Additive for Positive Electrode of Lithium Secondary Battery, Method for Manufacturing Same, and Lithium Secondary Battery Comprising Same

    公开(公告)号:US20240059581A1

    公开(公告)日:2024-02-22

    申请号:US18269719

    申请日:2022-05-10

    IPC分类号: C01G53/00

    摘要: An additive for a positive electrode of a lithium secondary battery comprising a lithium transition metal oxide, Li3PO4 and Li5AlO4. The lithium transition metal oxide is doped with aluminum. The additive comprising Li3PO4 and Li5AlO4 together with the lithium transition metal oxide has a function of improving battery stability when applied to a positive electrode of a lithium secondary battery. Specifically, when a general lithium transition metal oxide is applied to the positive electrode of a lithium secondary battery, it may cause a side reaction with the electrolyte solution to generate gas in the battery, which may cause a problem with poor stability. However, Li3PO4 and Li5AlO4 are uniformly mixed with the lithium transition metal oxide or partially form a coating layer, and some aluminum is doped into the lithium transition metal oxide to inhibit the lithium transition metal oxide from causing side reactions with the electrolyte solution.

    Positive Electrode Active Material for Secondary Battery and Lithium Secondary Battery Including the Same

    公开(公告)号:US20230095804A1

    公开(公告)日:2023-03-30

    申请号:US17795049

    申请日:2021-01-19

    摘要: A positive electrode active material, and a positive electrode and a lithium secondary battery including the same are disclosed herein. In some embodiments, a positive electrode active material includes a lithium composite transition metal oxide containing nickel, cobalt, and manganese and having a nickel content for 60 mol % or more, based on metals (M) excluding lithium, and is in the form of single particles having an average particle diameter (D50) of 1 to 10 μm, wherein a 100-nm region extending from the surface toward the center of a single particle has crystal structures of a Fd3M and a Fm3m space group, and a phase ratio is 0.2 to 0.7, which is a ratio of a first portion of a maximum straight length of the 100-nm region occupied by the crystal structure of the Fd3M space group to a second portion occupied by the crystal structure of the Fm3m space group.