passed through a cathode-air heat exchanger to warm combustion air entering the cathode chambers of the stack. The combustor may continue to be supplied with a low level of air during steady-state operation of the SOFC, thereby providing a moist environment within the anode chambers to prevent coking of the anodes and providing additional heat to the reformate. The combustor decouples the reformer from the stack thermodynamically, permitting the reformer and the stack each to run in its own optimal temperature range.
摘要:
In a solid-oxide fuel cell assembly comprising a plurality of components having electrically-conductive mating surfaces therebetween, the surfaces are sealed by gasket elements that include first and second silver braze alloy layers and a dielectric layer, formed preferably of yttrium-stabilized zirconia (YSZ), disposed between the alloy layers. The alloy is capable of bonding to many ceramics, including YSZ, and is readily brazed to the oxide layer formed on many metals at elevated temperatures. Because the braze alloy is electrically conductive, a dielectric layer must be included to break conductivity in bonding applications where electrical insulation is required. YSZ functions as a reliable insulator and will not crystallize or fracture as do prior art glass insulators. The assembly is useful as an auxiliary power unit in a vehicle.
摘要:
A minimum joint thickness can be assured by incorporating beads or particles having a diameter corresponding to the joint thickness desired and which are infusible at the brazing temperature. Preferably such particles are formed of high-melting metals, metal oxides, ceramics, or cermets and are mixed into the alloy paste prior to fusing. In a preferred embodiment, the particle-containing paste is mixed with a non-flux carrier to facilitate application to the elements to be brazed. Exemplary application methods may include painting, rolling, screening, or extrusion dispensing. Brazing alloys in accordance with the invention are useful in bonding ceramics to ceramics, ceramics to metals, and metals to metals.