公开(公告)号：US10280236B2

公开(公告)日：2019-05-07

申请号：US16121157

申请日：2018-09-04

Applicant: LG CHEM, LTD.

Inventor： A Rim Kim ,  Dong Eun Kim ,  Jin Sam Gong ,  Seung Hwan Jung ,  Hae Woong Park

IPC: C07F7/10 ,  C07F17/00 ,  C08F4/6592 ,  C08F210/16 ,  C08F4/76 ,  C07F7/08 ,  C07F7/28 ,  C08F4/659

Abstract: The present invention relates to a novel ligand compound, a transition metal compound and a catalyst composition including the transition metal compound. The novel ligand compound and the transition metal compound of the present invention may be usefully used as the catalyst of a polymerization reaction for preparing an olefin polymer having a low density relative to a CGC catalyst. In addition, a product having a low melt index (MI) and a high molecular weight may be manufactured using the olefin polymer polymerized using the catalyst composition including the transition metal compound.

公开(公告)号：US10023669B2

公开(公告)日：2018-07-17

申请号：US15500859

申请日：2016-03-23

Applicant: LG CHEM, LTD.

Inventor： Hyo Ju Kim ,  Ji Yoon Woo ,  Sang Eun Park ,  Young Woo Lee ,  Choong Hoon Lee ,  Hae Woong Park ,  Ik Je Choe

IPC: C08F110/00 ,  C08F210/16 ,  C08F4/76

Abstract: The present invention relates to an olefin-based polymer exhibiting a single peak when analyzed by gel permeation chromatography (GPC), and having three elution temperatures Te1, Te2 and Te3 when measuring temperature rising elution fractionation (TREF) at a temperature ranging from −20° C. to 120° C. Accordingly, the olefin-based polymer having excellent mechanical strength, and in particular, significantly improved impact strength is provided.

公开(公告)号：US09725531B2

公开(公告)日：2017-08-08

申请号：US14895763

申请日：2013-12-27

Applicant: LG CHEM, LTD.

Inventor： Young Shil Do ,  Choong Hoon Lee ,  Seung Hwan Jung ,  Don Ho Kum ,  Sang Eun Park ,  Hae Woong Park

IPC: C07F17/00 ,  C08F4/6592 ,  C08F10/00 ,  C08F4/659

CPC classification number: C08F4/65925 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/16 ,  C08F2410/03 ,  C08F2420/02 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/08 ,  C08F210/08

Abstract: This disclosure relates to a catalyst composition that can prepare polyolefin having high molecular weight, a method for preparing the same, and a method for preparing polyolefin using the same. The dinuclear metallocene compound included in the catalyst composition according to the present invention is a dinuclear metallocene compound with a new structure, and, unlike a single-site catalyst, has high accessibility to a substrate, and thus, can provide a multi-site catalyst with high activity.

公开(公告)号：US09701768B2

公开(公告)日：2017-07-11

申请号：US15021149

申请日：2014-09-29

Applicant: LG CHEM, LTD.

Inventor： Don Ho Kum ,  Choong Hoon Lee ,  Sang Eun Park ,  Seung Hwan Jung ,  Yoon Hee Cho ,  Young Shil Do ,  Hae Woong Park ,  Young Woo Lee

IPC: C08L23/08 ,  C08F4/653 ,  C08F4/6592 ,  C08F210/02 ,  C08F4/659 ,  C08F210/16

CPC classification number: C08F210/02 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F210/16 ,  C08F2420/02 ,  C08L23/0815 ,  C08F210/08 ,  C08F2500/10 ,  C08F2500/08 ,  C08F2500/12 ,  C08F2500/03 ,  C08F2500/02

Abstract: The present invention relates to a polyolefin having a molecular weight distribution of 1.5 to 3.0 and having a branch gradient number (BGN) of 0.01 to 1.0. According to the present invention, there is provided the polyolefin having a narrow molecular weight distribution and showing a unique comonomer distribution to have excellent impact strength and mechanical physical properties.

公开(公告)号：US09550848B2

公开(公告)日：2017-01-24

申请号：US14779788

申请日：2014-09-25

Applicant: LG CHEM, LTD.

Inventor： Young Woo Lee ,  Hae Woong Park ,  Sang Eun Park ,  Choong Hoon Lee ,  Don Ho Kum

IPC: C08F4/6592 ,  C08F4/642 ,  C08F4/643 ,  C08F4/653 ,  C08F10/00 ,  C08F210/16 ,  C08L23/08 ,  C08F4/659 ,  C07F7/28 ,  B01J31/14 ,  B01J31/22 ,  C08F4/52 ,  C08F4/76 ,  C07F17/00

CPC classification number: C08F210/16 ,  B01J31/143 ,  B01J31/2295 ,  B01J2531/46 ,  B01J2531/48 ,  C07F7/28 ,  C07F17/00 ,  C08F4/52 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/76 ,  C08F2420/02 ,  C08F2420/06 ,  C08L23/0815 ,  C08L2205/025 ,  C08F10/00 ,  C08F4/6592 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/08 ,  C08F2500/12 ,  C08F210/08

Abstract: The present invention relates to a method of preparing an olefin-based polymer including a step of polymerizing an olefin monomer in the presence of a catalyst composition including a cis isomer and a trans isomer. According to the method of preparing an olefin-based polymer according to an embodiment of the present invention, similar level of density and molecular weight may be exhibited with a relatively smaller amount of octene when compared to that of a common polymer. Thus, a stable olefin-based polymer having good copolymerization properties may be prepared.

Abstract translation: 本发明涉及一种制备烯烃基聚合物的方法，包括在包含顺式异构体和反式异构体的催化剂组合物存在下使烯烃单体聚合的步骤。 根据本发明的一个实施方案的烯烃类聚合物的制备方法，与普通聚合物相比，可以用相对较少量的辛烯表现出类似的密度和分子量。 因此，可以制备具有良好共聚性能的稳定的烯烃基聚合物。

公开(公告)号：US09481747B2

公开(公告)日：2016-11-01

申请号：US14413076

申请日：2014-09-25

Applicant: LG CHEM, LTD.

Inventor： Sang Eun Park ,  Hae Woong Park ,  Young Woo Lee ,  Choong Hoon Lee ,  Don Ho Kum

IPC: B01J31/12 ,  C08F210/16 ,  C08L23/08

CPC classification number: C08F210/16 ,  B01J31/143 ,  B01J31/2295 ,  B01J2531/46 ,  B01J2531/48 ,  C07F7/28 ,  C07F17/00 ,  C08F4/52 ,  C08F4/65904 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/76 ,  C08F2420/02 ,  C08F2420/06 ,  C08L23/0815 ,  C08L2205/025 ,  C08F10/00 ,  C08F4/6592 ,  C08F210/14 ,  C08F2500/03 ,  C08F2500/08 ,  C08F2500/12 ,  C08F210/08

Abstract: The present invention relates to an olefin-based polymer including an elution temperature 1 (Te1) and an elution temperature 2 (Te2), which are elution temperatures of the olefin-based polymer in a temperature range from −20° C. to 130° C. when measuring temperature rising elution fractionation (TREF) and having branch gradient number (BGN) from −1.0 to −0.001 when measuring chromatography Fourier transform infrared spectroscopy (GPC FT-IR).

Abstract translation: 本发明涉及一种包含洗脱温度1（Te1）和洗脱温度2（Te2）的烯烃类聚合物，它们是在-20℃至130℃的温度范围内的烯烃类聚合物的洗脱温度 当测量色谱傅立叶变换红外光谱（GPC FT-IR）时，测量升温洗脱分级（TREF）并具有-1.0至-0.001的分枝梯度数（BGN）时的C.

公开(公告)号：US10508165B2

公开(公告)日：2019-12-17

申请号：US15743469

申请日：2016-12-08

Applicant: LG Chem, Ltd.

Inventor： Sang Eun Park ,  Hae Woong Park ,  Choong Hoon Lee ,  Seung Hwan Jung ,  Ji Yoon Woo ,  Hyo Ju Kim ,  Young Woo Lee

IPC: C08F210/16 ,  C08F2/04 ,  C08F4/42 ,  C08F210/02 ,  C08F210/06 ,  C08F210/08 ,  C08F210/14 ,  C08F212/08 ,  C08F212/36 ,  C08F236/06 ,  C08F236/04

Abstract: The present invention provides an olefin-based polymer which satisfies the following conditions of (1) to (4) and is capable of exhibiting improved impact strength without degrading mechanical properties such as tensile strength:(1) density (d): from 0.850 to 0.910 g/cc, (2) melting index (MI, 190° C., 2.16 kg load conditions): from 0.1 to 100 g/10 min, (3) molecular weight distribution (MWD): from 1.5 to 3.0, and (4) two peaks are shown in a temperature range of −20° C. to 120° C. when taking measurements of temperature rising elution fractionation (TREF), and a relation of T(90)−T(50)≥60° C. is satisfied (where T(90) is a temperature at which 90 wt % of the olefin-based polymer is eluted, and T(50) is a temperature at which 50 wt % of the olefin-based polymer is eluted).

公开(公告)号：US20180201706A1

公开(公告)日：2018-07-19

申请号：US15743469

申请日：2016-12-08

Applicant: LG Chem, Ltd.

Inventor： Sang Eun Park ,  Hae Woong Park ,  Choong Hoon Lee ,  Seung Hwan Jung ,  Ji Yoon Woo ,  Hyo Ju Kim ,  Young Woo Lee

IPC: C08F210/16 ,  C08F210/14 ,  C08F210/08 ,  C08F210/06 ,  C08F210/02 ,  C08F212/36 ,  C08F212/08 ,  C08F236/06 ,  C08F236/04 ,  C08F2/04 ,  C08F4/42

CPC classification number: C08F210/16 ,  C08F2/04 ,  C08F4/42 ,  C08F210/02 ,  C08F210/06 ,  C08F210/08 ,  C08F210/14 ,  C08F212/08 ,  C08F212/36 ,  C08F236/045 ,  C08F236/06 ,  C08F2500/01 ,  C08F2500/04 ,  C08F2500/08 ,  C08F2800/20 ,  C08F2500/02 ,  C08F2500/03 ,  C08F2500/12 ,  C08F4/65904 ,  C08F4/6592

Abstract: The present invention provides an olefin-based polymer which satisfies the following conditions of (1) to (4) and is capable of exhibiting improved impact strength without degrading mechanical properties such as tensile strength: (1) density (d): from 0.850 to 0.910 g/cc, (2) melting index (MI, 190° C., 2.16 kg load conditions): from 0.1 to 100 g/10 min, (3) molecular weight distribution (MWD): from 1.5 to 3.0, and (4) two peaks are shown in a temperature range of −20° C. to 120° C. when taking measurements of temperature rising elution fractionation (TREF), and a relation of T(90)−T(50)≥60° C. is satisfied (where T(90) is a temperature at which 90 wt % of the olefin-based polymer is eluted, and T(50) is a temperature at which 50 wt % of the olefin-based polymer is eluted).

公开(公告)号：US09822200B2

公开(公告)日：2017-11-21

申请号：US15110596

申请日：2015-11-06

Applicant: LG CHEM, LTD.

Inventor： Dong Eun Kim ,  A Rim Kim ,  Jin Sam Gong ,  Seung Hwan Jung ,  Hae Woong Park

IPC: C08F10/00 ,  C08F4/02 ,  C08F4/6592 ,  C08F110/02 ,  C08F210/16 ,  C07F7/10 ,  C07F7/28 ,  C07F17/00

CPC classification number: C08F210/16 ,  C07F7/10 ,  C07F7/28 ,  C07F17/00 ,  C08F4/6592

Abstract: The present invention relates to a novel ligand compound, a transition metal compound, and a catalytic composition including the same. The novel ligand compound and the transition metal compound of the present invention are useful as a polymerization reaction catalyst in preparing an olefin-based polymer having low density. In addition, an olefin polymer polymerized using a catalytic composition including the transition metal compound is capable of being prepared to a high molecular weight product having a low melt index (MI).

公开(公告)号：US20210238398A1

公开(公告)日：2021-08-05

申请号：US17050998

申请日：2019-05-03

Applicant: LG Chem, Ltd.

Inventor： Seul Ki Kim ,  Hae Woong Park ,  Young Woo Lee ,  Ki Eun Kim ,  Choong Hoon Lee

IPC: C08L23/08 ,  C08F210/08 ,  C08F4/6592 ,  G02B1/04

Abstract: The present invention provides an ethylene/alpha-olefin copolymer satisfying the following conditions (a) to (d): (a) density: 0.850 to 0.910 g/cc, (b) melt index (MI, 190° C., 2.16 kg load conditions): 0.1 to 100 dg/min, (c) molecular weight distribution (MWD): 1.5 to 3.0, and (d) a Rv value of 0.18 to 0.59.