公开(公告)号：US07038076B2

公开(公告)日：2006-05-02

申请号：US10088229

申请日：2001-07-11

Applicant: Kazufumi Kai ,  Keisuke Ohta ,  Yasushi Kadowaki ,  Hiroshi Uchida

Inventor： Kazufumi Kai ,  Keisuke Ohta ,  Yasushi Kadowaki ,  Hiroshi Uchida

IPC: C07C69/34 ,  C07C69/52

CPC classification number: C07C69/60 ,  C08G63/52 ,  C08G63/547 ,  C08G63/553

Abstract: This invention is to provide a polymerizable composition having excellent curability and surface hardness, and a cured product thereof. A novel fumarate derivative having two or more fumarate groups within one molecule and ensuring copolymerizability with the terminal alkenyloxy group, a method for producing the derivative, a polymerizable composition containing the derivative, and a cured product thereof are provided.

Abstract translation: 本发明提供一种固化性，表面硬度优异的聚合性组合物及其固化物。 提供了在一个分子内具有两个以上富马酸酯基并确保与末端烯氧基的共聚性的新型富马酸酯衍生物，该衍生物的制造方法，含有该衍生物的聚合性组合物及其固化物。

公开(公告)号：US06376702B1

公开(公告)日：2002-04-23

申请号：US09495292

申请日：2000-02-01

Applicant: Kazufumi Kai ,  Keisuke Ohta ,  Hiroshi Uchida

Inventor： Kazufumi Kai ,  Keisuke Ohta ,  Hiroshi Uchida

IPC: C07C6748

CPC classification number: C07C69/593 ,  C07C69/60

Abstract: Disclosed herein is a novel 1-alkenyl ether compound which can be cured by radical polymerization. The invention provides a 1-alkenyl ether compound represented by the formula: R1—CH═CH—(OR2)n—OCO—X—COO—(R2O)n—CH═CH—R1  (1) wherein X represents —CH═CH— or —CH2—C(═CH2)—, each of R1 independently represents hydrogen or an alkyl group having 1 to 3 carbon atoms, each of R2 independently represents an alkylene group having 2 to 4 carbon atoms or a cycloalkylene group having 5 to 12 carbon atoms, and n is an integer of 1 to 10, and a 2-alkenyl ether compound represented by the formula: R5—CH═CH—CH2—(OR2)n—OCO—X—COO—(R2O)n—CH2—CH═CH—R5  (2) wherein X represents —CH═CH— or —CH2—C(═CH2)—, each of R5 independently represents hydrogen or an alkyl group having 1 to 2 carbon atoms, each of R2 independently represents an alkylene group having 2 to 4 carbon atoms or a cycloalkylene group having 5 to 12 carbon atoms, and n is an integer of 1 to 5, provided that, when n=1, each of R2 represents an alkylene group having 3 or 4 carbon atoms or a cycloalkylene group having 5 to 12 carbon atoms. The above compounds can be obtained by the reaction between fumaric acid, maleic acid, itaconic acid, a derivative thereof or the like and a polyalkylene glycol monopropenyl ether, a polyalkylene glycol monoallyl ether or the like. Further, the compound of the formula (1) (provided that R1 is not hydrogen) can be obtained by isomerizing the 2-alkenyl ether compound.

Abstract translation: 本文公开了一种可通过自由基聚合固化的新型1-链烯基醚化合物。本发明提供由下式表示的1-烯基醚化合物：其中X表示-CH = CH-或-CH 2 -C（= CH 2） - 中，R 1各自独立地表示氢或碳原子数1〜3的烷基，R2各自独立地表示碳原子数2〜4的亚烷基或碳原子数为5〜12的亚环烷基，n为1的整数 至10，和由下式表示的2-烯基醚化合物：其中X表示-CH = CH-或-CH 2 -C（= CH 2） - ，每个R 5独立地表示氢或具有1至2个碳原子的烷基， R 2各自独立地表示碳原子数为2〜4的亚烷基或碳原子数为5〜12的亚环烷基，n为1〜5的整数，条件是当n = 1时，R 2表示亚烷基 具有3或4个碳原子或具有5至12个碳原子的亚环烷基 可以通过富马酸，马来酸，衣康酸，其衍生物等与聚亚烷基二醇单丙烯基醚，聚亚烷基二醇单烯丙基醚等的反应获得。 此外，式（1）的化合物（其中R 1不是氢）可以通过异构化2-链烯基醚化合物来获得。

公开(公告)号：US06204410B1

公开(公告)日：2001-03-20

申请号：US09254595

申请日：1999-03-11

Applicant: Kazufumi Kai ,  Keisuke Ohta ,  Hiroshi Uchida

Inventor： Kazufumi Kai ,  Keisuke Ohta ,  Hiroshi Uchida

IPC: C07C6748

CPC classification number: C07C69/593 ,  C07C69/007 ,  C07C69/60 ,  C08F16/08 ,  C08F16/32 ,  C08F20/26

Abstract: Disclosed herein is a novel propenyl ether compound which can be cured by radical polymerization. The invention provides a propenyl ether compound represented by the formula: CH3—CH═CH—(OR1)n—OCO—X—COO—(R2O)n—CH═CH—CH3  (1) wherein X represents —CH═CH— or —CH2—C(═CH2)—, each of R1 and R2 represents an alkylene group having 2 to 4 carbon atoms or a cycloalkylene group having 5 to 12 carbon atoms, and n is an integer of 1 to 5, and an allyl ether compound represented by the formula: CH2═CH—CH2—(OR6)n—OCO—X—COO—(R7O)n—CH2—CH═CH2  (2)  wherein X represents —CH═CH— or —CH2—C(═CH2)—, each of R6 and R7 independently represents an alkylene group having 2 to 4 carbon atoms or a cycloalkylene group having 5 to 12 carbon atoms, and n is an integer of 1 to 5, provided that, when n=1, each of R6 and R7 represents an alkylene group having 3 or 4 carbon atoms or a cycloalkylene group having 5 to 12 carbon atoms. The above compounds can be obtained by the reaction between fumaric acid, maleic acid, itaconic acid, a derivative thereof or the like and a polyalkylene glycol monopropenyl ether, a polyalkylene glycol monoallyl ether or the like. Further, the compound of the formula (1) can be obtained by isomerizing the allyl ether compound.

Abstract translation: 本文公开了一种可通过自由基聚合固化的新型丙烯基醚化合物。本发明提供由下式表示的丙烯基醚化合物：其中X表示-CH = CH-或-CH 2 -C（= CH 2） - ，每个R 1 R2表示碳原子数2〜4的亚烷基或碳原子数5〜12的亚环烷基，n表示1〜5的整数，下式表示的烯丙基醚化合物：式中，X表示-CH = CH- 或-CH 2 -C（= CH 2） - ，R 6和R 7各自独立地表示碳原子数2〜4的亚烷基或碳原子数5〜12的亚环烷基，n为1〜5的整数，条件是 当n = 1时，R6和R7各自表示具有3或4个碳原子的亚烷基或具有5至12个碳原子的亚环烷基。上述化合物可以通过富马酸，马来酸，衣康酸 ，其衍生物等和聚亚烷基二醇单丙烯基醚，聚亚烷基 乙二醇单烯丙基醚等。 此外，式（1）的化合物可以通过使烯丙基醚化合物异构化获得。

公开(公告)号：US07049350B2

公开(公告)日：2006-05-23

申请号：US10484877

申请日：2002-07-25

Applicant: Yoshihiro Honda ,  Keisuke Ohta ,  Kazuhiko Ooga ,  Kazufumi Kai ,  Hiroshi Uchida

Inventor： Yoshihiro Honda ,  Keisuke Ohta ,  Kazuhiko Ooga ,  Kazufumi Kai ,  Hiroshi Uchida

IPC: C08F2/46 ,  C07C69/60

CPC classification number: C07C69/60 ,  C07C67/26 ,  C08F216/125

Abstract: A polymerizable compound represented by formula (1): wherein each R1 independently represents at least one organic residue selected from the group consisting of alkylene groups, branched alkylene groups, cycloalkylene groups and arylene groups, R2 represents an organic residue derived from an alcohol compound, a phenol compound or a carboxylic acid compound, n represents an integer of 0 to 20, a production process of the polymerizable composition, a composition using the polymerizable compound, a cured product obtained by curing the composition and a production process of the cured product. The polymerizable compound exhibits a good adhesive property to a substrate such as glass and is imparted with radical polymerizability to enable heat curing and/or active energy ray curing.

Abstract translation: 由式（1）表示的可聚合化合物：其中每个R 1独立地表示至少一种选自亚烷基，支链亚烷基，亚环烷基和亚芳基的有机残基，R SUP > 2表示衍生自醇化合物，酚化合物或羧酸化合物的有机残基，n表示0〜20的整数，可聚合组合物的制备方法，使用可聚合化合物的组合物， 通过固化组合物获得的固化产物和固化产物的生产方法。 可聚合化合物对玻璃等基材表现出良好的粘合性，并具有自由基聚合性，能够进行热固化和/或活性能量射线固化。

公开(公告)号：US07518001B2

公开(公告)日：2009-04-14

申请号：US11663228

申请日：2005-09-20

Applicant: Keisuke Ohta ,  Tsuneo Tajima ,  Kazufumi Kai ,  Yasuyuki Oyama

Inventor： Keisuke Ohta ,  Tsuneo Tajima ,  Kazufumi Kai ,  Yasuyuki Oyama

IPC: C07D327/04 ,  C08F290/14 ,  C08F299/00 ,  G08G75/28

CPC classification number: C08K5/46 ,  C07D327/04 ,  C08F216/1466 ,  C08F220/38 ,  C08G75/28

Abstract: The invention relates to a radically polymerizable sulfur-containing compound having a group represented by formula (1) and at least one selected from among groups represented by formulae (2) to (4), a radically polymerizable sulfur-containing polymer obtained by subjecting the compound to cationic ring-opening (co)polymerization, production process thereof, a composition containing the sulfur-containing compound and/or the sulfur-containing polymer, and a cured product obtained from the composition . . . (1)(2)(3)(4) . . . (R1 to R6 each independently represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms.) The cured product obtained from the radically polymerizable sulfur-containing compound and the radically polymerizable sulfur-containing polymer having a high refractive index is useful as an optical material, especially for lens material.

Abstract translation: 本发明涉及具有由式（1）表示的基团和选自式（2）至（4）表示的基团中的至少一种的自由基聚合性含硫化合物，通过使 化合物与阳离子开环（共）聚合反应，其制备方法，含有含硫化合物和/或含硫聚合物的组合物，以及由该组合物得到的固化物。 。 。 （1）（2）（3）（4）。 。 。 （R 1〜R 6各自独立地表示氢原子或碳原子数1〜4的烷基。）由具有高折射率的自由基聚合性含硫化合物和自由基聚合性含硫聚合物得到的固化物可用作 光学材料，特别是用于透镜材料。

公开(公告)号：US20070208149A1

公开(公告)日：2007-09-06

申请号：US11663228

申请日：2005-09-20

Applicant: Keisuke Ohta ,  Tsuneo Tajima ,  Kazufumi Kai ,  Yasuyuki Oyama

Inventor： Keisuke Ohta ,  Tsuneo Tajima ,  Kazufumi Kai ,  Yasuyuki Oyama

IPC: C08F2/00 ,  C07D327/04

CPC classification number: C08K5/46 ,  C07D327/04 ,  C08F216/1466 ,  C08F220/38 ,  C08G75/28

Abstract: The invention relates to a radically polymerizable sulfur-containing compound having a group represented by formula (1) and at least one selected from among groups represented by formulae (2) to (4), a radically polymerizable sulfur-containing polymer obtained by subjecting the compound to cationic ring-opening (co)polymerization, production process thereof, a composition containing the sulfur-containing compound and/or the sulfur-containing polymer, and a cured product obtained from the composition . . . (1)(2)(3)(4) . . . (R1 to R6 each independently represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms.) The cured product obtained from the radically polymerizable sulfur-containing compound and the radically polymerizable sulfur-containing polymer having a high refractive index is useful as an optical material, especially for lens material.

Abstract translation: 本发明涉及具有由式（1）表示的基团和选自式（2）至（4）表示的基团中的至少一种的自由基聚合性含硫化合物，通过使 化合物与阳离子开环（共）聚合反应，其制备方法，含有含硫化合物和/或含硫聚合物的组合物，以及由该组合物得到的固化物。 。 。 （1）（2）（3）（4）。 。 。 （R 1至R 6）各自独立地表示氢原子或具有1至4个碳原子的烷基。）从可自由基聚合的含硫化合物获得的固化产物 并且具有高折射率的自由基聚合性含硫聚合物可用作光学材料，特别是用于透镜材料。

公开(公告)号：US20090270574A1

公开(公告)日：2009-10-29

申请号：US12159045

申请日：2007-01-26

Applicant: Keisuke Ohta ,  Yasuyuki Oyama ,  Kazufumi Kai

Inventor： Keisuke Ohta ,  Yasuyuki Oyama ,  Kazufumi Kai

IPC: C08F28/06 ,  C07D339/06 ,  C08F228/06

CPC classification number: C08F220/38 ,  C08F220/18

Abstract: A radically polymerizable compound having a group represented by formula (1) (In the formula, R1 to R3 each independently represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, X represents an alkylene group having 1 to 4 carbon atoms.) and a radically polymerizable double bond and a composition for an optical material comprising the same have a high refractive index and excellent transparency and are hard to be oxidized in thermal curing and useful as an optical material with little tinting.

Abstract translation: 具有式（1）所示基团的自由基聚合性化合物（式中，R 1〜R 3各自独立地表示氢原子或碳原子数1〜4的烷基，X表示碳原子数1〜4的亚烷基。 ）和可自由基聚合的双键以及包含该组合物的光学材料组合物具有高折射率和优异的透明度，并且在热固化中难以氧化并且可用作少量着色的光学材料。

公开(公告)号：US07939612B2

公开(公告)日：2011-05-10

申请号：US12159045

申请日：2007-01-26

Applicant: Keisuke Ohta ,  Yasuyuki Oyama ,  Kazufumi Kai

Inventor： Keisuke Ohta ,  Yasuyuki Oyama ,  Kazufumi Kai

IPC: C08F28/06 ,  C08F228/06 ,  C07D339/06

CPC classification number: C08F220/38 ,  C08F220/18

Abstract: A radically polymerizable compound having a group represented by formula (1) (In the formula, R1 to R3 each independently represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, X represents an alkylene group having 1 to 4 carbon atoms.) and a radically polymerizable double bond and a composition for an optical material comprising the same have a high refractive index and excellent transparency and are hard to be oxidized in thermal curing and useful as an optical material with little tinting.

Abstract translation: 具有式（1）所示基团的自由基聚合性化合物（式中，R 1〜R 3各自独立地表示氢原子或碳原子数1〜4的烷基，X表示碳原子数1〜4的亚烷基。 ）和可自由基聚合的双键以及包含该组合物的光学材料组合物具有高折射率和优异的透明度，并且在热固化中难以氧化并且可用作少量着色的光学材料。

公开(公告)号：US07569327B2

公开(公告)日：2009-08-04

申请号：US10557173

申请日：2004-05-25

Applicant: Hirotoshi Kamata ,  Keisuke Ohta ,  Kazufumi Kai

Inventor： Hirotoshi Kamata ,  Keisuke Ohta ,  Kazufumi Kai

IPC: C08L71/02 ,  C08F20/00 ,  G03F7/038

CPC classification number: C08F220/18 ,  C08F8/14 ,  C08F8/46 ,  C08F283/06 ,  C08F283/10 ,  C08F290/04 ,  C08F290/06 ,  C08F290/14 ,  C08F2810/20 ,  C08F2810/30 ,  C08G59/1455 ,  C08G59/1461 ,  C08G59/1494 ,  C08G65/3322 ,  G03F7/033 ,  G03F7/0388 ,  C08F220/32 ,  C08F220/14 ,  C08F220/28

Abstract: This invention relates to a novel polymer compound, and a process for preparing the same and a radical polymerizable, curable composition using the same. The polymer of the invention has in the side chain thereof a structure represented by the formula (1): wherein R1 each independently represents at least one or more organic residue selected from the group consisting of an alkylene group, a branched alkylene group, a cycloalkylene group, an aralkylene group and an arylene group, R2 each independently represents at least one or more organic residue selected from the group consisting of an alkylene group, a branched alkylene group, an alkenylene group, a branched alkenylene group, a cycloalkylene group, a cycloalkenylene group and an arylene group, and n represents an integer of 0 to 20.

Abstract translation: 本发明涉及一种新的高分子化合物及其制备方法和使用其的可自由基聚合的可固化组合物。 本发明的聚合物在其侧链中具有由式（1）表示的结构：其中R1各自独立地表示至少一种或多种选自亚烷基，支链亚烷基，亚环烷基的有机残基 基团，亚芳基和亚芳基，R2各自独立地表示选自亚烷基，支链亚烷基，亚烯基，支链亚烯基，亚环烷基，亚环烷基，亚环烷基， 亚环烯基和亚芳基，n表示0〜20的整数。

公开(公告)号：US20070021571A1

公开(公告)日：2007-01-25

申请号：US10557173

申请日：2004-05-25

Applicant: Hirotoshi Kamata ,  Keisuke Ohta ,  Kazufumi Kai

Inventor： Hirotoshi Kamata ,  Keisuke Ohta ,  Kazufumi Kai

IPC: C08F8/00

CPC classification number: C08F220/18 ,  C08F8/14 ,  C08F8/46 ,  C08F283/06 ,  C08F283/10 ,  C08F290/04 ,  C08F290/06 ,  C08F290/14 ,  C08F2810/20 ,  C08F2810/30 ,  C08G59/1455 ,  C08G59/1461 ,  C08G59/1494 ,  C08G65/3322 ,  G03F7/033 ,  G03F7/0388 ,  C08F220/32 ,  C08F220/14 ,  C08F220/28

Abstract: This invention relates to a novel polymer compound, and a process for preparing the same and a radical polymerizable, curable composition using the same. The polymer of the invention has in the side chain thereof a structure represented by the formula (1): wherein R1 each independently represents at least one or more organic residue selected from the group consisting of an alkylene group, a branched alkylene group, a cycloalkylene group, an aralkylene group and an arylene group, R2 each independently represents at least one or more organic residue selected from the group consisting of an alkylene group, a branched alkylene group, an alkenylene group, a branched alkenylene group, a cycloalkylene group, a cycloalkenylene group and an arylene group, and n represents an integer of 0 to 20.

Abstract translation: 本发明涉及一种新的高分子化合物及其制备方法和使用其的可自由基聚合的可固化组合物。 本发明的聚合物在其侧链中具有由式（1）表示的结构：其中R1各自独立地表示至少一种或多种选自亚烷基，支链亚烷基，亚环烷基的有机残基 基团，亚芳基和亚芳基，R2各自独立地表示选自亚烷基，支链亚烷基，亚烯基，支链亚烯基，亚环烷基，亚环烷基，亚环烷基， 亚环烯基和亚芳基，n表示0〜20的整数。