公开(公告)号：US3886232A

公开(公告)日：1975-05-27

申请号：US48983674

申请日：1974-07-17

Applicant: KUREHA CHEMICAL IND CO LTD

Inventor： TANAKA TAKASHI ,  YUSA HARUHIKO ,  CHUBACHI SUSUMU

IPC: C08F285/00 ,  C08L27/06 ,  C08L51/00 ,  C08L51/04 ,  C08D9/10 ,  C08F14/00 ,  C08F15/00

CPC classification number: C08F285/00 ,  C08L27/06 ,  C08L51/00 ,  C08L51/04 ,  Y10S525/902 ,  C08L2666/24

Abstract: The invention relates to a process for production of vinyl chloride resin composition, by uniform blending of 95 to 70 parts by weight of vinyl chloride resin, and 5 to 30 parts by weight of a modifying component obtained by graft-polymerizing upon a cross-linked copolymer rubber latex a first and then a second grafting component in a sequential two-stage process.

Abstract translation: 本发明涉及一种氯乙烯树脂组合物的制造方法，其通过均匀混合95〜70重量份的氯乙烯树脂和5〜30重量份通过交联而接枝聚合得到的改性成分 共聚物橡胶胶乳在连续的两阶段过程中是第一次然后第二次接枝组分。

公开(公告)号：US3652483A

公开(公告)日：1972-03-28

申请号：US3652483D

申请日：1969-10-01

Applicant: KUREHA CHEMICAL IND CO LTD

Inventor： TANAKA TAKASHI ,  YUSA HARUHIKO

IPC: C08F279/06 ,  C08L27/06 ,  C08L33/12 ,  C08L51/04 ,  C08F29/24 ,  C08D9/08 ,  C08F29/50

CPC classification number: C08L27/06 ,  C08F279/06 ,  C08L33/12 ,  C08L51/04 ,  C08L51/003 ,  C08L55/02 ,  C08L2666/02 ,  C08L2666/24

Abstract: IMPACT-RESISTANT POLYVINYL CHLORIDE RESIN ADDED TO MBS POLYMER COMPOSITION CONSISTING OF CROSS-LINKED MBS GRAFT COPOLYMER AND POLYMETHYLMETHACRYLATE LATEX.

公开(公告)号：US3886235A

公开(公告)日：1975-05-27

申请号：US45534974

申请日：1974-03-27

Applicant: KUREHA CHEMICAL IND CO LTD

Inventor： TANAKA TAKASHI ,  YUSA HARUHIKO ,  CHUBACHI SUSUMU

IPC: C08F285/00 ,  C08L27/06 ,  C08L51/00 ,  C08L51/04 ,  C08D9/10 ,  C08F14/00 ,  C08F15/00

CPC classification number: C08F285/00 ,  C08L27/06 ,  C08L51/00 ,  C08L51/04 ,  C08L2666/24

Abstract: The invention relates to a process for production of vinyl chloride resin composition, by uniform blending of 95 to 70 parts by weight of vinyl chloride resin, and 5 to 30 parts by weight of a modifying component obtained by graft-polymerizing upon a cross-linked copolymer rubber latex a first and then a second grafting component in a sequential two-stage process.

公开(公告)号：US3922321A

公开(公告)日：1975-11-25

申请号：US48031274

申请日：1974-06-17

Applicant: KUREHA CHEMICAL IND CO LTD

Inventor： YUSA HARUHIKO ,  OCHIAI YUKIHIRO

IPC: C08L33/00 ,  C08F265/06 ,  C08L33/02 ,  C08L33/04 ,  C08L33/12 ,  C08L51/00 ,  C08L51/02 ,  C08L51/04 ,  C08F15/18 ,  C08F19/02 ,  C08F19/08 ,  C08F19/10 ,  C08F19/16 ,  C08F19/20 ,  C08F37/18

CPC classification number: C08F265/06 ,  C08L33/12 ,  C08L51/04 ,  Y10S525/932 ,  C08F2/16 ,  C08L2666/24

Abstract: By emulsion polymerizing a monomer mixture of an alkyl acrylate, styrene, and butadiene to produce an emulsion of a rubber polymer (A), adding to the latex containing 100 parts by weight of the rubber polymer (A) from 25 to 150 parts by weight of a monomer mixture (B) comprising an alkyl methacrylate, with or without a cross-linking monomer, and a vinyl monomer copolymerizable therewith, polymerizing the resulting mixture of the mixture (B) and the latex thereby to produce a graft copolymer (I), and mixing this graft copolymer (I) and a methacrylic resin (II), a methacrylic resin composition of high transparency, impact strength, and weather resistance is obtained.

Abstract translation: 通过将丙烯酸烷基酯，苯乙烯和丁二烯的单体混合物乳液聚合以制备橡胶聚合物（A）的乳液，将含有100重量份橡胶聚合物（A）的胶乳添加至25至150重量份 包含具有或不具有交联单体的甲基丙烯酸烷基酯和可与其共聚的乙烯基单体的单体混合物（B）的混合物（B），聚合混合物（B）和胶乳的所得混合物，从而产生接枝共聚物（I） ，并将该接枝共聚物（I）和甲基丙烯酸系树脂（II）进行混合，得到高透明性，冲击强度和耐候性的甲基丙烯酸系树脂组合物。

公开(公告)号：US3899547A

公开(公告)日：1975-08-12

申请号：US43093774

申请日：1974-01-04

Applicant: KUREHA CHEMICAL IND CO LTD

Inventor： AMAGI YASUO ,  YUSA HARUHIKO

IPC: C08F279/06 ,  C08L27/06 ,  C08L51/04 ,  C08F15/00 ,  C08F19/00

CPC classification number: C08F279/06 ,  C08L27/06 ,  C08L51/04 ,  Y10S525/932 ,  C08L2666/24

Abstract: Vinyl chloride polymer compositions of improved transparency, impact strength, and workability obtained by blending a substantial quantity of vinyl chloride polymers containing vinyl chloride as the principal constituent thereof and a supplemental quantity of a resin produced from post-polymerization of a monomer mixture of styrene, methylmethacrylate, and a crosslinking agent on coagulated particles of a latex containing butadiene polymer or butadiene-styrene copolymer.

Abstract translation: 通过混合大量含有氯乙烯作为其主要成分的氯乙烯聚合物和补充量的由苯乙烯单体混合物的后聚合产生的树脂而获得的具有改进的透明度，冲击强度和可加工性的氯乙烯聚合物组合物， 甲基丙烯酸甲酯，和含有丁二烯聚合物或丁二烯 - 苯乙烯共聚物的胶乳的凝结颗粒上的交联剂。

公开(公告)号：US3671610A

公开(公告)日：1972-06-20

申请号：US3671610D

申请日：1969-11-14

Applicant: KUREHA CHEMICAL IND CO LTD

Inventor： AMAGI YASUO ,  OHYA MASAKI ,  SHIIKI ZENYA ,  YUSA HARUHIKO

IPC: C08F279/06 ,  C08L9/06 ,  C08L27/06 ,  C08L51/04 ,  D06M15/21 ,  C08F19/08 ,  C08F37/18

CPC classification number: D06M15/21 ,  C08F279/06 ,  C08L27/06 ,  C08L51/04 ,  C08L2666/24

Abstract: Butadiene-styrene-methyl methacrylate copolymers prepared by graft-polymerization with cross-linked butadiene or polybutadiene-styrene copolymer latex of styrene-methyl methacrylate monomers and a cross-linking agent capable of copolymerizing with said monomers in two steps. Polyvinyl chloride resins incorporated with the graft copolymer exhibits improved mechanical strength and other physical properties.

Abstract translation: 通过用苯乙烯 - 甲基丙烯酸甲酯单体的交联丁二烯或聚丁二烯 - 苯乙烯共聚物胶乳接枝聚合制备的丁二烯 - 苯乙烯 - 甲基丙烯酸甲酯共​​聚物和能够在两个步骤中与所述单体共聚的交联剂。

公开(公告)号：US3657390A

公开(公告)日：1972-04-18

申请号：US3657390D

申请日：1969-09-02

Applicant: KUREHA CHEMICAL IND CO LTD

Inventor： TANAKA TAKASHI ,  YUSA HARUHIKO

IPC: C08L27/06 ,  C08L51/04 ,  C08L55/02 ,  C08F29/24 ,  C08F29/50 ,  C08F29/56

CPC classification number: C08L27/06 ,  C08L51/04 ,  C08L55/02 ,  C08L2205/02 ,  Y10S525/931 ,  Y10S525/932 ,  C08L2666/24

Abstract: POLYVINYL CHLORIDE RESIN COMPSITION HAVING EXCELLENT TRANSPARENCY AND IMPACT RESISTANCE PREPARED BY MIXING POLYVINYL CHLORIDE RESIN WITH AT LEAST TWO KINDS OF GRAFTCOPOLYMERS OF BUTADIENE-STYRENE-ACRYLIC MONOMERS, THE ONE HAVING A HIGHER REFRACTIVE INDEX THAN THAT OF THE POLYVINYL CHLORIDE AND THE OTHER HAVING A LOWER REFRACTIVE INDEX THAN THAT OF THE POLYVINYL CHLORIDE, BOTH GRAFT-POLYMERS BEING MIXED AT VARYING PROPORTIONS DEPENDING ON THE KIND AND QUANTITY OF ADDITIVE ASSISTANTS.